Citation: Tongtong CHEN, Peng ZHAO, Shijia KANG, Huanhuan YU, Baolin ZHU, Shoumin ZHANG. Ultrafine seagrass-shaped La-doped NiCo2O4 composite: Hydrothermal-calcination preparation and oxygen evolution reaction performance[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(10): 2217-2231. doi: 10.11862/CJIC.20260056 shu

Ultrafine seagrass-shaped La-doped NiCo2O4 composite: Hydrothermal-calcination preparation and oxygen evolution reaction performance

Figures(7)

  • The rare-earth (La3+, Gd3+, or Er3+)-doped NiCo2O4 catalysts were supported on nickel foam to optimize charge rearrangement and structural reconstruction, thereby improving oxygen evolution reaction (OER) performance. Notably, the incorporation of La3+ collectively modulates the electronic configuration of Ni2+ and Co3+ through lattice distortion. It strengthens metal-oxygen bonding, thereby constructing the La—O—Ni/Co structural unit, which promotes charge transfer during the OER process and enhances catalytic activity. As a result, the ultrafine seagrass-shaped La-NiCo2O4-1 exhibited excellent OER activity. In a 1 mol·L-1 KOH electrolyte, the prepared 0.25 mmol La3+ doped NiCo2O4 exhibited high OER activity with a low overpotential of 283 mV at 10 mA·cm-2, along with outstanding stability for over 75 h at the multi-step chronoamperometry curve of 50→100→150→100→50 mA·cm-2.
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