Citation: Xiaopei HE, Jing HAN, Zhong YU, Na YE, Yi WAN. Preparation and antimicrobial properties of polyvinyl alcohol composite film based on Ag(Ⅰ) complex[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(3): 531-542. doi: 10.11862/CJIC.20250271 shu

Preparation and antimicrobial properties of polyvinyl alcohol composite film based on Ag(Ⅰ) complex

Xiaopei HE ¹ ,
Jing HAN ^1,, ,
Zhong YU ² ,
Na YE ¹ ,
Yi WAN ³

1.
Department of Materials Physics and Chemistry, Xi′an University of Technology, Xi′an 710048, China
2.
Department of Applied Chemistry, Xi′an University of Technology, Xi′an 710061, China
3.
Shaanxi Institute of Microbiology, Xi′an 710043, China

Corresponding author: Jing HAN, hanj@xaut.edu.cn
Received Date: 25 August 2025
Revised Date: 17 November 2025

Figures(5)

The antimicrobial activities of silver(Ⅰ) complexes can be enhanced by increasing the content and release of silver ions, which may also cause potential toxicity. Additionally, the powder form of silver(Ⅰ) complexes is not advantageous for clinical applications. To address the above challenges, an antimicrobial film based on silver(Ⅰ) complex was constructed through the following three design strategies. First, complex 1 was self-assembled using an antimicrobial ligand (indole-3-carboxylic acid) and tert-butylacetylene silver to enhance antimicrobial effects by releasing Ag⁺ and antimicrobial ligands simultaneously. Then, the third antimicrobial source, i.e., graphene oxide (GO), was introduced to prepare 1@GO composite with GO addition optimized by antimicrobial performance. Finally, 1@GO/PVA film was prepared by selecting polyvinyl alcohol (PVA) as a matrix for potential applications. The structure, photostability, and solution stability of 1 were characterized by IR spectra and powder X-ray diffraction. Ag⁺ releasing test showed the enhanced pH-responsive Ag⁺ release of 1. The results of the inhibition zones test showed weak antimicrobial effects of GO (1 000 μg·mL^-1) on Escherichia coli (E. coli), Pseudomonas aeruginosa (P. aeruginosa), Staphylococcus aureus (S. aureus), and Candida albicans (C. albicans) with increased inhibition zone diameters of 1.1, 2.5, 3.5, and 1.8 mm, respectively. 1 showed good broad-spectra antimicrobial activities against the four microorganisms, and diameters of inhibitory zones increased by 5.0, 10.5, 5.8, and 5.0 mm, respectively. SEM images of 1@GO (1∶1 of mass concentration ratio) exhibited that 1 was dispersed evenly in GO, exposing a large number of sharp edges. The diameters of inhibition zones for 1@GO(1∶1) against E. coli, S. aureus, and C. albicans increased by 6.2, 10.4, and 9.8 mm, respectively, which are larger than the algebraic sum of respective contributions of 1 and GO to the diameter of inhibition zones (6.1, 9.3, and 6.8 mm). This result indicated clearly the successful realization of synergistic antimicrobial effects of silver complex and GO. Minimum inhibitory concentration (MIC) results exhibited the best inhibitory effect of 1 on P. aeruginosa and S. aureus with low MIC values of 20 and 15 μg·mL^-1, respectively. After adding GO, MIC values of 1@GO against E. coli, P. aeruginosa, S. aureus, and C. albicans reduced to 5-10 μg·mL^-1, 5-10 μg·mL^-1, and 10-15 μg·mL^-1, respectively. 1(0.5%)@GO(1∶1)/PVA film displayed good antimicrobial properties for four strains, with the largest diameter of inhibition zones of 18.5 mm against P. aeruginosa.
