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Citation: Siyu ZU, Jianhui LUO, Qingfa SU, Jianchun WANG, Yizhen CHENG, Zhihang GUO, Jinhong BI. Preparation and degrading formaldehyde properties of TiO2/flue gas desulfurization ash photocatalytic composites[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(7): 1437-1452. doi: 10.11862/CJIC.20260043 shu

Preparation and degrading formaldehyde properties of TiO2/flue gas desulfurization ash photocatalytic composites

  • 1.

    Department of Environmental Science and Engineering, Fuzhou University, Fuzhou, Fujian 350108, China

  • 2.

    Fujian Longking Co. Ltd., Longyan, Fujian 364000, China

  • 3.

    Fujian Lonjing Environment Technology Co., Ltd, Xiamen, Fujian 361000, China

Figures(17)

  • A series of TiO2/SGFGDA composite photocatalytic materials were prepared using industrial solid waste Sangang flu gas desulfurization ash (SGFGDA) and industrial titanium gel (TG) as precursors via impregnation‑ loading method. Characterization results from X-ray powder diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and photoelectrochemical tests revealed that TiO2 particles were uniformly dispersed on the surface of SGFGDA, forming a tight and strong interfacial interaction between the two components, which effectively promoted the separation of photogenerated electron-hole pairs. The TiO2 loading amount significantly influenced the photocatalytic degradation performance of the composites toward formaldehyde (HCHO). The sample (TiO2/SGFGDA-40) with TiO2 loading amount (mass fraction) of 40% exhibited optimal HCHO degradation performance under ultraviolet light irradiation, with a degradation efficiency of 87% in 4 h. This performance was significantly superior to that of pure TiO2 and its physical mixture. Systematic comparative studies reveal that the composite obtained by combining SGFGDA with TiO2 outperformed conventional supports in terms of photocatalytic HCHO degradation. Moreover, it can be found that the photocatalytic activity of the flue gas desulfurization ash (FGDA) from different sources-based composites is closely correlated with the CaSO3·0.5H2O content in the FGDA. Furthermore, the above-mentioned powder composite with optimal performance was fabricated into a putty powder coating. The coating retained 80% of the HCHO degradation efficiency after 4 h of ultraviolet light irradiation and retained stable performance over five cycles. It showed good compatibility with common building additives, demonstrating promising potential for engineering applications. Under 72-hour solar irradiation, the optimal powder composite TiO2/SGFGDA-40 achieved 24% HCHO degradation efficiency, comparable to powdered P25 (26%). Its derived putty powder coating exhibited enhanced efficiency of 35%, significantly higher than the putty powder coating prepared by mixing SGFGDA and P25 (19%).
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    1. [1]

      ZHONG Z Y, CHEN M H, HUANG X L, WANG P. Design and synthesis of Pt/TiO2 catalyst with abundant surface hydroxyl for formaldehyde oxidation[J]. J. Hazard. Mater., 2025, 487: 137302  doi: 10.1016/j.jhazmat.2025.137302

    2. [2]

      ZHA F J, LIU Q, WANG J Y, LIN Y H, WANG C Y, LI Y X. One- dimensional TiO2 anatase/rutile heterophase junctions: Preparation and photocatalytic properties for degrading formaldehyde[J]. Chinese J. Inorg. Chem., 2022, 38(3): 510-518  doi: 10.11862/CJIC.2022.057

    3. [3]

      WANG S, WANG Z H, WANG X C, MENG E, LI J, ZHOU B, LI D, HU Z P, ZHAO H Q. Synergistic formaldehyde adsorption under humidity via nitrogen-ethyl modified activated carbon[J]. J. Environ. Chem. Eng., 2025, 13(6): 119665  doi: 10.1016/j.jece.2025.119665

    4. [4]

      ZVULUNOV Y, BEN-BARAK-ZELAS Z, FISHMAN A, RADIAN A. A self-regenerating clay-polymer-bacteria composite for formaldehyde removal from water[J]. Chem. Eng. J., 2019, 374: 1275-1285  doi: 10.1016/j.cej.2019.06.017

    5. [5]

