Citation: Liang WANG, Hongxu WU, Yunsong RAO, Dun HAN, Xuan SONG, Jianlong LIN, Dongfang LI, Sheng ZHANG. Research progress in graphene-based materials for hydrogen production via water electrolysis[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(7): 1368-1382. doi: 10.11862/CJIC.20260057 shu

Research progress in graphene-based materials for hydrogen production via water electrolysis

Liang WANG ^{1, #} ,
Hongxu WU ^{2, #} ,
Yunsong RAO ¹ ,
Dun HAN ² ,
Xuan SONG ¹ ,
Jianlong LIN ^{2, 3} ,
Dongfang LI ¹ ,
Sheng ZHANG ^2,,

1.
Offshore Oil Engineering CO., LTD., Tianjin 300451, China
2.
Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Centre of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
3.
Zhejiang Institute of Tianjin University, Ningbo, Zhejiang 315201, China

Corresponding author: Sheng ZHANG, sheng.zhang@tju.edu.cn
Received Date: 16 February 2026
Revised Date: 23 May 2026

Figures(5)

In the face of the global energy crisis and environmental pollution, hydrogen energy, as a clean, high- energy-density carrier, has garnered significant attention. Water electrolysis for hydrogen production, which converts renewable electrical energy into hydrogen, has become a mainstream technology for green hydrogen production. However, the electrocatalytic oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) suffer from kinetic barriers, and the high cost and limited availability of traditional precious metal catalysts hinder their large-scale application. Graphene, with its exceptional conductivity, large specific surface area, excellent mechanical strength, and rich surface chemistry, shows great potential in the field of electrocatalysis. This paper systematically reviews the preparation techniques of graphene materials and their applications in water electrolysis for hydrogen production. Firstly, the advantages and disadvantages of various graphene preparation methods are analyzed from two categories: "top-down" and "bottom-up". In water electrolysis catalysts, graphene can serve as a catalyst support due to its high mechanical strength and electrical conductivity, and can also form active sites through defect engineering and heteroatom doping to develop high-performance catalysts. Moreover, due to its unique structure and properties, graphene plays a key role in coupled processes such as small molecule oxidation in water electrolysis, heavy water purification, seawater desalination, and direct seawater electrolysis. Additionally, the paper discusses the challenges graphene materials face in the widespread application of water electrolysis, focusing on challenges such as scalable production, stability, and defect control, and offers insights into the future development of graphene materials.
- graphene,
- water electrolysis,
- electrocatalysts,
- heavy water,
- hydrogen isotope separation
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沈阳化工大学材料科学与工程学院沈阳 110142