Citation: Xiaoyu CHEN, Fei DOU, Juan AN, Mingyuan PANG, Min YANG, Haohao ZHANG, Laixin HONG, Zhen KONG, Kongming HU, Yaqing HU, Huan PANG. MOF-based materials for fast charging batteries: Mechanistic insights, application advances, and future perspectives[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(9): 1816-1844. doi: 10.11862/CJIC.20250383 shu

MOF-based materials for fast charging batteries: Mechanistic insights, application advances, and future perspectives

Xiaoyu CHEN ^{1, #} ,
Fei DOU ^{2, #} ,
Juan AN ¹ ,
Mingyuan PANG ¹ ,
Min YANG ¹ ,
Haohao ZHANG ^1,, ,
Laixin HONG ¹ ,
Zhen KONG ^1,, ,
Kongming HU ² ,
Yaqing HU ² ,
Huan PANG ^3,,

1.
College of Biological and Chemical Engineering, Qilu Institute of Technology, Jinan 250200, China
2.
School of Automotive Engineering, Anhui Yangtse Vocational and Technical College, Wuhu, Anhui 241080, China
3.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225009, China

Corresponding author: Haohao ZHANG, haonier2@163.com Zhen KONG, kz577718484@163.com Huan PANG, panghuan@yzu.edu.cn
Received Date: 29 December 2025
Revised Date: 23 March 2026

Figures(16)

In the context of the global energy transition, lithium-ion batteries have emerged as the predominant energy storage technology. However, their fast-charging capabilities continue to be limited by challenges such as lithium dendrite formation, electrode volume expansion, and interfacial instability. Metal-organic frameworks (MOFs) offer promising opportunities to improve battery performance owing to their high specific surface area, tunable pore architectures, and abundant redox-active sites. Their ordered porous structure not only promotes efficient ion transport and electrolyte penetration but also enables the incorporation of numerous active sites through precise structural design. This review systematically outlines recent progress in the use of MOFs and their derivatives for fast-charging lithium-ion batteries, with a focus on their applications in electrode materials and critical battery components, as well as the associated enhancement mechanisms. It aims to provide guidance for the design and development of high-performance MOF-based materials for fast-charging batteries.
- metal-organic frameworks,
- lithium-ion batteries,
- fast-charging,
- electrode materials
1. [1]
  HOLECHEK J L, GELI H M E, SAWALHAH M N, VALDEZ R. A global assessment: can renewable energy replace fossil fuels by 2050?[J]. Sustainability, 2022, 14(8): 4792 doi: 10.3390/su14084792
2. [2]
  YANG M, PANG M Y, ZHANG H H, AN J, WANG Z F, YE J J, KONG Z, DU Y Y, QU J Y, LI C X, SONG J B. Synthesis strategies, characterization techniques, and prospects of defect-engineered single-atom catalysts for electrocatalysis[J]. Fuel, 2026, 407: 137384 doi: 10.1016/j.fuel.2025.137384
3. [3]
  LV T T, ZHU G Y, DONG S Y, KONG Q Q, PENG Y, JIANG S, ZHANG G X, YANG Z L, YANG S Y, DONG X C, PANG H, ZHANG Y Z. Co-intercalation of dual charge carriers in metal-ion-confining layered vanadium oxide nanobelts for aqueous zinc-ion batteries[J]. Angew. Chem.‒Int. Edit., 2023, 62(5): e202216089 doi: 10.1002/anie.202216089
4. [4]
  WILLIAMS J H, DEBENEDICTIS A, GHANADAN R, MAHONE A, MOORE J, MORROW W R, PRICE S, TORN M S. The technology path to deep greenhouse gas emissions cuts by 2050: The pivotal role of electricity[J]. Science, 2012, 335(6064): 53-59 doi: 10.1126/science.1208365
5. [5]
  AN J, ZHANG H H, WANG Y J, KONG Z, LI W S, GAO X, SONG J B, YAO Y C. Application and prospects of interface engineering in energy storage and conversion of graphdiyne-based materials[J]. EcoEnergy, 2025, 3(1): 77-104 doi: 10.1002/ece2.76