- antimicrobial,
- silver complex,
- antimicrobial ligand,
- graphene oxide,
- polyvinyl alcohol
1. [1]
  LIU Y W, ZHOU L Y, DONG Y, WANG R, PAN Y, ZHUANG S, LIU D, LIU J Q. Recent developments on MOF-based platforms for antibacterial therapy[J]. RSC Med. Chem., 2021, 12(6): 915-928 doi: 10.1039/D0MD00416B
2. [2]
  LI J S, KLEINTSCHEK T, RIEDER A, CHENG Y, BAUMBACH T, OBST U, SCHWARTZ T, LEVKIN P A. Hydrophobic liquid-infused porous polymer surfaces for antibacterial applications[J]. ACS Appl. Mater. Interfaces, 2023, 5(14): 6704-6711
3. [3]
  ALI S A, KONWAR A N, THAKUR D, KUNDU S. Metal(Ag)/metal oxide(CuO, ZnO)@polyvinyl alcohol(PVA) nanocomposite free-standing films: Physical and antimicrobial properties[J]. Surf. Interfaces, 2025, 56: 105587 doi: 10.1016/j.surfin.2024.105587
4. [4]
  HE L, LI Z, GU M Q, LI Y F, YI C L, JIANG M, YU X, XU L. Intelligent carbon dots with switchable photo-activated oxidase-mimicking activity and pH responsive antioxidant activity adaptive to the wound microenvironment for selective antibacterial therapy[J]. Adv. Sci., 2024, 11(40): 2406681 doi: 10.1002/advs.202406681
5. [5]
  LI J H, ZHANG S L. Antibacterial activity of chitosan and its derivatives and their interaction mechanism with bacteria: Current state and perspectives[J]. Eur. Polym. J., 2020, 138: 109984 doi: 10.1016/j.eurpolymj.2020.109984
6. [6]
  ZHOU H J, ZOU F M, KOH K, LEE J. Antibacterial activity of graphene-based nanomaterials[J]. Adv. Exp. Med. Biol., 2022, 1351: 233-250
7. [7]
  MU W Y, LIU J, ZHANG H D, WENG L, LIU T, CHEN X. Intelligent hydrogel with physiologically dependent capacities of photothermal conversion and nanocatalytic medicine to integratively inhibit bacteria and inflammation for on-demand treatment of infected wound[J]. Small, 2024, 20(51): 2405464 doi: 10.1002/smll.202405464
8. [8]
  AL-TAYYAR N A, YOUSSEF A M, AL-HINDI R R. Antimicrobial packaging efficiency of ZnO-SiO₂ nanocomposites infused into PVA/CS film for enhancing the shelf life of food products[J]. Food Packaging Shelf Life, 2020, 25: 100523 doi: 10.1016/j.fpsl.2020.100523
9. [9]
  LU X T, ZHANG P, ZHAO Z J, HUANG L, ZUO H W, LIANG L L. Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes[J]. Chinese J. Inorg. Chem., 2025, 41(8): 1523-1532
10. [10]
  CHU H Y, FU H F, LIU A, WANG P, CAO Y L, DU A F, WANG C C. Two silver-based coordination polymers constructed from organic carboxylate acids and 4, 4′-bipyridine-like bidentate ligands: Synthesis, structure, and antimicrobial performances[J]. Polyhedron, 2020, 188: 114684 doi: 10.1016/j.poly.2020.114684
11. [11]
  WANG X, SU K, TAN L, LIU X M, CUI Z D, JING D D, YANG X J, LIANG Y Q, LI Z Y, ZHU S L, YEUNG K W K, ZHENG D, WU S L. Rapid and highly effective noninvasive disinfection by hybrid Ag/CS@MnO₂ nanosheets using near-infrared light[J]. ACS Appl. Mater. Interfaces, 2019, 11(16): 15014-15027 doi: 10.1021/acsami.8b22136
12. [12]
  HECEL A, KOLKOWSKA P, KRZYWOSZYNSKA K, SZEBESCZYK A, ROWINSKA-ZYREK M, KOZLOWSKI H. Ag⁺ complexes as potential therapeutic agents in medicine and pharmacy[J]. Curr. Med. Chem., 2019, 26(4): 624-647 doi: 10.2174/0929867324666170920125943
13. [13]
  DURÁN N, DURÁN M, JESUS M B, SEABRA A B, FÁVARO W J, NAKAZATO G. Silver nanoparticles: A new view on mechanistic aspects on antimicrobial activity[J]. Nanomed.‒Nanotechnol., 2016, 12(3): 789-799 doi: 10.1016/j.nano.2015.11.016
