Citation: Xiaofen GUAN, Liuqing KANG, Yingyue ZHANG, Linjing XUE, Xinyu LI, Wenmin WANG. Design, synthesis, DNA interaction, and dual catalytic properties of tetranuclear holmium (Ho) complex[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(7): 1543-1554. doi: 10.11862/CJIC.20250380 shu

Design, synthesis, DNA interaction, and dual catalytic properties of tetranuclear holmium (Ho) complex

College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, Shanxi 030619, China

Corresponding author: Xiaofen GUAN, guanxiaofen325@163.com Wenmin WANG, wangwenmin0506@126.com
Received Date: 22 December 2025
Revised Date: 9 May 2026

Figures(5)

A tetranuclear Ho(Ⅲ)-based complex [Ho₄(L)₂(dbm)₆(CH₃O)₄] (1) was synthesized via solvothermal methods, where HL=(E)-2-hydroxy-3-methoxy-N′-[(6-methoxypyridin-2-yl)methylene]benzohydrazide and Hdbm=dibenzoylmethane. Structural characterization revealed that this complex is composed of four Ho³⁺ ions, six dbm^- ions, two L^- ions, and four coordinated CH₃O^- ions. The interaction mechanisms between ligand HL, 1 and calf thymus DNA (CT-DNA) were investigated by using UV-Vis spectroscopy, fluorescence titration, and cyclic voltammetry. The results indicated that 1 can interact with DNA via intercalation. Catalytic tests showed that 1 exhibits remarkable catalytic activity, capable of catalyzing the cycloaddition reaction of CO₂ with epoxides and the Knoevenagel condensation reaction between malononitrile and aldehydes.
- tetranuclear Ho(Ⅲ)-based complex,
- polydentate Schiff base,
- DNA interaction,
- catalytic performance,
- CO₂ cycloaddition,
- Knoevenagel condensation reaction
1. [1]
  CHEN H, ZHANG Z, LV H, LIU S, ZHANG X. Investigation on the catalytic behavior of a novel thulium-organic framework with a planar tetranuclear {Tm₄} cluster as the active center for chemical CO₂ fixation[J]. Dalton Trans., 2022, 51(2): 532-540 doi: 10.1039/D1DT03646G
2. [2]
  SUN Y, LIU G, XIONG G, XU G W. Two novel tetranuclear Yb(Ⅲ)-based compounds for highly efficient conversion of CO₂ to cyclic carbonates[J]. CrystEngComm, 2025, 27(14): 2148-2153 doi: 10.1039/D4CE00662C
3. [3]
  WANG Z F, FEI Y, QIN A, ZHANG S H, ZHANG X T. Robust fluorine-decorated {Yb₄}-organic framework for C₂H₆ capture and efficient catalytic performance on CO₂-epoxide cycloaddition[J]. ACS Appl. Mater. Interfaces, 2025, 17(20): 29788-29798 doi: 10.1021/acsami.5c07205
4. [4]
  WANG W M, HAN T L, SHAO Y L, QIAO X Y, WU Z L, WANG Q L, SHI P F, GAO H L, CUI J Z. Butterfly-shaped tetranuclear Ln₄ clusters showing magnetic refrigeration and single molecule-magnet behavior[J]. New J. Chem., 2018, 42(18): 14949-14955 doi: 10.1039/C8NJ02479K
5. [5]
  PAJEROWSKI D M, LI Q, HYUN J, DENNIS C L, PHELAN D, YAN P F, CHEN P, LI G M. Chloride-bridged, defect-dicubane {Ln₄} core clusters: Syntheses, crystal structures and magnetic properties[J]. Dalton Trans., 2014, 43(31): 11973-11980 doi: 10.1039/C4DT01329H
6. [6]
  FUNAKOSHI N, WAKIZAKA M, WAN Q, SHEN Y B, ZHANG H T, ITO H S, IGUCHI H, ISHIKAWA R, HORII Y, BREEDLOVE B K, TAKAISHI A, YAMASHITA M. Distinctive magnetic relaxation behavior of Ln(Ⅲ) single-molecule magnets with a conducting organic π donor system[J]. Cryst. Growth Des., 2025, 25(8): 2650-2656 doi: 10.1021/acs.cgd.5c00120
7. [7]
  LIAO P Y, LI Z, HUANG J R, LU W, LIU J C, LIU Z W, WANG J, TONG M L. On-demand vitrification of multicomponent lanthanide complexes for magnetism and up-conversion emission[J]. J. Am. Chem. Soc., 2025, 147(46): 42766-42776
