Advanced Search

Citation: Ziying YUAN, Zhen DUAN, Dan LIU, Jingrui NIU, Feiyan LAI, Xiaohui ZHANG, Guangchang YANG. Modification of O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 cathode material via Ti4+/P5+ dual-site co-doping[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(8): 1647-1657. doi: 10.11862/CJIC.20260041 shu

Modification of O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 cathode material via Ti4+/P5+ dual-site co-doping

  • College of Materials and Chemical Engineering, Hezhou University, Hezhou, Guangxi 542899, China

  • Corresponding author: Guangchang YANG, gcyang010101@163.com
  • Received Date: 6 February 2026
    Revised Date: 29 June 2026

Figures(6)

  • To address the issues of detrimental phase transition of the O3-type Na0.86Ni1/3Fe1/3Mn1/3O2 (NFM) cathode material during cycling, a Ti4+/P5+ dual-site co-doping strategy was employed to enhance its structural stability. Na0.82Ni1/3Fe1/3Mn1/3Ti0.02P0.01O2 (NFMTP) was successfully synthesized via a combined sol-gel and high-temperature solid-state method. Electrochemical tests demonstrated that the NFMTP cathode exhibited a capacity retention of 80.1% after 200 cycles at 1C (160 mA·g-1), significantly higher than that of pristine NFM (45.4%). NFMTP still delivered a reversible capacity of 111.6 mAh·g-1 at 10C. Mechanistic investigations reveal that the synergistic effect of Ti occupying Na sites and P occupying tetrahedral interstitial sites in the transition metal (TM) layer effectively strengthens the TM—O bonds, suppresses harmful phase transitions, and accelerates Na+ diffusion, thereby collectively improving the overall electrochemical performance of the material.
  • 加载中
    1. [1]

      LI Z F, ZHU P. Optimization of interface and solid phase structure of Prussian blue analogue cathode for sodium ion battery[J]. Journal of Advances in Physical Chemistry, 2024, 13(4): 670-684

    2. [2]

      GU Z Y, GUO J Z, YANG Y, LÜ H Y, ZHAO X X, XI X T, HE X Y, WU X L. Controlled preparation and performance optimization of Na3V2(PO4)2O2F as cathode material for sodium ion batteries[J]. Chinese J. lnorg. Chem., 2018, 34(9): 1641-1648  doi: 10.11862/CJIC.2018.204

    3. [3]

      XU S, CHEN H, ZHANG X, ZHOU M, ZHOU H. Nasicon-type NaTi2(PO4)3 surface modified O3-type NaNi0.3Fe0.2Mn0.5O2 for high-performance cathode material for sodium-ion batteries[J]. ACS Appl. Mater. Interfaces, 2023, 15(40): 47764  doi: 10.1021/acsami.3c09876

    4. [4]

      XU M F, THAPLIYAL P, LAURIER J, TUCOULOU R, BURGHAMMER M, SEIDIMAYER S, BIANCHINI M. From P3 to P2: Synthesis and role of morphology in Li-substituted layered oxides for Na-ion batteries[J]. ACS Energy Lett., 2025, 10(12): 6347-6355  doi: 10.1021/acsenergylett.5c03108

    5. [5]

      XU W, DANG R, ZHOU L, YANG Y, LIN T, GUO Q B, XIE F, HU Z L, DING F X, LIU Y P, LIU Y, MAO H C, HONG J, ZUO Z C, WANG X Q, YANG R, JIN X, HOU X Y, LU Y X, RONG X H, XU N, HU Y S. Conversion of surface residual alkali to solid electrolyte to enable Na-ion full cells with robust interfaces[J]. Adv. Mater., 2023, 35(42): 2301314  doi: 10.1002/adma.202301314

    6. [6]

      ZHANG T, KONG J, SHEN C, CUI S J, LIN Z Z, DENG Y Y, SONG M H, JIAO L F, HUANG H T, JIN T, XIE K Y. Converting residual alkali into sodium compensation additive for high-energy Na-ion batteries[J]. ACS Energy Lett., 2023, 8(11): 4753-4761  doi: 10.1021/acsenergylett.3c02075

    7. [7]

      HUANG Z X, YANG T Q, CAO J M, ZHANG K Y, KIU Y, XIN B J, XU K, LIU Y, ZHOU X Y, GUO J Z, WANG T, GENG H B, WU X L. Multifunctional and radii-matched high-entropy engineering toward locally-regulable metal oxide layers in sodium-layered oxide cathode[J]. Angew. Chem. ‒Int. Edit., 2025, 64(33): e202505367  doi: 10.1002/anie.202505367

