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Citation: Yawen WEN, Rui ZHU, Yunfang DONG, Jing LIANG, Qian WANG, Junfeng BAI. An open metal sites-occupied [Fe2.9Mn0.1(μ3-OH)(COO)6] cluster-based microporous acs-metal-organic framework for trace C3H4 capture[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(10): 2186-2192. doi: 10.11862/CJIC.20260058 shu

An open metal sites-occupied [Fe2.9Mn0.1(μ3-OH)(COO)6] cluster-based microporous acs-metal-organic framework for trace C3H4 capture

  • School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

Figures(2)

  • A microporous acs-metal-organic framework (MOF) is reported as [Fe2.9Mn0.1(μ3-OH)(L)3·xGuest] (NJTU-Bai88, NJTU-Bai=Nanjing Tech University Bai′s group; H2L=bicyclo[2.2.2]octane-1, 4-dicarboxylic acid), in which potential open metal sites (OMSs) are occupied by solvent molecules with the pore size adjusted (approximately 0.47 nm by Horváth-Kawazoe model) to be close to the kinetic diameter of C3H4 (0.476 nm) and the strong adsorption sites reduced. Interestingly, NJTU-Bai88 showed a high C3H4 adsorption uptake (27.5 cm3·g-1 at 298 K and 1 kPa) and moderate adsorption enthalpy (-58.8 kJ·mol-1).
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