      HUA Y B, AHMADI Y, KIM K H. Thermocatalytic degradation of gaseous formaldehyde using transition metal-based catalysts[J]. Adv. Sci., 2023, 10(21): e2300079  doi: 10.1002/advs.202300079

    6. [6]

      SONG S Q, LU C H, WU X, JIANG S J, SUN C Z, LE Z G. Strong base g-C3N4 with perfect structure for photocatalytically eliminating formaldehyde under visible‑light irradiation[J]. Appl. Catal. B‒Environ., 2018, 227: 145-152  doi: 10.1016/j.apcatb.2018.01.014

    7. [7]

      MA L, HUANG C F, LI X C, AN X, LI J P, ZOU L, ZHU X X, YUAN C, DAI X, ZHOU Y W, ZHU X, TIAN C C. In situ synthesis of mesoporous TiO2 doped with bismuth single atoms for tunable photocatalytic degradation of formaldehyde[J]. Sep. Purif. Technol., 2025, 354(P1): 128635

    8. [8]

      LIU T X, LI F B, LI X Z. TiO2 hydrosols with high activity for photocatalytic degradation of formaldehyde in a gaseous phase[J]. J. Hazard. Mater., 2008, 152(1): 347-355  doi: 10.1016/j.jhazmat.2007.07.003

    9. [9]

      LI S T, LIU H D, HU X, FANG Y F, GAO X F, CHEN Q F. Selective activation of dioxygen to singlet oxygen over La-Si co-doped TiO2 microspheres for photocatalytic degradation of formaldehyde[J]. J. Environ. Sci., 2025, 151: 594-607  doi: 10.1016/j.jes.2024.04.012

    10. [10]

      SAHRIN N T, NAWAZ R, KAIT C F, LEE S L, WIRZAL M D H. Visible light photodegradation of formaldehyde over TiO2 nanotubes synthesized via electrochemical anodization of titanium foil[J]. Nanomaterials, 2020, 10(1): 128-128  doi: 10.3390/nano10010128

    11. [11]

      NISHIYAMA N, YAMAZAKI S. Effect of mixed valence states of platinum ion dopants on the photocatalytic activity of titanium dioxide under visible light irradiation[J]. ACS Omega, 2017, 2(12): 9033-9039  doi: 10.1021/acsomega.7b01393

    12. [12]

      LIU R X, WU L Z, LIU H, ZHANG Y K, MA J J, JIANG C R, DUAN T. High-efficiency photocatalytic degradation of tannic acid using TiO2 heterojunction catalysts[J]. ACS Omega, 2021, 6(43): 28538-28547  doi: 10.1021/acsomega.1c02500

    13. [13]

      DONG Y S, FEI X N. Effect of isopropanol on crystal growth and photocatalytic properties regulation of anatase TiO2 single crystals[J]. Mater. Technol., 2020, 35(2): 102-111  doi: 10.1080/10667857.2019.1659526

    14. [14]

      LI M, LOU T F, LI Q. TiO2 nanoparticles anchored on hollow carbon spheres for enhanced photocatalytic antibacterial[J]. Chinese J. Inorg. Chem., 2023, 39(8): 1489-1500  doi: 10.11862/CJIC.2023.115

    15. [15]

      WANG J, SUN S J, DING H, CHEN W T, LIANG Y. Preparation of a composite photocatalyst with enhanced photocatalytic activity: Smaller TiO2 carried on SiO2 microsphere[J]. Appl. Surf. Sci., 2019, 493: 146-156  doi: 10.1016/j.apsusc.2019.07.005

    16. [16]

      HUANG Q Q, HU Y, PEI Y, ZHANG J H, FU M L. In situ synthesis of TiO2 @NH2-MIL-125 composites for use in combined adsorption and photocatalytic degradation of formaldehyde[J]. Appl. Catal. B‒Environ., 2019, 259: 118106  doi: 10.1016/j.apcatb.2019.118106

    17. [17]

      ZHANG G X, SUN Z M, DUAN Y W, MA R X, ZHENG S L. Synthesis of nano-TiO2/diatomite composite and its photocatalytic degradation of gaseous formaldehyde[J]. Appl. Surf. Sci., 2017, 412: 105-112  doi: 10.1016/j.apsusc.2017.03.198