6. [6]
  LIU C L, BAI Y, LI W T, YANG F Y, ZHANG G, X, PANG H. In situ growth of three-dimensional MXene/metal-organic framework composites for high-performance supercapacitors[J]. Angew. Chem.‒Int. Edit., 2022, 61(11): e202116282 doi: 10.1002/anie.202116282
7. [7]
  CHEN T T, WANG F F, CAO S, BAI Y, ZHENG S S, LI W T, ZHANG S T, HU S X, PANG H. In situ synthesis of MOF-74 family for high areal energy density of aqueous nickel-zinc batteries[J]. Adv. Mater., 2022, 34(30): 2201779 doi: 10.1002/adma.202201779
8. [8]
  BAI Y, LIU C L, CHEN T T, LI W T, ZHENG S S, PI Y C, LUO Y S, PANG H. MXene-copper/ccobalt hhybrids via Lewis acidic molten salts etching for high performance symmetric supercapacitors[J]. Angew. Chem.‒Int. Edit., 2021, 60(48): 25318-25322 doi: 10.1002/anie.202112381
9. [9]
  LIN S N, ZHANG T G. NiCo-MOFs porous nanomaterials prepared by different organic frameworks as anodes for Li-ion batteries[J]. J. Energy Storage, 2023, 72: 108492 doi: 10.1016/j.est.2023.108492
10. [10]
  CHENG H, SHAPTER J G, LI Y Y, GAO G. Recent progress of advanced anode materials of lithium-ion batteries[J]. J. Energy Chem., 2021, 57: 451-468 doi: 10.1016/j.jechem.2020.08.056
11. [11]
  GENG J R, NI Y X, ZHU Z, WU Q, GAO S N, HUA W B, INDRIS S, CHEN J, LI F. Reversible metal and ligand redox chemistry in two-dimensional iron-organic framework for sustainable lithium-ion batteries[J]. J. Am. Chem. Soc., 2023, 145(3): 1564-1571 doi: 10.1021/jacs.2c08273
12. [12]
  WANG R, WANG L, LIU R, LI, X Y, WU Y Z, RAN F. "Fast-charging" anode materials for lithium-ion batteries from perspective of ion diffusion in crystal structure[J]. ACS Nano, 2024, 18(4): 2611-2648 doi: 10.1021/acsnano.3c08712
13. [13]
  ZHAO F S, WANG J, JIANG T Y, SI Y L, ZHU X Y, ZHANG S T, LI K, MENG W J, ZHANG H M, CAO G P, MING H, ZHANG W F, QIU J Y. Internal resistance reduction strategies for high-power and fast-charging lithium-ion batteries[J]. Mater. Sci. Eng. R‒Rep., 2025, 166: 101076 doi: 10.1016/j.mser.2025.101076
14. [14]
  LI J W, GUO C Y, TAO L J, MENG J S, XU X M, LIU F, WANG X P. Electrode and electrolyte design strategies toward fast-charging lithium-ion batteries[J]. Adv. Funct. Mater., 2024, 34(49): 2409097 doi: 10.1002/adfm.202409097
15. [15]
  ZENG Q H, DONG Y T, CHEN Y M, YUE X Y, LIANG Z. Recent advancements and perspectives of fast-charging composite anodes for lithium-ion batteries[J]. Sci. China Chem., 2024, 67(12): 3952-3963 doi: 10.1007/s11426-024-2265-9
16. [16]
  WANG R, LI Y, LI G Y, FU Y H, WU Y Z, RAN F. "Fast-charging" mechanism of Li₃VO₄ from the perspective of material science for lithium-ion battery[J]. Chem. Eng. J., 2024, 498: 155371 doi: 10.1016/j.cej.2024.155371
17. [17]
  KANG S, MA G, LIU Y X, WANG D M, ZHANG Y, LI J J, XU C, LI Y F. Progress in fast-charging graphite anodes for lithium-ion batteries: reaction kinetics[J]. Energy Storage Mater., 2025, 81: 104531 doi: 10.1016/j.ensm.2025.104531
18. [18]
  ZHU X T, CAO B, YAN C, TANG C, CHEN A B, ZHANG Q. Advances in coating strategies for graphite anodes in lithium-ion batteries[J]. Acta Phys.‒Chim. Sin., 2025, 41(9): 100096 doi: 10.1016/j.actphy.2025.100096
19. [19]
  DONG Y, LIU C, RUI M X, ZHANG X Y, GUAN Y B, CHEN L, HUANG Q, WANG M, SU Y F, WU F, LI N. Review on graphite anodes for fast-charging lithium-ion batteries: Mechanism, modification and characterizations[J]. Adv. Funct. Mater., 2025, 35(45): 2506190 doi: 10.1002/adfm.202506190
20. [20]
  MA D, KIM D H, YU M CHO Y E, KIM H S. Porous silicon layer overlaid graphite anode materials for fast-charging of lithium-ion batteries[J]. J. Power Sources, 2025, 645: 237199 doi: 10.1016/j.jpowsour.2025.237199
