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Citation: Dehua XIN, Min WANG, Wei ZHANG, Wenjie KOU, Xuezhi HAO. Z-scheme g-C3N4/Bi2WO6 heterojunction: Construction and photocatalytic degradation performance for ofloxacin[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(6): 1215-1228. doi: 10.11862/CJIC.20250368 shu

Z-scheme g-C3N4/Bi2WO6 heterojunction: Construction and photocatalytic degradation performance for ofloxacin

  • Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Figures(9)

  • A Z-scheme g-C3N4/Bi2WO6 heterojunction photocatalytic material was constructed via high-temperature thermal polymerization combined with an in-situ solvothermal method. The composition, structure, and optical properties of the heterojunction were thoroughly characterized using X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and ultraviolet-visible-near infrared diffuse reflectance spectroscopy. The results indicate that the presence of oxygen vacancies enhances the absorption capacity of the heterojunction for visible and NIR light. The transformation of the Ⅱ-type structure to the Z-scheme mechanism improves the separation efficiency and redox ability of photogenerated electron-hole pairs. Under visible and NIR light irradiation, the apparent rate constants for the degradation of ofloxacin by the optimal g-C3N4/Bi2WO6 heterojunction reached 0.045 8 and 0.003 8 min-1, respectively, which were significantly higher than those of the individual g-C3N4 and Bi2WO6 components. Moreover, the prepared heterojunction exhibited excellent cycling stability and reusability.
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