    8. [8]

      ZHANG H, GU Z Y, WANG X T, ZHAO X X, HENG Y L, LIU Y, YANG J L, ZHENG S H, WU X L. Electronic confinement-restrained Mn·Na anti-site defects in sodium-rich phosphates toward multi- electron transfer and high energy efficiency[J]. Adv. Mater., 2024, 36(47): 2410797  doi: 10.1002/adma.202410797

    9. [9]

      WANG X T, GU Z Y, CAO J M, ZHAO X X, LIU H H, ZHENG S H, HENG Y L, ZHANG K Y, HONG H X, WANG Z, ZENG R H, WU X L. Dual-loop upcycling of spent LiFePO4: Defect inheritance enables durable and fast-charging sodium-ion batteries[J]. Natl. Sci. Rev, 2025, 12(9): nwaf321  doi: 10.1093/nsr/nwaf321

    10. [10]

      DUAN Y, MA Z H, LI L L, SU G Q, BAO S, LU J L. Research on sodium storage performance of Cu and Mg doped P2 type layered oxide cathode materials[J]. J. Electrochem. Soc., 2025, 171(3): 030502

    11. [11]

      XUE H T, LIAN Z Y, LIU Y J, BAI P, LIU Y Y, LIU Q, QIU H R, ZHANG Y Q, HE W X. Synergistic Cu/Mg co-doping enables P2/O3 composite phase engineering for high-performance Fe/Mn-based sodium-ion battery cathodes[J]. J. Alloy. Compd., 2025, 1037: 182423  doi: 10.1016/j.jallcom.2025.182423

    12. [12]

      LIANG X H, SONG X S, SUN Y H, KIM H. High-energy and long-life O3-type layered cathode material for sodium-ion batteries[J]. Nat. Commun., 2025, 16(1): 3505  doi: 10.1038/s41467-025-58637-1

    13. [13]

      YAN J X, WANG Y H, ZHOU Q J, CHEN X, YANG H X, LI J T, XU X, YUAN Z F, ZUO P J. Improved anionic redox reversibility of layered oxides by modulating transition metal-oxygen bonds for sodium ion batteries[J]. J. Mater. Chem. A, 2025, 13(16): 11684-11693  doi: 10.1039/D5TA00231A

    14. [14]

      LI S W, LI Y X, ZHANG Z J, SHEN X, JI H X, LIU Z P, HU Z L, WANG H B, YU H, HU Z W, KONG Q Y, GAO Y R, WANG X F, YU R C, WANG Z X, CHEN L Q. Interplays between TM migration, cation mixing and oxygen defects and their impacts on degradation of layer‑structured oxide cathode materials[J]. Energy Storage Mater., 2025, 79: 104337  doi: 10.1016/j.ensm.2025.104337

    15. [15]

      LIU M T, GUAN Z K, ZHENG L, JING Q Q, CHEN S F, XU S W, HU L J, LIU X, ZHAO L F, XIAO B, WANG P F. Layered-to-rocksalt atomic reconfiguration on O3-type cathodes surface for high-energy and durable sodium-ion batteries[J]. Mater. Today, 2025, 89: 35-43  doi: 10.1016/j.mattod.2025.08.013

    16. [16]

      WU Y R, DANG Y Z, XIAO Z, ZHENG R G, SONG Z H, WANG Q C, MAO J, WANG D, LIU Y G, WANG Z Y. Mg anti-site occupation suppresses Fe migration in O3-type NaNi1/3Fe1/3Mn1/3O2 cathodes toward high-performance sodium-ion batteries[J]. Energy Storage Mater., 2025, 83: 104736  doi: 10.1016/j.ensm.2025.104736

    17. [17]

      YANG H F, LI W B, XU J T, LI Y T, LI M J, ZHANG J H, LUO Y Y, JIANG Q T, YANG L K, ZUO J X, SONG X X, WANG J J, LI X F. Coupled optimization of electronic and lattice structure for sodium storage stability in layered sodium vanadate cathodes[J]. Science, 2025, 6(4): 100512

    18. [18]

      LUO T, DING X, SUN H, DENG Z, LUO X, ZHANG L L, YANG X L. Influence of Co/Ca codoping induced interlayer structural regulation on sodium storage of P2-Mn-Fe-Cu-based oxide cathodes[J]. ACS Appl. Mater. Interfaces, 2025, 17(15): 22594-22603  doi: 10.1021/acsami.4c22684