21. [21]
  ZHAO H L, ZUO H B, WANG J X, JIAO S Q. Practical application of graphite in lithium-ion batteries: Modification, composite, and sustainable recycling[J]. J. Energy Storage, 2024, 98: 113125 doi: 10.1016/j.est.2024.113125
22. [22]
  MATSUO Y, FUMITA K, FUKUTSUKA T, SUGIE Y, KOYAMA H, INOUE K. Butyrolactone derivatives as electrolyte additives for lithium-ion batteries with graphite anodes[J]. J. Power Sources, 2003, 119-121: 373-377 doi: 10.1016/S0378-7753(03)00271-4
23. [23]
  QUAN Z H, LU A B, WANG F, LIU Z D, WANG S, ZHOU Y D, ZHANG C Z, YE C, LIU J S, TAN J. Soft carbon filled in expanded graphite layer pores for superior fast-charging lithium-ion batteries[J]. Carbon, 2024, 229: 119500 doi: 10.1016/j.carbon.2024.119500
24. [24]
  ZHANG H H, PANG M Y, YANG M, KONG Z, YE J J, SUN C Y, HE W, LI W S, PAK Y L, AN J, GAO X, SONG J B. Constructing three-dimensional porous SnS₂/RGO as superior-rate and long-life anodes for lithium-ion batteries[J]. Langmuir, 2025, 41(1): 876-884 doi: 10.1021/acs.langmuir.4c04214
25. [25]
  ZHENG S S, SUN Y, XUE H G, BRAUNSTEIN P, HUANG W, PANG H. Dual-ligand and hard-soft-acid-base strategies to optimize metal-organic framework nanocrystals for stable electrochemical cycling performance[J]. Natl. Sci Rev., 2022, 9(7): nwab197 doi: 10.1093/nsr/nwab197
26. [26]
  TANG J Y, WANG D H, QIN W, FANG S Y, XU T, HUANG J M, TANG M, WANG Z B. In-situ solvent-free preparation of MOF/polymer composite electrolytes with highly dispersed and defected MOF nanoparticles for lithium-metal batteries[J]. Chem. Eng. J., 2025, 513: 163082 doi: 10.1016/j.cej.2025.163082
27. [27]
  NIU Y W, WANG Y H, ZHANG H J. MOF in catalysis, sensing and energy storage applications[J]. Nano Energy, 2026, 147: 111598 doi: 10.1016/j.nanoen.2025.111598
28. [28]
  ZHENG H Q, ZHANG Y N, LIU L F, WAN W, GUO P, NYSTRÖM A M, ZOU X D. One-pot synthesis of metal-organic frameworks with encapsulated target molecules and their applications for controlled drug delivery[J]. J. Am. Chem. Soc., 2016, 138(3): 962-968 doi: 10.1021/jacs.5b11720
29. [29]
  TEPLENSKY M H, FANTHAM M, POUDEL C, HOCKINGS C, LU M, GUNA A, ARAGONES-ANGLADA M, MOGHADAM P Z, LI P, FARHA O K, FERNÁNDEZ S B D, RICHARDS F M, JODRELL D I, SCHIERLE G K, KAMINSKI C F, FAIREN-JIMENEZ D. A highly porous metal-organic framework system to deliver payloads for gene knockdown[J]. Chem, 2019, 5(11): 2926-2941 doi: 10.1016/j.chempr.2019.08.015
30. [30]
  HOU C C, XU Q. Metal-organic frameworks for energy[J]. Adv. Energy Mater., 2019, 9(23): 1801307 doi: 10.1002/aenm.201801307
31. [31]
  LI Z Q, GE X L, LI C X, DONG S H, TANG R, WANG C X, ZHANG Z W, YIN L W. Rational microstructure design on metal-organic framework composites for better electrochemical performances: Design principle, synthetic strategy, and promotion mechanism[J]. Small Methods, 2020, 4(3): 1900756 doi: 10.1002/smtd.201900756
32. [32]
  YANG H Z, LI X K, TIAN L Y, LIU J G, LI Z S, WANG Y, ZOU, Z G. Boosting photocatalytic performance of MOF-on-MOF heterostructures by constructing rigid charge channels[J]. Small, 2025, 22(2): e10060
33. [33]
  JIANG H Q, LIU X C, WU Y S, SHU Y F, GONG X, KE F S, DENG H X. Metal-organic frameworks for high charge-discharge rates in lithium-sulfur batteries[J]. Angew. Chem.‒Int. Edit. 2018, 57(15): 3916-3921 doi: 10.1002/anie.201712872
34. [34]
  SAMMAWIPAWEKUL N, KAEOSAMUT N, AUTTHAWONG T, WATWIANGKHAM A, SUTHIRAKUN S, WANNAPAIBOON S, MAHAMAI N, SARAKONSRI T, CHIMUPALA Y, YIMKLAN S. Isostructural dual-ligand-based MOFs with different metal centers in response to diverse capacity lithium-ion battery anode[J]. Chem. Eng. J., 2024, 482: 148904 doi: 10.1016/j.cej.2024.148904
