Citation: Gaoxin ZHANG, Chenkai ZHENG, Liangjie MENG, Guoqing CHEN, Hui GAO. Ag@CsPbBr3@ZIF-8 surface enhanced Raman scattering substrate: Preparation and detection of pyrene in corn oil[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(5): 980-990. doi: 10.11862/CJIC.20250304 shu

Ag@CsPbBr3@ZIF-8 surface enhanced Raman scattering substrate: Preparation and detection of pyrene in corn oil

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  • A surface-enhanced Raman scattering (SERS) composite substrate was designed and prepared based on Ag nanoparticle-composited ZIF-8-coated perovskite nanocrystals (Ag@CsPbBr3@ZIF-8). This composite substrate exhibited excellent water stability and, compared to a pure Ag substrate, significantly enhanced the Raman signal of pyrene molecules in aqueous solution. Using spectral analysis, a fitting equation was derived, revealing that the composite substrate enabled highly sensitive detection of pyrene with a detection limit of 8.58 μg·L-1. In spiked recovery tests, the recovery rate of pyrene ranged from 97.6% to 109.2%, with a relative standard deviation (RSD) between 1.12% and 7.91%. These results indicate that the substrate possesses good reproducibility and specificity for pyrene detection.
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