    19. [19]

      ZHANG K, XU Z M, LI G D, LUO R J, MA C, WANG Y G, ZHOU Y N, XIA Y Y. Regulating phase transition and oxygen redox to achieve stable high-voltage O3-type cathode materials for sodium-Ion batteries[J]. Adv. Energy Mater., 2023, 13(45): 2302793  doi: 10.1002/aenm.202302793

    20. [20]

      MENG W, GUO H J, WANG Z X, LI G C, WU B C, WANG J X, PENG W J, LI X H, DUAN H, YAN G C. In situ formation of NaTi2(PO4)3 coating layers to enhance the high-temperature performance of NaNi1/3Fe1/3Mn1/3O2 cathode materials[J]. Mater. Horiz., 2025, 12(9): 3160-3170  doi: 10.1039/D4MH01766H

    21. [21]

      FENG S, ZHENG C J, SONG Z Y, WU X W, WU M F, XU F F, WEN Z Y. Boosting fast ionic transport and stability of O3‑ NaNi1/3Fe1/3Mn1/3O2 cathode via Al/Cu synergistically modulating microstructure for high-rate sodium-ion batteries[J]. Chem. Eng. J., 2023, 475: 146090  doi: 10.1016/j.cej.2023.146090

    22. [22]

      MENG W, GUO H J, WANG Z X, LI G C, WU B C, WANG J X, PENG W J, LI X H, DUAN H, YAN G C. In situ formation of NaTi2(PO4)3 coating layers to enhance the high-temperature performance of NaNi1/3Fe1/3Mn1/3O2 cathode materials[J]. Mater. Horiz., 2025, 12(9): 3160-3170  doi: 10.1039/D4MH01766H

    23. [23]

      XING H R, HU P, LI S L, ZUO Y G, HAN J Y, HUA X J, WANG K S, YANG F, FENG P F, CHANG T. Adsorption and diffusion of oxygen on metal surfaces tudied by first-principle study: A review[J]. J Mater. Sci. Technol., 2021, 62: 180-194  doi: 10.1016/j.jmst.2020.04.063

    24. [24]

      ZHAO Q H, PAN F. Disorder and spin-electron interaction in oxide cathodes[J]. Joule, 2024, 8(8): 2187-2189  doi: 10.1016/j.joule.2024.07.022

    25. [25]

      SHEVCHENKO V A, GLAZKOVA I S, NOVICHKOV D A, SKVORTSOVA I, SOBOLEV A V, ABAKUMOV A M, PRESNIAKOV I A, DROZHZHIN O A, ANTIPOV E V. Competition between the Ni and Fe redox in the O3-NaNi1/3Fe1/3Mn1/3O2 cathode material for Na-ion batteries[J]. Chem. Mater., 2023, 35(10): 4015-4025  doi: 10.1021/acs.chemmater.3c00338

    26. [26]

      HWANG J Y, MYUNG S T, AURBACH D, SUN Y K. Effect of nickel and iron on structural and electrochemical properties of O3 type layer cathode materials for sodium-ion batteries[J]. J. Power Sources, 2016, 324: 106-112  doi: 10.1016/j.jpowsour.2016.05.064

    27. [27]

      YU Y, NING D, LI Q Y, FRANZ A, ZHENG L R, ZHANG N A, REN G X, SCHUMACHER G, LIU X F. Revealing the anionic redox chemistry in O3-type layered oxide cathode for sodium-ion batteries[J]. Energy Storage Mater., 2021, 38: 130-140  doi: 10.1016/j.ensm.2021.03.004

    28. [28]

      YANG T T, HUANG Y L, ZHANG J, ZHU H, REN J C, LI T Y, GALLINGTON L C, LAN S, YANG L G, LIU Q. Insights into Ti doping for stabilizing the Na2/3Fe1/3Mn2/3O2 cathode in sodium ion battery[J]. J. Energy Chem., 2022, 73: 542-548  doi: 10.1016/j.jechem.2022.06.016

    29. [29]

      LIN F, ZHAO K J, LIU Y J. Heterogeneous reaction activities and statistical characteristics of particle cracking in battery electrodes[J]. ACS Energy Lett., 2021, 6(11): 4065-4070  doi: 10.1021/acsenergylett.1c02135

    30. [30]

      FANG L B, WANG C Y, HUANGFU L, BAHLAWANE N, TIAN H, LU Y H, PAN H G, YAN M, JIANG Y Z. Enabling full conversion reaction with high reversibility to approach theoretical capacity for sodium storage[J]. Adv. Funct. Mater., 2019, 29(46): 1906680  doi: 10.1002/adfm.201906680