35. [35]
  HU Q, HAN G G, WANG A P, GAO K D, LIAO J Y, DING M L, ZHOU Y C, DOMINKO R, WANG H T, YAO J F. Functionalized MOF enables stable cycling of nickel-rich layered oxides for lithium-ion batteries[J]. Chem. Eng. J. 2024, 497: 154608 doi: 10.1016/j.cej.2024.154608
36. [36]
  MWIZERWA J P, LI J, NSENGIYUMVA W, LI C, XU K, RASAKI S A, LIU C. Thick 3D-printed hierarchical Li₄Ti₅O₁₂@MOF anode and grid-lined micropores for high-performance lithium-ion batteries[J]. J. Colloid Interface Sci., 2025, 696: 137883 doi: 10.1016/j.jcis.2025.137883
37. [37]
  LIU M W, LI A, LIN H A, LI Z J, WANG L, DENG Y R, WANG Y F, LIU R P, HE X M. Architectural engineering of metal-organic frameworks in lithium-ion batteries: Multifunctional roles, challenges, and future perspectives[J]. Nano Energy, 2025, 143: 111310 doi: 10.1016/j.nanoen.2025.111310
38. [38]
  YANG J C, LIU Q, SONG Z X, LIU Z H, WANG K H, HAO J H, WANG X, XU L F, WANG Z Z, SHEN B X. Research progress in the application of metal-organic framework materials as anodes for lithium-ion batteries[J]. Coord. Chem. Rev. 2026, 549: 217343 doi: 10.1016/j.ccr.2025.217343
39. [39]
  LUO B Q, WANG Z R, ZHU X T, LI J Y, YANG H X, GUO B, WANG K. Linker fluorinated metal-organic frameworks enhancing ion conduction for fast-charging lithium metal batteries[J]. J. Energy Chem., 2026, 113: 749-760 doi: 10.1016/j.jechem.2025.09.063
40. [40]
  LI L C, JIANG G S, WANG K, YANG A P, CAO T F, KONG O, LI J J, ZHU J P, ZHENG J G, SUN C G, LI L X, XU F, AN B G. Engineering electronic inductive effect of linker in metal-organic framework glass toward fast-charging and stable-cycling quasi-solid-state lithium metal batteries[J]. Adv. Funct. Mater., 2025, 35(46): 2505700 doi: 10.1002/adfm.202505700
41. [41]
  WANG Z R, XU Z, MU Y B, SLATER B, LI J Y, ZENG L, GUO B, WANG K. Defect-tailoring metal-organic frameworks for highly fast-charging quasi-solid-state electrolytes lithium metal batteries[J]. ACS Appl. Mater. Interfaces, 2025, 17(17): 25223-25236 doi: 10.1021/acsami.4c22902
42. [42]
  CHENG L, ZHANG Y X, LI D D, LI R, OUYANG H, HE H G, CHEN S, ZHENG S Y, LI H. Cu-MOF functionalized hydroxyapatite/bacterial cellulose composite separator enabling dendrite-free fast charging and enhanced thermal safety for high-loading graphite anode[J]. Adv. Funct. Mater., 2025, 36(3): e15523
43. [43]
  XIANG J H, LI M J, LI M R, HUANG L Z, LIU S C, LIANG J H, DU L, CUI Z M, SONG H Y, LIANG Z X. Durable 4.5 V sodium metal batteries stabilized by negatively charged metal-organic frameworks in gel polymer electrolyte[J]. J. Energy Chem., 2025, 111: 886-895 doi: 10.1016/j.jechem.2025.07.089
44. [44]
  MA Y T, QIU Y, YANG K, LV S, LI Y H, AN X F, XIAO G Y, HAN Z, MA Y T, CHEN L K, ZHANG D F, LV W, TIAN Y, HOU T Z, LIU M, ZHOU Z, KANG F Y, HE Y B. Competitive Li-ion coordination for constructing a three-dimensional transport network to achieve ultra-high ionic conductivity of a composite solid-state electrolyte[J]. Energy Environ. Sci., 2024, 17(21): 8274-8283 doi: 10.1039/D4EE03134B
45. [45]
  XU Z, WANG Z R, LI J Y, ZHU X T, REN H X, GUO B, WANG K. Engineering 3D lattice oxygen metal-organic frameworks for fast-charging quasi-solid-state lithium metal batteries[J]. Small, 2025, 21(29): 2501103 doi: 10.1002/smll.202501103
46. [46]
  YANG Z H, WENG C C, GAO X Y, MENG F Y, JI Y Y, LI J B, LU T, LI J L, WANG J C, PAN L K. In situ construction of Sn-based metal-organic frameworks on MXene achieving fast electron transfer for rapid lithium storage[J]. Chem. Eng. J., 2024, 486: 150299 doi: 10.1016/j.cej.2024.150299