14. [14]
  HORCAJADA P, GREF R, BAATI T, ALLAN P K, MAURIN G, COUVREUR P, FEREY G, MORRIS R, SERRE C. Metal-organic frameworks in biomedicine[J]. Chem. Rev., 2011, 112(2): 1232-1268
15. [15]
  CHERNOUSOVA S, EPPLE M. Silver as antibacterial agent: ion, nanoparticle, and metal[J]. Angew. Chem.‒Int. Edit., 2013, 52: 1636-1653 doi: 10.1002/anie.201205923
16. [16]
  SLENTERS T V, HAUSER-GERSPACH I, DANIELS A U, FROMM K M. Silver coordination compounds as light-stable, nano-structured and anti-bacterial coatings for dental implant and restorative materials[J]. J. Mater. Chem., 2008, 18(44): 5359-5362 doi: 10.1039/b813026d
17. [17]
  ABD EI SALAM H M, NASSAR H N, KHIDR A S A, ZAKI T. Antimicrobial activities of green synthesized Ag nanoparticles@Ni-MOF nanosheets[J]. J. Inorg. Organomet. Polym., 2018, 28(6): 2791-2798 doi: 10.1007/s10904-018-0950-4
18. [18]
  ECKHARDT S, BRUNETTO P S, GAGNON J, PRIEBE M, GIESE B, FROMM K M. Nanobio silver: Its interactions with peptides and bacteria, and its uses in medicine[J]. Chem. Rev., 2013, 113(7): 4708-4754 doi: 10.1021/cr300288v
19. [19]
  XIE X L, SUN T C, XUE J Z, MIAO Z H, YAN X, FANG W W, LI Q, TANG R P, LU Y, TANG L X, ZHA Z B, HE T. Ag nanoparticles cluster with pH-triggered reassembly in targeting antimicrobial applications[J]. Adv. Funct. Mater., 2020, 30(17): 2000511 doi: 10.1002/adfm.202000511
20. [20]
  SUGDEN R, KELLY R, DAVIES S. Combatting antimicrobial resistance globally[J]. Nat. Microbiol., 2016, 10: 16187
21. [21]
  WYSZOGRODZKA G, MARSZAŁEK B, GIL B, DOROŻYŃSKI P. Metal-organic frameworks: Mechanisms of antibacterial action and potential applications [J]. Drug Discov. Today, 2016, 21(9): 1009-1018
22. [22]
  NICOLA C D, MARCHETTI F, TOMBESI A, XHAFA S, CAMPITELLI P, MORONI M, GALLI S, PETTINARI R, PETTINARI C. Antibacterial activity of copper pyrazolate coordination polymers[J]. New J. Chem., 2023, 47(41): 19047-19056 doi: 10.1039/D3NJ02378H
23. [23]
  WANG D M, XING X W, YE X M, CHEN Z, GOU Z P, WU D D. Synthesis, characterization and antibacterial activity of Zn(Ⅱ) coordination polymer[J]. J. Inorg. Biochem., 2019, 194: 153-159 doi: 10.1016/j.jinorgbio.2019.02.014
24. [24]
  UVAROVA M A, SHMELEV M A, BEKKER O B, LUTSENKO I A, NEFEDOV S E, EREMENKO I L. Targeted design of heterotrimetallic 1-D coordination polymers based on functionalized metallocenes featuring antibacterial activity[J]. New J. Chem., 2024, 48(40): 17391 doi: 10.1039/D4NJ03598D
25. [25]
  ZHANG L Y, SHI H R, TAN X, JIANG Z Q, WANG P, QIN J L. Ten-gram-scale mechanochemical synthesis of ternary lanthanum coordination polymers for antibacterial and antitumor activities[J]. Front. Chem., 2022, 10: 898324 doi: 10.3389/fchem.2022.898324
26. [26]
  KHAN S A, BHAT S A, NAMI S A A, KAREEM A, NISHAT N. Design and development of several polymeric metal-organic frameworks, spectral characterization, and their antimicrobial activity[J]. C. R. Chim., 2018, 21(9): 872-879 doi: 10.1016/j.crci.2018.07.003
27. [27]
  QIN J, GUO N N, YANG J, CHEN Y. Recent advances of metal-polyphenol coordination polymers for biomedical applications[J]. Biosensors, 2023, 13(8): 776 doi: 10.3390/bios13080776
28. [28]
