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Citation: Ziying YUAN, Zhen DUAN, Dan LIU, Jingrui NIU, Feiyan LAI, Xiaohui ZHANG, Guangchang YANG. Modification of O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 cathode material via Ti4+/P5+ dual-site co-doping[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(8): 1647-1657. doi: 10.11862/CJIC.20260041 shu

Modification of O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 cathode material via Ti4+/P5+ dual-site co-doping

  • College of Materials and Chemical Engineering, Hezhou University, Hezhou, Guangxi 542899, China

  • Corresponding author: Guangchang YANG, gcyang010101@163.com
  • Received Date: 6 February 2026
    Revised Date: 29 June 2026

Figures(6)

  • To address the issues of detrimental phase transition of the O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 (NFM) cathode material during cycling, a Ti4+/P5+ dual-site co-doping strategy was employed to enhance its structural stability. Na0.82Ni1/3Fe1/3Mn1/3Ti0.02P0.01O2 (NFMTP) was successfully synthesized via a combined sol-gel and high-temperature solid-state method. Electrochemical tests demonstrated that the NFMTP cathode exhibited a capacity retention of 80.1% after 200 cycles at 1C (160 mA·g-1), significantly higher than that of pristine NFM (45.4%). NFMTP still delivered a reversible capacity of 111.6 mAh·g-1 at 10C. Mechanistic investigations reveal that the synergistic effect of Ti occupying Na sites and P occupying tetrahedral interstitial sites in the transition metal (TM) layer effectively strengthens the TM—O bonds, suppresses harmful phase transitions, and accelerates Na+ diffusion, thereby collectively improving the overall electrochemical performance of the material.
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