47. [47]
  HAN X, WU T T, GU L H, CHEN M F, SONG J Z, TIAN D, CHEN J Z. Li-MOF-based ions regulator enabling fast-charging and dendrite-free lithium metal anode[J]. Chin. Chem. Lett., 2023, 34(2): 107594 doi: 10.1016/j.cclet.2022.06.017
48. [48]
  XU L Q, XIAO X H, TU H Y, ZHU F J, WANG J, LIU H X, HUANG W Y, DENG W T, HOU H S, LIU T C, JI X B, AMINE K, ZOU G Q. Engineering functionalized 2D metal-organic frameworks nanosheets with fast Li⁺ conduction for advanced solid Li batteries[J]. Adv. Mater., 2023, 35(38): 2303193 doi: 10.1002/adma.202303193
49. [49]
  ZHANG Y J, SUN S, WANG M, LUO X, JIA Z H, PENG J Y, CONG S Z, HE T, PANG H. Rationally engineered metal-organic framework membrane structure for effective Mg²⁺/Li⁺ separation[J]. Chem. Eng. J., 2025, 525: 170104 doi: 10.1016/j.cej.2025.170104
50. [50]
  ZHAO X D, ZHANG X Y, XING X X, BIAN F L, GAO X L, LIU B S, SONG S F, ZHANG Y Z, HUANG H L. Constructing angstrom-level ion pocket array in 1D channel wall for efficient lithium ion sieving[J]. Adv. Funct. Mater., 2025, 35(10): 2416628 doi: 10.1002/adfm.202416628
51. [51]
  CAO H Y, XIA Y, LU Y Q, WU Y L, XIA Y S, HOU X X, WANG Y X, LIU G P, HUANG K, XU Z. MOF-801 polycrystalline membrane with sub-10 nm polymeric assembly layer for ion sieving and flow battery storage[J]. AIChE J., 2022, 68(6): e17657 doi: 10.1002/aic.17657
52. [52]
  YAO B, HUSSAIN S, YE Z Z, PENG X S. Electrodeposited MOFs membrane with in situ incorporation of charged molecules for osmotic energy harvesting[J]. Small, 2023, 19(18): 2207559 doi: 10.1002/smll.202207559
53. [53]
  LIU Y C, LI Y, FU X, XUE Z A, WANG J J. Lithium dendrite growth, evolution, inhibition in lithium-ion batteries[J]. J. Energy Storage, 2025, 138: 118559 doi: 10.1016/j.est.2025.118559
54. [54]
  LI J Y, MEI B A, FENG H H, ZUO Z X, XIONG R. Lithium dendrite deposition kinetics and its dynamic impact on capacity fading of lithium-ion batteries[J]. J. Power Sources, 2025, 654: 237753 doi: 10.1016/j.jpowsour.2025.237753
55. [55]
  XU Y J, WANG B, WAN Y, SUN Y, WANG W L, SUN K, YANG L J, HU H, WU M B. Understanding the process of lithium deposition on a graphite anode for better lithium-ion batteries[J]. New Carbon Mater., 2023, 38(4): 678-693 doi: 10.1016/S1872-5805(23)60747-4
56. [56]
  YANG L Y, CAO J H, LIANG W H, WANG Y K, WU D Y. Effects of the separator MOF-Al₂O₃ coating on battery rate performance and solid-electrolyte interphase formation[J]. ACS Appl. Mater. Interfaces, 2022, 14(11): 13722-13732 doi: 10.1021/acsami.2c00390
57. [57]
  XU Y, ZHANG D N, ZHANG S B, BAI L S, LIU Y, ZHAO J W, CHANG Z, ZHOU H S. Accelerating lithium-ion pre-desolvation and transport via glassy MOF for fast-charging and high-energy-density lithium-ion batteries[J]. Natl. Sci Rev., 2025, 12(11): nwaf349 doi: 10.1093/nsr/nwaf349
58. [58]
  ZHU M Q, HAN D Y, CAI C Y, ZHONG J Y, WENG J Z, TANG C G, GAO F, ZHANG J D. Two-dimensional MXene/MOFs heterojunction nanosheets as confinement hosts for dendrite-free lithium metal anodes[J]. Carbon, 2024, 227: 119248 doi: 10.1016/j.carbon.2024.119248
59. [59]
  XU M, LIANG S T, SHI H T, MIAO J P, TIAN F, CUI W H, SHAO R Q, XU Z W. High-strength MOF-based polymer electrolytes with uniform ionic flow for lithium dendrite suppression[J]. Small, 2024, 20(46): 2406007 doi: 10.1002/smll.202406007
60. [60]
  SONG C, HAN S H, MOON H, CHOI N S. Unlocking fast-charging capabilities of lithium-ion batteries through liquid electrolyte engineering[J]. EcoMat, 2024, 6(7): e12476 doi: 10.1002/eom2.12476