  COLINAS I R, ROJAS-ANDRADE M D, CHAKRABORTY I, OLIVER S R J. Two structurally diverse Zn-based coordination polymers with excellent antibacterial activity[J]. CrystEngComm, 2018, 20(24): 3353-3362 doi: 10.1039/C8CE00394G
29. [29]
  JAROS S W, KROGUL-SOBCZAK A, BAŻANÓW B, FLOREK M, PORADOWSKI D, NESTEROV D S, ŚLIWIŃSKA-HILL U, KIRILLOV A M, SMOLEŃSKI P. Self-assembly and multifaceted bioactivity of a silver(Ⅰ) quinolinate coordination polymer[J]. Inorg. Chem., 2021, 60(20): 15435-15444 doi: 10.1021/acs.inorgchem.1c02110
30. [30]
  ROGOVOY M I, BEREZIN A S, KOZLOVA Y N, SAMSONENKO D G, ARTEM′EV A V. A layered Ag(Ⅰ)-based coordination polymer showing sky-blue luminescence and antibacterial activity[J]. Inorg. Chem. Commun., 2019, 108: 107513 doi: 10.1016/j.inoche.2019.107513
31. [31]
  YOUNG R J, BEGG S L, COGHLAN C J, MCDEVITT C A, SUMBY C J. Exploring the use of structure and polymer incorporation to tune silver ion release and antibacterial activity of silver coordination polymers[J]. Eur. J. Inorg. Chem., 2018, 30: 3512-3518
32. [32]
  AHADIAT G, TABATABAEE M, GHOLIVAND K, ZARE K, DUŠEK M. A new silver 1D-coordination polymer with bridging 2-aminopyrimidine, synthesis, characterization and antibacterial activity[J]. J. Coord. Chem., 2021, 74(7): 1057-1065 doi: 10.1080/00958972.2021.1896712
33. [33]
  LIU A, WANG C C, WANG C Z, FU H F, PENG W, CAO Y L, CHU H Y, DU A F. Selective adsorption activities toward organic dyes and antibacterial performance of silver-based coordination polymers[J]. J. Colloid Interface Sci., 2018, 512: 730-739 doi: 10.1016/j.jcis.2017.10.099
34. [34]
  GAUDILLAT Q, KRUPP A, ZWINGELSTEIN T, HUMBLOT V, STROHMANN C, JOURDAIN I, KNORR M, VIAU L. Silver-based coordination polymers assembled by dithioether ligands: Potential antibacterial materials despite received ideas[J]. Dalton Trans., 2023, 52(18): 5859-5864 doi: 10.1039/D3DT00683B
35. [35]
  YU H H, HE S X, LU J H, HUANG C, CHEN D M, ZHU B X. Synthesis, crystal structures, photophysical and antibacterial properties of Ag(Ⅰ) and Zn(Ⅱ) coordination polymers based on a flexible bisacylhydrazone ligand[J]. Inorg. Chim. Acta, 2023, 557: 121713 doi: 10.1016/j.ica.2023.121713
36. [36]
  BEHESHTI A, PANAHI F, MAYER P, MOTAMEDI H, PARISI E, CENTORE R. Synthesis, structural characterization, antibacterial activity and selective dye adsorption of silver(Ⅰ)-based coordination polymers by tuning spacer length and binding mode of chromate anion[J]. J. Solid State Chem., 2020, 287: 121322 doi: 10.1016/j.jssc.2020.121322
37. [37]
  WANG J, LI L, HU X Y, ZHOU L L, HU J. pH-responsive on-demand release of eugenol from metal-organic frameworks for synergistic bacterial killing[J]. Dalton Trans., 2024, 53(6): 2826-2832 doi: 10.1039/D3DT04216B
38. [38]
  TRAVLOU N A, ALGARRA M, ALCOHOLADO C. Carbon quantum dot surface-chemistry-dependent Ag release governs the high antibacterial activity of Ag-metal-organic framework composites [J]. ACS Appl. Bio Mater., 2018, 1: 693-707 doi: 10.1021/acsabm.8b00166
39. [39]
  HAO Z, LI X Y, ZHANG R Z, ZHANG L B. Stimuli-responsive hydrogels for antibacterial applications[J]. Adv. Healthc. Mater., 2024, 13(22): DOI10.1002/adhm.202400513 doi: 10.1002/adhm.202400513
40. [40]
