Citation: Jing FENG, Renshu WANG, Hu WANG, Hailong LIU. Co(Ⅱ) and Ni(Ⅱ) complexes of 3,3-diphenylpropionic acid and 2,2′-dipyridylamine: Structures and biological activities[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(3): 617-631. doi: 10.11862/CJIC.20250265 shu

Co(Ⅱ) and Ni(Ⅱ) complexes of 3,3-diphenylpropionic acid and 2,2′-dipyridylamine: Structures and biological activities

School of Chemistry and Materials Engineering, Liupanshui Normal University, Liupanshui, Guizhou 553004, China

Corresponding author: Renshu WANG, wangrenshu@lpssy.edu.cn
Received Date: 13 August 2025
Revised Date: 16 November 2025

Figures(10)

Two Co(Ⅱ) and Ni(Ⅱ) complexes were synthesized by synergistic coordination of 3,3-diphenylpropionic acid (HDPA) and 2,2′-bipyridylamine (PAm). The structures of complexes [Co(DPA)₂(PAm)]·2H₂O (1) and [Ni(DPA)₂(PAm)]·2H₂O (2) were determined by single-crystal X-ray diffraction, IR spectroscopy, and powder X-ray diffraction. Hirshfeld surface analysis provided quantitative insights into the intermolecular interactions within the complexes, while molecular docking studies elucidated their binding modes and affinities toward urease. Furthermore, the biological activities of both complexes were systematically evaluated through a range of assays, including DNA binding, urease inhibition, antibacterial activity, and in vitro cytotoxicity against cancer cells. Both complexes exhibited binding affinity for DNA and displayed notable urease inhibitory activity. Under in vitro conditions, both complexes showed appreciable cytotoxicity toward HepG2 cells with efficacy comparable to clinically used platinum-based anticancer agents.
- crystal structure,
- computational analysis,
- urease inhibition,
- antibacterial activity,
- cytotoxicity
1. [1]
  PAKULA R J, BERRY J F. Cobalt complexes of the chelating dicarboxylate ligand "esp": A paddlewheel-type dimer and a heptanuclear coordination cluster[J]. Dalton Trans., 2018, 47(39): 13887-13893 doi: 10.1039/C8DT03030H
2. [2]
  BIÇER F A, ARICI M, YEŞILEL O Z. Syntheses, characterization of three new cobalt(Ⅱ) complexes with 2-phenylsuccinic acid and flexible bis(imidazole) linkers[J]. J. Mol. Struct., 2023, 1284: 135444 doi: 10.1016/j.molstruc.2023.135444
3. [3]
  YEŞILEL O Z, GÜLER U, ÇIFTÇI E, ARICI M. A series of coordination polymers constructed by 2-phenylsuccinic acid and flexible bis(imidazole) ligands: Syntheses, structures, and photoluminescent properties[J]. J. Mol. Struct., 2022, 1262: 132991 doi: 10.1016/j.molstruc.2022.132991
4. [4]
  HO P H, HUNG C C, WANG Y H, CHUANG G J. Intermolecular nitrene insertion by bimetallic catalysts[J]. Asian J. Org. Chem., 2019, 8(2): 275-278 doi: 10.1002/ajoc.201800641
5. [5]
  PAKULA R J, MARTINEZ A M, NOTEN E A, HARRIS C F, BERRY J F. New chromium, molybdenum, and cobalt complexes of the chelating esp ligand[J]. Polyhedron, 2019, 161: 93-103 doi: 10.1016/j.poly.2018.12.045
6. [6]
  SKIPPER H E, MAY C V, RHEINGOLD A L, DOERRER L H, KAMENETSKA M. Hard-soft chemistry design principles for predictive assembly of single molecule-metal junctions[J]. J. Am. Chem. Soc., 2021, 143(40): 16439-16447 doi: 10.1021/jacs.1c05142