61. [61]
  WANG M X, TONG L J, LV S W, LI M X, ZHAO J Y, LI X, LI C P, CHEN X C, WU J X, LI X Y, CHEN Q H, CHEN Y M. In situ-engineered MOF/polymer hybrid electrolyte with 3D continuous ion channels for high-voltage and thermal-resistant lithium metal batteries[J]. Interd. Mater., 2025, 4(5): 763-774
62. [62]
  NIU X Y, JU C J, XU D, WANG T T, FU N, YANG Z L. Fluorine-rich MOFs-based composite solid electrolytes realizing fast Li⁺ transportation kinetics and dendrite-free interface[J]. Chem. Eng. J., 2025, 519: 165463 doi: 10.1016/j.cej.2025.165463
63. [63]
  ZHANG X X, SU Q M, ZHANG F, LV Y J, SHI W H, WANG L M, HUANG W H, ZHANG J, ZHAO W Q, ZHANG M, DING S K, DU G H, XU B S. Realizing high-flux Li⁺ conduction and stable solid electrolyte interface by iodine- and amino-functionalized MOFs doping in solid-state electrolytes[J]. Chem. Eng. J., 2024, 500: 157242 doi: 10.1016/j.cej.2024.157242
64. [64]
  DONG P P, ZHANG X H, HISCOX W, LIU J J, ZAMORA J, LI X Y, SU M Q, ZHANG Q, GUO X F, MCCLOY J, SONG M K. Toward high-performance metal-organic-framework-based quasi-solid-state electrolytes: Tunable structures and electrochemical properties[J]. Adv. Mater., 2023, 35(32): 2211841 doi: 10.1002/adma.202211841
65. [65]
  YANG L Y, CAO J H, CAI B R, LIANG T, WU D Y. Electrospun MOF/PAN composite separator with superior electrochemical performances for high energy density lithium batteries[J]. Electrochim. Acta, 2021, 382: 138346 doi: 10.1016/j.electacta.2021.138346
66. [66]
  LAN F F, ZHAO H J, JIANG Y, JIN C C, ZHAO G D, LI L. A thermomechanically stable nanofiber separator with multiscale MOF networks towards high-efficiency ion transport[J]. J. Mater. Chem. A, 2025, 13(10): 7357-7370 doi: 10.1039/D4TA07790C
67. [67]
  REN Z P, CONG B, XU F, OUYANG S, ZHAO J H, YANG H J, GUO S, WU D, DUAN X, ZHANG X M. Construction of excellent solid-state electrolyte by incorporating Li-IL into open-pore MOF/polymer-based materials[J]. Mater. Chem. Front., 2024, 8(19): 3166-3174 doi: 10.1039/D4QM00436A
68. [68]
  HAN G M, HU Q, XIA Y, GAO K D, WANG Y, YAO J F. Stabilizing dendrite-free lithium metal batteries via an anionphilic ZIF-67 modified separator[J]. J. Alloy. Compd., 2025, 1036: 181713 doi: 10.1016/j.jallcom.2025.181713
69. [69]
  RUAN H, ZHANG L F, LI S, WANG K, HUANG W H, GUO S W. Carbon polyhedra encapsulated Si derived from Co-Mo bimetal MOFs as anode materials for lithium-ion batteries[J]. J. Mater. Sci. Technol., 2023, 159: 91-98 doi: 10.1016/j.jmst.2023.03.009
70. [70]
  JIANG S, LV T T, PENG Y, PANG H. MOFs containing solid-state electrolytes for batteries[J]. Adv. Sci., 2023, 10(10): 2206887 doi: 10.1002/advs.202206887
71. [71]
  KONG W Q, ZHAO L Z, GUO J C, ZHU H Y, LI W R, HAN X, LIU S, YU W H, CUI L Y, WEN Z S. Phosphorus decorated MOF-derived microflower-like carbon as a superior anode for lithium-ion batteries[J]. Carbon, 2023, 215: 118439 doi: 10.1016/j.carbon.2023.118439
72. [72]
  KITCHAMSETTI N, NARSIMULU D, PAYYAVULA S, CHAKRA C S, DE BARROS A L F. V-MOF derived porous nanorods comprising polydopamine-derived C coated VN quantum dots composited with graphitic C as electrodes for long-lasting and high-rate lithium-ion batteries and hybrid supercapacitors[J]. J. Energy Storage, 2025, 109: 115144 doi: 10.1016/j.est.2024.115144
73. [73]
  KONG O, JIANG G S, WANG K, YANG A P, ZHENG J G, WU S, HAN W C, LI J J, LI L C, AN X L, WANG J, SUN C G, LI L X, XU F, AN B G. Elucidation of Li⁺ conduction behavior in MOF glass electrolyte toward long-cycling and high C-rate lithium metal batteries[J]. Adv. Energy Mater., 2025, 15(22): 2405593 doi: 10.1002/aenm.202405593
