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Citation: Wenjing SHI, Chunxiang ZHANG, Shuqin LIU, Jianjun ZHANG. Syntheses, structures, and doping-modulated afterglow properties of ZnSO4-based hybrid materials[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(7): 1534-1542. doi: 10.11862/CJIC.20260079 shu

Syntheses, structures, and doping-modulated afterglow properties of ZnSO4-based hybrid materials

  • School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

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  • Two zero-dimensional inorganic-organic hybrids, (NMe3CH2Ph)2[Zn(H2O)6](SO4)2 (1) and (NMe3CH2Ph)4[Zn2Cl2(SO4)3] (2), were assembled from ZnSO4 and trimethylbenzylammonium chloride. Both feature an inorganic-organic sandwich structure with organic layers formed via aromatic stacking. 1 contains a {[Zn(H2O)6](SO4)2}2- hydrogen-bonded network, while 2 consists of binuclear zinc clusters. Both exhibited room-temperature phosphorescence. 1 showed a lifetime of 14.00 ms (invisible), whereas 2 displayed a lifetime of 290.00 ms with visible green afterglow. Furthermore, a series of host-guest doped afterglow materials was developed using compound 1 as the host matrix. Tuning the guest molecules enabled afterglow tuning from cyan to orange-yellow, with lifetimes enhanced up to about 65-fold versus the pristine host. Furthermore, the application of the doped systems in advanced anti-counterfeiting was preliminarily explored.
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