8. [8]
  LIU C M, HAO X, HU Z B, WEN H R. Solvent-dependent Ln(Ⅲ) clusters assembled by immobilization of CO₂ in air: Zero-field single-molecule magnets and magnetic refrigerant materials[J]. Dalton Trans., 2025, 54(1): 96-107 doi: 10.1039/D4DT02310B
9. [9]
  NATH J K, BORAH R. A lanthanide cluster formed by fixing atmospheric CO₂ to carbonate: A molecular magnetic refrigerant and photoluminescent material[J]. J. Chem. Sci., 2023, 135(3): 58 doi: 10.1007/s12039-023-02176-z
10. [10]
  LI X Z, TIAN C B, SUN Q F. Coordination-directed self-assembly of functional polynuclear lanthanide supramolecular architectures[J]. Chem. Rev., 2022, 122(6): 6374-6458 doi: 10.1021/acs.chemrev.1c00602
11. [11]
  AGUILÀ D, ROUBEAU O, AROMÍ G. Designed polynuclear lanthanide complexes for quantum information processing[J]. Dalton Trans., 2021, 50(35): 12045-12057 doi: 10.1039/D1DT01862K
12. [12]
  GUPTA R, GOYAL H, GUPTA R. Lanthanide-based metallogels with tunable luminescence: Nanomolar detection of a nerve agent simulant and anticounterfeiting applications[J]. J. Mater. Chem. C, 2025, 13(22): 11084-11095 doi: 10.1039/D5TC00739A
13. [13]
  ZHENG K T, MA P T. Recent advances in lanthanide-based POMs for photoluminescent applications[J]. Dalton Trans., 2024, 53(9): 3949-3958 doi: 10.1039/D3DT03999D
14. [14]
  ZHANG H, LIU G Y, DIAO X H, YASEEN M, CHEN Z, GAO Y Y, WANG H, QI C S, LI W. A series of isostructural Ln-based coordination polymers: Crystal structure, luminescence sensing and color tuning[J]. J. Solid State Chem., 2023, 324: 124114 doi: 10.1016/j.jssc.2023.124114
15. [15]
  PASWAN S, JAISWAL N, URVASHI, NATH A, KUMAR M, MISHRA D, YADAV N. Emerging trends and structure-activity insights of Schiff base-lanthanide complexes as antibacterial agents[J]. RSC Adv., 2026, 16(4): 3478-3508 doi: 10.1039/D5RA08181E
16. [16]
  STASZAK K, RZELEWSKA-PIEKUT M, REGEL-ROSOCKA M. Role of noble and rare earth metals in bioactive materials for medical applications in tissue engineering[J]. RSC Adv., 2025, 15(48): 40709-40729 doi: 10.1039/D5RA04036A
17. [17]
  ZHAO L, HAN Y, GUO G, BAI H, WANG Z X, JING H W, SONG G Y, WANG Z Y, LI J Y, LI J. Application of three Ln(Ⅲ)-coordination polymers in fields of luminescence, antibacteria and detection of Fe³⁺ and 4-nitrophenol[J]. J. Rare Earths, 2023, 41(9): 1392-1397 doi: 10.1016/j.jre.2022.08.018
18. [18]
  MISRA S N, GAGNANI M A, SHUKLA R S. Biological and clinical aspects of lanthanide coordination compounds[J]. Bioinorg. Chem. Appl., 2004, 2(3/4): 155
19. [19]
  ZHANG Y H, LI X S, LI K S, WANG L, LUO X, ZHANG Y, SUN N, ZHU M C. DNA binding studies and in-vitro anticancer studies of novel lanthanide complexes[J]. Int. J. Biol. Macromol., 2024, 279: 135048 doi: 10.1016/j.ijbiomac.2024.135048
20. [20]
  HUANG J B, HU B, MENG J S, MENG T, LIU W X, GUAN Y T, JIN L ZHANG X C. Highly efficient sustainable strategies toward carbon-neutral energy production[J]. Energy Environ. Sci., 2024, 17(3): 1007-1045 doi: 10.1039/D3EE03363E
21. [21]
  KUMARI S, GUSAIN M, LAMBA B Y, KUMAR S. A critical review on recent advancements in metal-organic frameworks for CO₂ capture, storage and utilization[J]. J. Mater. Chem. A, 2025, 13: 21352-21388 doi: 10.1039/D5TA02338F
22. [22]
  WEI R Z, ZHAO T, XU H, GAO J K. Recent advances and challenges of metal-organic frameworks for CO₂ capture[J]. Dalton Trans., 2025, 54: 8385-8391 doi: 10.1039/D5DT00204D