74. [74]
  GUO C F, XIE Y, PAN K, LI L. MOF-derived hollow SiO_x nanoparticles wrapped in 3D porous nitrogen-doped graphene aerogel and their superior performance as the anode for lithium-ion batteries[J]. Nanoscale, 2020, 12(24): 13017-13027 doi: 10.1039/D0NR02453H
75. [75]
  LI Z A, WANG S G, CHEN P P, LEI J T, HOU Y L, CHEN J Z, ZHAO D L. Interface engineering of MOF-derived Co₃O₄@CNT and CoS₂@CNT anodes with long cycle life and high-rate properties in lithium/sodium-ion batteries[J]. ACS Appl. Mater. Interfaces, 2024, 16(15): 19730-19741 doi: 10.1021/acsami.3c19361
76. [76]
  YANILMAZ M, ATIK A, TOSUN M, ZHANG X W. MOF@nanofiber separators for lithium-ion batteries[J]. J. Appl. Polym. Sci., 2025, 142(10): e56562 doi: 10.1002/app.56562
77. [77]
  WANG G X, HE P G, FAN L Z. Asymmetric polymer electrolyte constructed by metal-organic framework for solid-state, dendrite-free lithium metal battery[J]. Adv. Funct. Mater., 2021, 31(3): 2007198 doi: 10.1002/adfm.202007198
78. [78]
  WANG P, SHEN M Q, ZHOU H, MENG C F, YUAN A H. MOF-derived CuS@Cu-BTC composites as high-performance anodes for lithium-ion batteries[J]. Small, 2019, 15(47): 1903522 doi: 10.1002/smll.201903522
79. [79]
  ZHANG C L, LI H, ZHANG Q, CAO F H, XIE Y, LU B R, ZHANG W D, CONG H P, LI H. Core-shell structured porous carbon nanofibers integrated with ultra-small SnO₂ nanocrystals for fast and stable lithium storage[J]. Chem. Eng. J., 2021, 420: 127705 doi: 10.1016/j.cej.2020.127705
80. [80]
  LI J S, XU N N, HAN Q, ZHU L M, CAO X Y. Spherical NiCo₂S₄ wrapped with nitrogen-doped carbon as ultra-fast/high lithium storage materials[J]. J. Alloy. Compd., 2022, 927: 167067 doi: 10.1016/j.jallcom.2022.167067
81. [81]
  ZHENG G J, XING Z, GAO X R, NIE C H, XU Z H, JU Z C. Fabrication of 2D Cu-BDC MOF and its derived porous carbon as anode material for high-performance Li/K-ion batteries[J]. Appl. Surf. Sci., 2021, 559: 149701 doi: 10.1016/j.apsusc.2021.149701
82. [82]
  GABER S, MOHAMMED A K, JAVAREGOWDA B H, MARTÍNEZ J I, SÁNCHEZ P P, GÁNDARA F, KRISHNAMOORTHY K, SHETTY D. MOFite: A high-density lithiophilic and scalable metal-organic framework anode for rechargeable lithium-ion battery[J]. Angew. Chem.‒Int. Edit., 2024, 63(44): e202409256 doi: 10.1002/anie.202409256
83. [83]
  SU L H, CHEN J, ZHOU J Z, LIU J J, HU Z L, LI S, HU X B, XU L L, ZHANG L. Co-based metal-organic frameworks with dual redox active centers for lithium-ion batteries with high capacity and excellent rate capability[J]. Adv. Energy Mater., 2024, 14(48): 2402489 doi: 10.1002/aenm.202402489
84. [84]
  CHEN Z, HUA Y N, CHEN B, FENG J W, LIU G, JIANG B. In-situ compositing HA significantly enhancing electrochemical performance of Mn-MOF anode materials[J]. Chem. Eng. J., 2025, 506: 160004 doi: 10.1016/j.cej.2025.160004
85. [85]
  BAI L S, XU Y, LIU Y, ZHANG D N, ZHANG S B, YANG W J, CHANG Z, ZHOU H S. Metal-organic framework glass stabilizes high-voltage cathodes for efficient lithium-metal batteries[J]. Nat. Commun., 2025, 16(1): 3484 doi: 10.1038/s41467-025-58639-z
86. [86]
  YANG M H, WANG Y, HUANG Y F, XIAO J M, ZHU G Y, FANG Y, ZHOU X C, LONG J H, XIE M, BIN D S, LI D. A conductive Cu-based metal-organic framework ribbon with high-density redox-active centers as cathode for stable high-capacity lithium-ion batteries[J]. Angew. Chem.‒Int. Edit., 2025, 64: e202421008 doi: 10.1002/anie.202421008
87. [87]
  AHN H, PARK Y, NAM K W. Chelated metal-organic frameworks for improved the performance of high-nickel cathodes in lithium-ion batteries[J]. ChemSusChem, 2025, 18(2): e202400823 doi: 10.1002/cssc.202400823