  WATANABE G, SEKIYA H, TAMAI E, SAIJO R, UNO H, MORI S, TANAKA T, MAKI J, KAWASE M. Synthesis and antimicrobial activity of 2-trifluoroacetonylbenzoxazole ligands and their metal complexes[J]. Chem. Pharm. Bull., 2018, 66(7): 732-740 doi: 10.1248/cpb.c18-00158
41. [41]
  HUANG R, CAI G Q, LI J, LI X S, LIU H T, SHANG X L, ZHOU J D, NIE X M, GUI R. Platelet membrane-camouflaged silver metal-organic framework drug system against infections caused by methicillin-resistant Staphylococcus aureus[J]. J. Nanobiotechnol., 2021, 19(1): 229 doi: 10.1186/s12951-021-00978-2
42. [42]
  CHENG Z R, FENG Y H. Research progress on graphene oxide nanocomposites in antibacterial application[J]. Materials China, 2025, 44(2): 209-216
43. [43]
  AKHAVAN O, GIHADDERI E, ESFANDIAR A. Wrapping bacteria by graphene nanosheets for isolation from environment, reactivation by sonication, and inactivation by near-infrared irradiation[J]. J. Phys. Chem. B, 2011, 115(19): 6279-6288 doi: 10.1021/jp200686k
44. [44]
  BARBARA M O, EWA R S. Structures and spectroscopic studies of indolecarboxylic acids. Part Ⅲ. Diamminetetrakis-μ-(O, O′-indole-3-carboxylate) dicopper(Ⅱ)[J]. J. Mol. Struct., 2006, 784(1/2/3): 69-77
45. [45]
  HU W, PENG C, LV M, LI X M, ZHANG Y J, CHEN N, FAN C H, HUANG Q. Protein corona-mediated mitigation of cytotoxicity of graphene oxide[J]. ACS Nano, 2011, 5(5): 3693-700 doi: 10.1021/nn200021j
46. [46]
  HE P, YANG M, LEI Y, GUO L, WANG Y, WEI G. Solvent-evaporation-induced synthesis of graphene oxide/peptide nanofiber (GO/PNF) hybrid membranes doped with silver nanoparticles for antibacterial application[J]. Polymers, 2023, 15(5): 1321 doi: 10.3390/polym15051321
47. [47]
  MOSTAFA D F, AHMAD A S, MOHAMMAD S GH, AHMAD R, MASOUD S. A novel nanocomposite with superior antibacterial activity: A silver-based metal organic framework embellished with graphene oxide[J]. Adv. Mater. Interfaces, 2018, 5(11): 1701365 doi: 10.1002/admi.201701365
48. [48]
  CHEN L J, SHAO J, YU Q J, WANG S. High-strength, anti-fatigue, stretchable self-healing polyvinyl alcohol hydrogel based on borate bonds and hydrogen bonds[J]. J. Dispersion Sci. Technol., 2022, 43(5): 690-703 doi: 10.1080/01932691.2020.1844740
49. [49]
  ROSCIARDI V, CHELAZZI D, BAGLIONI P. "Green" biocomposite poly(vinyl alcohol)/starch cryogels as new advanced tools for the cleaning of artifacts[J]. J. Colloid Interface Sci., 2022, 613: 697-708 doi: 10.1016/j.jcis.2021.12.145
50. [50]
  ELMELIGY O, RAHMAN B A, GALAL K. Experimental investigation of the compressive and shear behaviours of grouted and hollow masonry constructed with PVA fibre-reinforced mortar and grout[J]. Constr. Build. Mater., 2024, 415: 134954 doi: 10.1016/j.conbuildmat.2024.134954
51. [51]
  XIE Y J, CAI P X, CAO X F, PAN Y F. High-strength, water-resistant polyvinyl alcohol films reinforced with regenerated cellulose fibers for food packaging[J]. Ind. Crop. Prod., 2024, 207: 117768 doi: 10.1016/j.indcrop.2023.117768
52. [52]
  IQBAL M, ZAFAR H, MAHMOOD A, NIAZI M B K, ASLAM M W. Starch-capped silver nanoparticles impregnated into propylamine-substituted PVA films with improved antibacterial and mechanical properties for wound-bandage applications[J]. Polymers, 2020, 12(9): 2112 doi: 10.3390/polym12092112
53. [53]
