Citation: Shuting KONG, Fengshi ZHANG, Zhiyi LU, Yanling LIU, Minglang YE, Zhengfang HU, Longsheng WANG, Bing HU, Haiying WANG. Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303 shu

Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts

Shuting KONG ^{1, #} ,
Fengshi ZHANG ^{2, #} ,
Zhiyi LU ¹ ,
Yanling LIU ¹ ,
Minglang YE ¹ ,
Zhengfang HU ¹ ,
Longsheng WANG ^1,, ,
Bing HU ¹ ,
Haiying WANG ^3,,

1.
Hubei Provincial Key Laboratory of Green Materials of Light Industry, School of Material Science and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China
2.
School of Material Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
3.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: Longsheng WANG, wangls@mail.hbut.edu.cn Haiying WANG, wanghaiying@nju.edu.cn
Received Date: 28 September 2025
Revised Date: 30 January 2026

Figures(4)

Tributyl citrate (TBC) is an environmentally friendly plasticizer with low toxicity, good compatibility and degradability. Compared to the traditional catalysts of the concentrated H₂SO₄ to produce TBC, heteropolyacid (HPA), as solid superacid, are non-volatile and no-corrosive to equipment, but are expensive and difficult to recycle. In order to recycle HPA, supported heteropolyacid catalysts using different carriers exhibit promising potential in the preparation of TBC owing to their large surface area and easy separability. This review summarizes the research progress in preparing TBC using supported HPA catalysts. Those catalysts are loaded on the carriers such metal oxides, carbon materials, molecular sieves, and ionic liquids through surface loading, internal encapsulation and ionic bonding. A key challenge in advancing these materials toward industrial application is strengthening the interaction between the HPAs and their supporting carriers. Polyoxometalate-based metal-organic frameworks (POMOFs) and polyoxometalate-based covalent organic frameworks (POMCOFs), which employ metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as carriers to support HPAs, effectively reduce the leaching of HPA catalysts through internal encapsulation. The characteristics and limitations of different carrier systems in terms of catalytic activity, structure-activity relationships, and compatibility with novel processes are systematically summarized, which can provide some references to develop efficient, stable, and eco-friendly catalysts for TBC synthesis.
- tributyl citrate,
- catalyst,
- heteropoly acid
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沈阳化工大学材料科学与工程学院沈阳 110142