88. [88]
  SHIN S, YOON Y, PARK S, SHIN M W. Metal-organic framework coating layer with inherent self-reactivity toward lithium ions to enhance both structural stability and electrochemical performance of LiNi_0.9Co_0.085Mn_0.015O₂ cathodes[J]. Appl. Surf. Sci., 2024, 643: 158735 doi: 10.1016/j.apsusc.2023.158735
89. [89]
  LIN J, SUN Y H, LIN X M. Metal-organic framework-derived LiFePO₄ cathode encapsulated in O, F-codoped carbon matrix towards superior lithium storage[J]. Nano Energy, 2022, 91: 106655 doi: 10.1016/j.nanoen.2021.106655
90. [90]
  CHU Z H, GAO X C, WANG C Y, WANG T Y, WANG G X. Metal-organic frameworks as separators and electrolytes for lithium-sulfur batteries[J]. J. Mater. Chem. A, 2021, 9(12): 7301-7316 doi: 10.1039/D0TA11624F
91. [91]
  HUANG D, LIANG C, CHEN L N, TANG M, ZHENG Z J, WANG Z B. MOF composite fibrous separators for high-rate lithium-ion batteries[J]. J. Mater. Sci., 2021, 56(9): 5868-5877 doi: 10.1007/s10853-020-05559-6
92. [92]
  ZHOU Q, HUSSAIN S, HU J S, ZHANG G H, ZHANG W X, ZHANG B, WANG L. Polybenzimidazole composite separators engineered from MOFs-HNTs composites applicated in lithium-ion batteries[J]. Small, 2025, 21(19): 2502051 doi: 10.1002/smll.202502051
93. [93]
  SUN N, LIU Q S, CAO Y, LOU S F, GE M Y, XIAO X H, LEE W K, GAO Y Z, YIN G P, WANG J J, SUN X L. Anisotropically electrochemical-mechanical evolution in solid-state batteries and interfacial tailored strategy[J]. Angew. Chem.‒Int. Edit., 2019, 58(51): 18647-18653 doi: 10.1002/anie.201910993
94. [94]
  KIM K O, PARK S H, CHUN H B, LEE W Y, JANG B Y, KIM D, YU J H, YUN K S, KIM J, LI O. L, HAN, Y J. Design and optimization of composite cathodes for solid-state batteries using hybrid carbon networks with facile electronic and ionic percolation pathways[J]. ACS Appl. Mater. Interfaces, 2023, 15(30): 36748-36758 doi: 10.1021/acsami.3c04394
95. [95]
  HAN D D, WANG P F, LI P, SHI J, LIU J, CHEN P J, ZHAI L P, MI L W, FU Y Z. Homogeneous and fast Li-ion transport enabled by a novel metal-organic-framework-based succinonitrile electrolyte for dendrite-free Li deposition[J]. ACS Appl. Mater. Interfaces, 2021, 13(44): 52688-52696 doi: 10.1021/acsami.1c16498
96. [96]
  LIU Y X, WANG S Q, CHEN W C, KONG W H, WANG S P, LIU H X, DING L, DING L X, WANG H H. 5.1 µm ion-regulated rigid quasi-solid electrolyte constructed by bridging fast Li-ion transfer channels for lithium metal batteries[J]. Adv. Mater., 2024, 36(28): 2401837 doi: 10.1002/adma.202401837
97. [97]
  LI S, CHEN Y N, LENG X L, YANG M D, ARIFEEN W U, KO T J. Rapid Li⁺ transport within the MOF-based composite solid electrolyte enables high-performance solid-state lithium-ion batteries[J]. Chem. Eng. J., 2024, 500: 157209 doi: 10.1016/j.cej.2024.157209
98. [98]
  XIONG Z Y, WU S T, GU L, ZHAI M Y, PAN Y K, MA Y H, CHEN Z J. The assembly of a high-efficiency tris-benzotriazolate-based metal-organic framework solid-state electrolyte[J]. ACS Cent. Sci., 2025, 11(7): 1199-1206 doi: 10.1021/acscentsci.5c00567
99. [99]
  ZHOU J, WANG X, FU J F, CHEN L Y, WEI X R, JIA R R, SHI L Y. A 3D cross-linked metal-organic framework (MOF)-derived polymer electrolyte for dendrite-free solid-state lithium-ion batteries[J]. Small, 2024, 20(18): 2309317 doi: 10.1002/smll.202309317
100. [100]
  LUO H B, CHEN W Z, MO Y H, GAO J L, ZHANG G Q, TONG Y B, REN X M. In situ polymer‒Integrated metal-organic framework for solid-state electrolyte membrane. inorganic chemistry[J]. Inorg. Chem., 2025, 64(42): 21255-21262 doi: 10.1021/acs.inorgchem.5c04173
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