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Citation: Zifang ZHAO, Jingteng FENG, Jiaxin LI, Cong YANG, Linhan XING, Weifeng HUANG, Mingming HAN. Research progress and prospects on electrolyte additives for aqueous Zn-I2 battery[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(7): 1345-1367. doi: 10.11862/CJIC.20260066 shu

Research progress and prospects on electrolyte additives for aqueous Zn-I2 battery

  • 1.

    School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China

  • 2.

    Hangzhou Institute of Advanced Studies, Zhejiang Normal University, Hangzhou 311231, China

Figures(12)

  • The aqueous Zn-I2 battery has emerged as a promising candidate in the field of energy storage due to its abundant raw material reserves, low cost, intrinsic safety, and high theoretical energy density. However, both the cathode and anode of this battery system encounter a series of persistent challenges in conventional electrolyte systems (such as ZnSO4, Zn(CF3SO3)2, and ZnCl2) including the shuttle effect of polyiodides at the cathode, dissolution of active iodine species, formation of zinc dendrites, zinc corrosion, and parasitic side reactions. These issues collectively hinder the further advancement and practical application of aqueous Zn-I2 battery. The incorporation of functional additives into the electrolyte offers a viable strategy to simultaneously mitigate these interfacial problems, with the added advantage of operational simplicity conducive to large-scale industrial implementation. This paper focuses on electrolyte additives for aqueous Zn-I2 battery, systematically analyzing the critical challenges encountered in common electrolyte systems. It further reviews the mechanisms, functions, characteristics, and performance of various additive types (macromolecular, organic, and inorganic compounds) in aqueous Zn-I2 battery. Finally, future research directions for electrolyte additives are proposed, aiming to provide guidance for the rational screening and design of targeted functional additives toward achieving high-performance aqueous Zn-I2 battery.
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