    31. [31]

      JIANG Q T, LI M, LI J, WANG J J, ZHANG G N, WANG J, ZUO J X, CAO G Q, DUAN R X, HAO Y C, LI M J, YANG Z H, YANG H F, BAI M X, SONG X X, XI Y K, LI W B, SUN X L, LI X F. LiF-rich cathode electrolyte interphases homogenizing Li+ fluxes toward stable interface in Li-rich Mn-based cathodes[J]. Adv. Mater., 2025, 37(15): 2417620  doi: 10.1002/adma.202417620

    32. [32]

      LI J B, LI Z X, WANG R X, TANG S C, HAO J J, WANG C Y, PAN L K. The modified electrochemical performance of sodium vanadate phosphate through carbon coating and titanium doping[J]. Journal of Liaocheng University(Natural Science Edition), 2023, 36(2): 17-24, 52

  • 加载中
    1. [1]

      Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270

    2. [2]

      Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-0. doi: 10.3866/PKU.WHXB202406014

    3. [3]

      Li Peicai ,  Wang Xubin ,  Zhang Qinghua ,  Wang Bowen ,  Rong Xiaohui ,  Hu Yong-Sheng ,  Li Zhongtao . High-rate and long-cycling P2-type cathode material for sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(5): 100214-. doi: 10.1016/j.actphy.2025.100214

    4. [4]

      Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na3.5−xMn0.5V1.5−xZrx (PO4)3/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023

    5. [5]

      Zilin Hu , Yaoshen Niu , Xiaohui Rong , Yongsheng Hu . Suppression of Voltage Decay through Ni3+ Barrier in Anionic-Redox Active Cathode for Na-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306005-0. doi: 10.3866/PKU.WHXB202306005

    6. [6]

      Rongzhan LOU , Qiaoling KANG , Zhenchao BAI , Dongyun LI , Yang XU , Rui WANG , Qingyi LU . Research progress of sodium ion high entropy layered oxide cathode. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2411-2428. doi: 10.11862/CJIC.20250142

    7. [7]

      Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085

    8. [8]

      Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    9. [9]

      Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . Recent Advances in Iron-based Heterostructure Anode Materials for Sodium Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(3): 100022-0. doi: 10.3866/PKU.WHXB202311015

    10. [10]

      Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO2 with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

    11. [11]

      Wang Shuang ,  Fu Xiaoqi ,  Yao Shanshan . Synergistic optimization of ion migration and electron transfer in sodium-ion battery cathode materials. Acta Physico-Chimica Sinica, 2026, 42(5): 100206-. doi: 10.1016/j.actphy.2025.100206

    12. [12]

      Shan Zhao , Xu Liu , Haotian Guo , Zonglin Liu , Pengfei Wang , Jie Shu , Tingfeng Yi . Synergistic design of high-entropy P2/O3 biphasic cathodes for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2026, 42(1): 100129-0. doi: 10.1016/j.actphy.2025.100129

    13. [13]

      Wenhui Li , Yakun Tang , Yusheng Zhou , Yue Zhang , Wenhai Zhang , Qingtao Ma , Lang Liu , Sen Dong , Yuliang Cao . Enhanced sodium storage performance of asphalt-derived hard carbon through intramolecular oxidation for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(10): 100119-0. doi: 10.1016/j.actphy.2025.100119

    14. [14]

      Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS2 nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339

    15. [15]

      Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb12WO33 Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040

    16. [16]

      Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe0.95S1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006

    17. [17]

      Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363

    18. [18]

      Huiwei Ding , Bo Peng , Zhihao Wang , Qiaofeng Han . Advances in Metal or Nonmetal Modification of Bismuth-Based Photocatalysts. Acta Physico-Chimica Sinica, 2024, 40(4): 2305048-0. doi: 10.3866/PKU.WHXB202305048

    19. [19]

      Débora Ferreira dos Santos Morais , José Luis Tirado , Carlos Pérez-Vicente , Fabiana Villela da Motta , Pedro Lavela , Mauricio Bomio , Sergio Lavela . Unlocking the performance of sodium-ion batteries by coating Na3V2(PO4)3 with Nb2O5. Acta Physico-Chimica Sinica, 2026, 42(2): 100180-0. doi: 10.1016/j.actphy.2025.100180

    20. [20]

      Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

Get Citation
PDF
XML
Metrics
  • PDF Downloads(0)
  • Abstract views(13)
  • HTML views(2)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return