7. [7]
  ZAVAKHINA M S, SAMSONENKO D G, DYBTSEV D N, FEDIN V P. Rigid 1D coordination polymers with tunable metal cation and chiral pendant moieties[J]. Z. Anorg. Allg. Chem., 2015, 641(3/4): 590-595
8. [8]
  FERNÁNDEZ C Y, ALVAREZ N, ROCHA A, MENDES L F S, COSTA-FILHO A J, ELLENA J, BATISTA A A, FACCHIN G. Phenanthroline and phenyl carboxylate mixed ligand copper complexes in developing drugs to treat cancer[J]. J. Inorg. Biochem., 2024, 260: 112700 doi: 10.1016/j.jinorgbio.2024.112700
9. [9]
  ARUN P P, PATEL R R, SINGH S K, PARMAR K, SINGH M. Exploring metal complexes for cancer treatment: Mechanistic insights and therapeutic potential[J]. J. Organomet. Chem., 2025, 1035: 123682 doi: 10.1016/j.jorganchem.2025.123682
10. [10]
  HAMER H M, JONKERS D, VENEMA K, VANHOUTVIN S, TROOST F J, BRUMMER R J. Review article: The role of butyrate on colonic function[J]. Aliment. Pharmacol. Ther., 2008, 27(2): 104-119 doi: 10.1111/j.1365-2036.2007.03562.x
11. [11]
  PAUTOVA A K, BURNAKOVA N A, BELOBORODOVA N V, REVELSKY A I. Simultaneous determination of aromatic, short-chain fatty and dicarboxylic acids in blood serum and cerebrospinal fluid by gas chromatography-mass spectrometry[J]. J. Anal. Chem., 2023, 78(14): 1942-1954 doi: 10.1134/S1061934823140058
12. [12]
  HAYS K E, PFAFFINGER J M, RYZNAR R. The interplay between gut microbiota, short-chain fatty acids, and implications for host health and disease[J]. Gut Microbes, 2024, 16(1): 2393270 doi: 10.1080/19490976.2024.2393270
13. [13]
  AL-LAHHAM S H, PEPPELENBOSCH M P, ROELOFSEN H, VONK R J, VENEMA K. Biological effects of propionic acid in humans; metabolism, potential applications and underlying mechanisms[J]. Biochim. Biophys. Acta Mol. Cell Biol. Lipids, 2010, 1801(11): 1175-1183
14. [14]
  COLLADO M S, ARMSTRONG A J, OLSON M, HOANG S A, DAY N, SUMMAR M, CHAPMAN K A, REARDON J, FIGLER R A, WAMHOFF B R. Biochemical and anaplerotic applications of in vitro models of propionic acidemia and methylmalonic acidemia using patient-derived primary hepatocytes[J]. Mol. Genet. Metab., 2020, 130(3): 183-196 doi: 10.1016/j.ymgme.2020.05.003
15. [15]
  YANG Y L, LIU C M, ZHAO W Y, MAZARJI M, REN L H, LIU C, PAN J T, YAN B H. Anaerobic propionic acid production via succinate pathway at extremely low pH[J]. Chem. Eng. J., 2024, 486: 150190 doi: 10.1016/j.cej.2024.150190
16. [16]
  LOREFICE L, ZOLEDZIEWSKA M. Propionic acid impact on multiple sclerosis: Evidence and challenges[J]. Nutrients, 2024, 16(22): 3887 doi: 10.3390/nu16223887
17. [17]
  WANG Y N, LI M J, GUO J Y, KANG S G, HUANG K L, TONG T. Olfr78, a novel short-chain fatty acid receptor, regulates glucose homeostasis and gut GLP-1 secretion in mice[J]. Food Frontiers, 2023, 4(4): 1893-1912 doi: 10.1002/fft2.301
18. [18]
  FOLEY K A, MACFABE D F, VAZ A, OSSENKOPP K P, KAVALIERS M. Sexually dimorphic effects of prenatal exposure to propionic acid and lipopolysaccharide on social behavior in neonatal, adolescent, and adult rats: Implications for autism spectrum disorders[J]. Int. J. Dev. Neurosci., 2014, 39(1): 68-78 doi: 10.1016/j.ijdevneu.2014.04.001