23. [23]
  DING M, FLAIG R W, JIANG H L, YAGHI O M. Carbon capture and conversion using metal-organic frameworks and MOF-based materials[J]. Chem. Soc. Rev., 2019, 48(10): 2783-2828 doi: 10.1039/C8CS00829A
24. [24]
  DAS P, MANDAL S K. Unprecedented high temperature CO₂ selectivity and effective chemical fixation by a copper-based undulated metal-organic framework[J]. ACS Appl. Mater. Interfaces, 2020, 12(33): 37137-37146 doi: 10.1021/acsami.0c09024
25. [25]
  LV H X, CHEN H T, HU T P, ZHANG X T. Nanocage-based {Ln₂Tm₂}-organic framework for efficiently catalyzing the cycloaddition reaction of CO₂ with epoxides and Knoevenagel condensation[J]. Inorg. Chem. Front., 2022, 9(22): 5788-5798 doi: 10.1039/D2QI01271E
26. [26]
  CHUGHTAI A H, AHMAD N. YOUNUS H A, LAYPKOV A, VERPOORT F. Metal-organic frameworks: Versatile heterogeneous catalysts for efficient catalytic organic transformations[J]. Chem. Soc. Rev., 2015, 44(19): 6804-6849 doi: 10.1039/C4CS00395K
27. [27]
  DAS R, MANNA S S, PATHAK B, NAGARAJA C M. Strategic design of Mg-centered porphyrin metal-organic framework for efficient visible light-promoted fixation of CO₂ under ambient conditions: Combined experimental and theoretical investigation[J]. ACS Appl. Mater. Interfaces, 2022, 14(29): 33285-33296 doi: 10.1021/acsami.2c07969
28. [28]
  ZHANG K L, TANG J L, JIA B W, GUO Z Q, YAN R, LI B F, CHEN J L, YANG C B, QIAO N, WANG W M. A novel Eu₈ cluster for efficiently catalyzing CO₂ cycloaddition and Knoevenagel condensation[J]. J. Mol. Struct., 2025, 1321(3): 140033
29. [29]
  ZHANG T, ZHANG, Z G, CHEN H T, ZHANG X T, LI Q L. Catalytic investigation of CO₂ chemical fixation and the Knoevenagel condensation reaction for a Tm^Ⅲ-organic framework. Cryst. Growth Des., 2021, 22(1): 304-312
30. [30]
  SAHOO R, MONDAL S, CHAND S, DAS M C. Highly robust metal-organic framework for efficiently catalyzing Knoevenagel condensation and the Strecker reaction under solvent-free conditions. Inorg. Chem. 2023, 62(32): 12989-13000 doi: 10.1021/acs.inorgchem.3c01767
31. [31]
  XU J, SU W P, HONG M C. A series of lanthanide secondary building units based metal-organic frameworks constructed by organic pyridine-2, 6-dicarboxylate and inorganic sulfate[J]. Cryst. Growth Des., 2011, 11(1): 337-346 doi: 10.1021/cg101343k
32. [32]
  SHI P F, CHEN Z, XIONG G, SHEN B, SUN J Z, CHENG P, ZHAO B. Structures, luminescence, and magnetic properties of several three-dimensional lanthanide-organic frameworks comprising 4-carboxyphenoxy acetic acid[J]. Cryst. Growth Des., 2012, 12(11): 5203-5210 doi: 10.1021/cg300277m
33. [33]
  PENG J M, YU Q X, ZHU Z H, LIU Z Y, LU X L, ZOU H H, LIANG F P. Two diamond-shaped Dy₄ complexes caused by different topological connections: Structure and magnetism[J]. Cryst. Growth Des., 2021, 21(11): 6056-6063 doi: 10.1021/acs.cgd.1c01094
34. [34]
  WANG Y, TAYLOR J S, GROSS M L. Isolation and mass spectrometric characterization of dimeric adenine photoproducts in oligodeoxynucleotides[J]. Chem. Res. Toxicol., 2001, 14(6): 738-745 doi: 10.1021/tx010009u
35. [35]
  SUN Y X, LI C Y, YANG C J, ZHAO Y Y, GUO J Q, YU B. Two Cu(Ⅱ) complexes with Schiff base ligands: Syntheses, crystal structures, spectroscopic properties, and substituent effect[J]. Chinese J. Inorg. Chem., 2016, 32(2): 327-335
36. [36]
  YAN J L, WU W N, WANG Y. Simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application[J]. Chinese J. Inorg. Chem., 2024, 40(9): 1653-1660