  FATEMA U K, RAHMAN M M, ISLAM M R, MOLLAH M Y A, SUSAN MD A B H. Silver/poly(vinyl alcohol) nanocomposite film prepared using water in oil microemulsion for antibacterial applications[J]. J. Colloid Interface Sci., 2018, 514: 648-655 doi: 10.1016/j.jcis.2017.12.084
54. [54]
  WEN H Y, HSU Y I, ASOH T A, UYAMA H. Antioxidant activity and physical properties of pH-sensitive biocomposite using poly (vinyl alcohol) incorporated with green tea extract[J]. Polym. Degrad. Stabil., 2020, 178: 109215 doi: 10.1016/j.polymdegradstab.2020.109215
55. [55]
  WANG Z Q, ZHAO S L, HONG L, HUANG J T. Preparation and properties of silver-based cellulose/polyvinyl alcohol antibacterial materials[J]. J. Inorg. Organomet. Polym. Mater., 2020, 30(11): 4382-4393 doi: 10.1007/s10904-020-01669-5
56. [56]
  CHEN S C, ZHANG Z H, CHEN Q, WANG L Q, XU J, HE M Y, DU M, YANG X P, JONES R A. An efficient strategy to achieve hydrophilic polymeric silver(Ⅰ) materials with exceptional antibacterial activity[J]. Chem. Commun., 2013, 49(13): 1270-1272 doi: 10.1039/C2CC36538C
57. [57]
  HAN J, CHEN Y X, YU Z, LI S, WAN Y. Syntheses and antimicrobial activities of two coordination polymers assembled with Ag—N and Ag—O bonds[J]. Inorg. Chim. Acta, 2024, 572: 122290 doi: 10.1016/j.ica.2024.122290
58. [58]
  YOUSRI A, HAUKKA M, ABU-YOUSSEF M A M, AYOUP M S, ISMAIL M M F, EL MENOFY N G, SOLIMAN S M, BARAKAT A, AMOMBO NOA F M, ÖHRSTRÖM L. Synthesis, structure diversity, and antimicrobial studies of Ag(Ⅰ) complexes with quinoline-type ligands[J]. CrystEngComm, 2023, 25(27): 3922-3930 doi: 10.1039/D3CE00417A
59. [59]
  REHMAN H, ALI Z, SHAHZADY T G, ABID M, NAZIR S, HUSSAIN H, ZAHRA A, HUSSAIN I. Synthesis, X-ray analysis and antibacterial study of silver complex with ethyl-5-hydroxy-2-oxo-2H-chromene-3-carboxylate[J]. Bull. Chem. Soc. Ethiop., 2019, 33(3): 467-474 doi: 10.4314/bcse.v33i3.7
1. [1]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
2. [2]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
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4. [4]
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5. [5]
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7. [7]
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8. [8]
  Weijie Yang , Mansheng Chen , Chen Xu , Fujian Xu . Hydroxyl-Rich Polycations: Innovative Materials Empowering Life and Health. University Chemistry, 2025, 40(9): 332-343. doi: 10.12461/PKU.DXHX202410072
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  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
10. [10]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
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13. [13]
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  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
15. [15]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
16. [16]
  Jingjie Tang , Luying Xie , Jiayu Liu , Shangyu Shi , Xinyu Sun , Jiayang Lin , Qikun Yang , Chuan'ang Yu , Zecheng Wang , Yingying Wang , Zengyang Xie . Efficient Rapid Synthesis and Antibacterial Activities of Tosylhydrazones: A Recommended Innovative Chemistry Experiment for Undergraduate Medical University. University Chemistry, 2024, 39(3): 316-326. doi: 10.3866/PKU.DXHX202309091
17. [17]
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18. [18]
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沈阳化工大学材料科学与工程学院沈阳 110142