    18. [18]

      ZHANG J J, JIN C Z, WANG B Q, HAN J, GUO L Y, TANG N N. Study on the micro-rheological properties of fly ash-based cement mortar[J]. Constr. Build. Mater., 2024, 442: 137664  doi: 10.1016/j.conbuildmat.2024.137664

    19. [19]

      YANG Z Q, XIONG L F, FANG L, GAO Q, TIAN L P. Experiment on preparation of new filling cementitious material using sintering desulfurization ash and slag[J]. Nonferrous Metals Science and Engineering, 2015, 6(1): 8-12

    20. [20]

      HE W J, XIONG J, TANG Z L, WANG Y L, WANG X, XU H, ZHAO Z, LIU J, WEI Y C. Localized surface plasmon resonance effect of bismuth nanoparticles in Bi/TiO2 catalysts for boosting visible light-driven CO2 reduction to CH4[J]. Appl. Catal. B‒Environ., 2024, 344: 123651  doi: 10.1016/j.apcatb.2023.123651

    21. [21]

      FANG D, LIAO X, ZHANG X F, TENG A J, XUE X X. A novel resource utilization of the calcium-based semi-dry flue gas desulfurization ash: As a reductant to remove chromium and vanadium from vanadium industrial wastewater[J]. J. Hazard. Mater., 2018, 342: 436-445  doi: 10.1016/j.jhazmat.2017.08.060

    22. [22]

      CIZER Ö, RODRIGUEZ-NAVARRO C, RUIZ-AGUDO E, ELSEN J, VAN GEMERT D, VAN BALEN K. Phase and morphology evolution of calcium carbonate precipitated by carbonation of hydrated lime[J]. J. Mater. Sci., 2012, 47: 6151-6165  doi: 10.1007/s10853-012-6535-7

    23. [23]

      LUO X W, WU J H, ZHU G Q, HAN X Y, ZHAO J J, LI Y Q, LI Y Y, GU S P. Controllable preparation of TiO2/SiO2@blast furnace slag fiber composites based on solid waste carriers and study on mechanism of photocatalytic degradation of urban sewage[J]. Catalysts, 2025, 15: 755-755  doi: 10.3390/catal15080755

    24. [24]

      WANG K, LIU B D, LI J, LIU X Y, ZHOU Y, ZHANG X L, BI X G, JIANG X. In-situ Synthesis of TiO2 Nanostructures on Ti foil for enhanced and stable photocatalytic performance[J]. J. Mater. Sci. Technol., 2018, 35: 615-622

    25. [25]

      DENG G Q, KANG X D, YANG Y Q, WANG L Z, LIU G. Skin B/N-doped anatase TiO2 {001} nanoflakes for visible-light photocatalytic water oxidation[J]. J. Colloid Interface Sci., 2023, 649: 140-147  doi: 10.1016/j.jcis.2023.06.046

    26. [26]

      LIU L D, PENG F, ZHANG D D, LI M, HUANG J, LIU X Y. A tightly bonded reduced graphene oxide coating on magnesium alloy with photothermal effect for tumor therapy[J]. J. Magnes. Alloy., 2022, 10(11): 3031-3040  doi: 10.1016/j.jma.2021.03.003

    27. [27]

      DIEBOLD U. The surface science of titanium dioxide[J]. Surf. Sci. Rep., 2003, 48(5/6/7/8): 53-229

    28. [28]

      FOLEY B, METHIVIER C, MICHE A, GUIRA S, VALENTIN L, EL K, GUIBERT C LANDOULSI J. Unveiling the composition of hydroxyapatite minerals and their (bio)-organic adlayer using X-ray photoelectron spectroscopy[J]. Appl. Surf. Sci., 2024, 647: 158577  doi: 10.1016/j.apsusc.2023.158577

    29. [29]

      PCHELAROV G, UZUN D, VASSILEV S, RAZKAZOVA-VELKOVA E, DIMITROV O, TSANEV A, GIGOVA A, SHUKOVA N, PETROV K. Electrocatalysts based on novel carbon forms for the oxidation of sulphite[J]. Catalysts, 2022, 12(1): 93-112  doi: 10.3390/catal12010093