37. [37]
  WANG H T, LING Y N, MA X Q, CHEN Y X, ZHANG R, WANG K Y, ZHANG Y, WANG W M. Construction, crystal structures, and biological activities of two Ln₃^Ⅲ complexes[J]. Chinese J. Inorg. Chem., 2024, 40(8): 1474-1482
38. [38]
  KUMAR R R, RAMESH R. Synthesis, molecular structure and electrochemical properties of nickel(Ⅱ) benzhydrazone complexes: Influence of ligand substitution on DNA/protein interaction, antioxidant activity and cytotoxicity[J]. RSC Adv., 2015, 5(123): 101932-101948 doi: 10.1039/C5RA19530F
39. [39]
  SRINIVASAN S, ANNARAJ J, ATHAPPAN P R. Spectral and redox studies on mixed ligand complexes of cobalt(Ⅲ) phenanthroline/bipyridyl and benzoylhydrazones, their DNA binding and antimicrobial activity[J]. J. Inorg. Biochem., 2005, 99(3): 876-882 doi: 10.1016/j.jinorgbio.2005.01.002
40. [40]
  LEONE A M, TIBODEAU J D, BULL S H, FELDBERG S W, THORP H H, MURRAY R W. Ion atmosphere relaxation and percolative electron transfer in Co bipyridine DNA molten salts[J]. J. Am. Chem. Soc., 2003, 125(22): 6784-6790 doi: 10.1021/ja0348795
41. [41]
  ZHANG Y Y, KANG L Q, YANG Y T, GUAN X F, WANG W M. Crystal structure and antibacterial activity of two Gd₂ complexes based on polydentate Schiff-base ligands[J]. Chinese J. Inorg. Chem., 2025, 41(9): 1867-1877
42. [42]
  GARAI A, GOSWAM A, BIRADHA K. In situ conversion of a MOG to a crystalline MOF: A case study on solvent-dependent gelation and crystallization[J]. Chem. Commun., 2022, 58(81): 11414-11417 doi: 10.1039/D2CC04724A
43. [43]
  KAMAKURAA Y, YASUDA S, HOSOKAWA N, NISHIOKA S, HONGO S, YOKOI T, MAEDA K. Selective CO₂-to-Formate conversion driven by visible light over a precious-metal-free nonporous coordination polymer[J]. ACS Catal., 2022, 12(16): 10172-10178 doi: 10.1021/acscatal.2c02177
44. [44]
  ZHANG T, CHEN H T, LIU S R, LU H X, ZHANG X T, LI Q L. Highly robust {Ln₄}-organic frameworks (Ln=Ho, Yb) for excellent catalytic performance on cycloaddition reaction of epoxides with CO₂ and Knoevenagel condensation[J]. ACS Catal., 2021, 11(24): 14916-14925 doi: 10.1021/acscatal.1c04260
45. [45]
  WANG W M, QIAO N, DONG S S, CHEN Y, XIN X Y, YANG G L, FANG M. Crystal structure, slow magnetic relaxation behavior and conversion CO₂ of a tetranuclear Ho(Ⅲ)-based complex[J]. Chinese J. Inorg. Chem., 2023, 39(5): 917-927
46. [46]
  LIU S, HU T, YANG K, ZHANG X. Robust {Cd₄}-organic framework for efficiently catalyzing CO₂ cycloaddition and Knoevenagel condensation[J]. Cryst. Growth Des., 2023, 23(5): 3320-3329 doi: 10.1021/acs.cgd.2c01472
47. [47]
  GUAN X F, LIU Y, CHEN W H, YANG Y T, XI L H, ZHANG X G, CHEN W Y, WANG W M. Two Yb₄ clusters enable efficient catalysis in CO₂ cycloaddition and Knoevenagel condensation reactions[J]. J. Mol. Struct., 2025, 1345: 143044 doi: 10.1016/j.molstruc.2025.143044
48. [48]
  LIU S R, CHEN H T, FAN L M, ZHANG X T. Highly robust {In₂}-organic framework for efficiently catalyzing CO₂ cycloaddition and Knoevenagel condensation[J]. Inorg. Chem., 2023, 62(8): 3562-3572 doi: 10.1021/acs.inorgchem.2c04130
49. [49]
  GUAN X F, TANG J L, YAN R, GUO Z Q, JIA B W, QIAO N, HOU Y L, WANG W M. Two rhombic-shaped Ln₄ clusters for efficiently catalyzing CO₂ cycloaddition and Knoevenagel condensation[J]. J. Organomet. Chem., 2024, 1021: 123355 doi: 10.1016/j.jorganchem.2024.123355
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