    30. [30]

      HU S Z, ZHANG W D, BAI J, LU G, ZHANG L, WU G. Construction of a 2D/2D g-C3N4/rGO hybrid heterojunction catalyst with outstanding charge separation ability and nitrogen photofixation performance via a surface protonation process[J]. RSC Adv., 2016, 6(31): 25695-25702  doi: 10.1039/C5RA28123G

    31. [31]

      NISHIKAWA H, IHARA T, KASUYA N, KOBAYASHI Y, TAKAHASHI S. Thermally-induced activation of titanium dioxide and its application to the oxidation of gaseous toluene[J]. Appl. Surf. Sci., 2019, 479: 1105-1109  doi: 10.1016/j.apsusc.2019.02.190

    32. [32]

      QI T Y, ZHANG J Z, LI T, AN S L, LI Q W, WANG L D. Facilitating calcium sulfite oxidation during flue-gas desulfurization for efficient sulfur utilization using a robust MnTiO3 perovskite[J]. Appl. Surf. Sci., 2024, 648: 158981  doi: 10.1016/j.apsusc.2023.158981

    33. [33]

      MA K H, DENG J Y, MA P S, SUN C F, ZHOU Q, XU J. A novel plant-internal route of recycling sulfur from the flue gas desulfurization (FGD) ash through sintering process: From lab-scale principles to industrial practices[J]. J. Environ. Chem. Eng., 2022, 10(1): 106957  doi: 10.1016/j.jece.2021.106957

    34. [34]

      LIU M F, ZHANG C Y, HU B, SUN Z M, XU Q H, WEN J, XIAO J, DONG Y H, GAN M, SUN W, ZHU J Y, CHEN D X. Enhancing flotation separation of chalcopyrite and galena by the surface synergism between sodium sulfite and sodium lignosulfonate[J]. Appl. Surf. Sci., 2020, 507: 145042  doi: 10.1016/j.apsusc.2019.145042

    35. [35]

      LI D Q, MENG Y J, LI J, SONG Y J, XU F. TiO2/carbonaceous nanocomposite from titanium‑alginate coordination compound[J]. Carbohydr. Polym., 2022, 288: 119400  doi: 10.1016/j.carbpol.2022.119400

    36. [36]

      XU K Q, ZHU W J, SAYED M, HAN S H. Design and preparation of 1D-based S-scheme photocatalysts[J]. Chin. J. Catal., 2026, 83: 24-53  doi: 10.1016/S1872-2067(26)64988-1

    37. [37]

      SING K S W, EVERETT D H, HAUL R A W, MOSCOU L, PIEROTTI R A, ROUQUEROL J, SIEMIENIEWSKA T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984)[J]. Pure Appl. Chem., 1985, 57(4): 603-619  doi: 10.1351/pac198557040603

    38. [38]

      LAZIC V, NEDELJKOVIC J M. Photocatalytic reactions over TiO2-based interfacial charge transfer complexes[J]. Catalysts, 2024, 14(11): 810  doi: 10.3390/catal14110810

    39. [39]

      WANG M Z, AFRIDI M N, MIAIO B J, LEE K H, WANG F Y, BAI J B, YASIR M. Preparation of a Co-MXene/CNT composite for enhanced photocatalytic degradation of methylene blue[J]. Molecules, 2026, 31(10): 1612  doi: 10.3390/molecules31101612

    40. [40]

      WANG D Q, SUN Z P, LU Z C, ZHANG T, YANG J B, JI Y L. Hydration characteristics and mechanism analysis of β-calcium sulfate hemihydrate based on low-field NMR[J]. J. Build. Eng., 2023, 80: 108077  doi: 10.1016/j.jobe.2023.108077

    41. [41]

      MAO Y P, ZHANG J Z, WU H, HUANG Y M, WANG X J, LI J W, SUN J, WANG W L. Preparation of architectural 3D printing material with a solid waste-derived sulfoaluminate matrix: A high-value conversion of solid waste[J]. Case Stud. Constr. Mater., 2023, 18: e01744

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