19. [19]
  RETA G F, TONN C E, RÍOS-LUCI C, LEÓN L G, PÉREZ-ROTH E, PADRÓN J M, DONADEL O J. Cytotoxic bioactivity of some phenylpropanoic acid derivatives[J]. Nat. Prod. Commun., 2012, 7(10): 1341-1346
20. [20]
  KINRA M, JOSEPH A, NAMPOOTHIRI M, ARORA D, MUDGAL J. Inhibition of NLRP3-inflammasome mediated IL-1β release by phenylpropanoic acid derivatives: In-silico and in-vitro approach[J]. Eur. J. Pharm. Sci., 2021, 157: 105637 doi: 10.1016/j.ejps.2020.105637
21. [21]
  AYYADURAI G K, JAYAPRAKASH R, SHAJAHAN A, RATHIKA S. Studies on 2-((2, 4-dihydroxybenzylidene) amino)-3-phenylpropanoic acid include antimicrobial, antidiabetic, antioxidant, anticancer, hemolysis, and theoretical QSAR[J]. J. Biomol. Struct. Dyn., 2025, 43(6): 2864-2876 doi: 10.1080/07391102.2023.2294383
22. [22]
  GENÇER H K, ÇEVIK U A, KAYA ÇAVUŞOĞLU B K, SAĞLIK B N, LEVENT S, ATLI Ö, ILGIN S, ÖZKAY Y, KAPLANCIKLI Z A. Design, synthesis, and evaluation of novel 2-phenylpropionic acid derivatives as dual COX inhibitory-antibacterial agents[J]. J. Enzym. Inhib. Med. Chem., 2017, 32(1): 732-745 doi: 10.1080/14756366.2017.1310726
23. [23]
  YEHIA R S, OSMAN G H, ASSAGGAF H, SALEM R, MOHAMED M S M. Isolation of potential antimicrobial metabolites from endophytic fungus Cladosporium cladosporioides from endemic plant Zygophyllum mandavillei[J]. S. Afr. J. Bot., 2020, 134: 296-302 doi: 10.1016/j.sajb.2020.02.033
24. [24]
  URBANI P, RAMUNNO A, FILOSA R, PINTO A, POPOLO A, BIANCHINO E, PIOTTO S, SATURNINO C, DE PRISCO R, NICOLAUS B, TOMMONARO G. Antioxidant activity of diphenylpropionamide derivatives: Synthesis, biological evaluation and computational analysis[J]. Molecules, 2008, 13(4): 749-761 doi: 10.3390/molecules13040749
25. [25]
  SWANNER E D, PLANAVSKY N J, LALONDE S V, ROBBINS L J, BEKKER A, ROUXEL O J, SAITO M A, KAPPLER A, MOJZSIS S J, KONHAUSER K O. Cobalt and marine redox evolution[J]. Earth Planet. Sci. Lett., 2014, 390: 253-263 doi: 10.1016/j.epsl.2014.01.001
26. [26]
  DING J, WEI Z M, LI F H, ZHANG J C, ZHANG Q, ZHOU J, WANG W J, LIU Y H, ZHANG Z, SU X Z, YANG R Z, LIU W, SU C L, YANG H B, HUANG Y Q, ZHAI Y M, LIU B. Atomic high-spin cobalt(Ⅱ) center for highly selective electrochemical CO reduction to CH₃OH[J]. Nat. Commun., 2023, 14(1): 6550 doi: 10.1038/s41467-023-42307-1
27. [27]
  LEONARD S, M. GANNETT P, ROJANASAKUL Y, SCHWEGLER-BERRY D, CASTRANOVA V, VALLYATHAN V, SHI X L. Cobalt-mediated generation of reactive oxygen species and its possible mechanism[J]. J. Inorg. Biochem., 1998, 70(3/4): 239-244
28. [28]
  MANIKANDAN R, VISWANATHAMURTHI P, VELMURUGAN K, NANDHAKUMAR R, HASHIMOTO T, ENDO A. Synthesis, characterization and crystal structure of cobalt􀃮 complexes containing 2-acetylpyridine thiosemicarbazones: DNA/protein interaction, radical scavenging and cytotoxic activities[J]. J. Photochem. Photobiol. B‒Biol., 2014, 130: 205-216 doi: 10.1016/j.jphotobiol.2013.11.008
29. [29]
  BANERJEE R, GHERASIM C, PADOVANI D. The tinker, tailor, soldier in intracellular B12 trafficking[J]. Curr. Opin. Chem. Biol., 2009, 13(4): 484-491 doi: 10.1016/j.cbpa.2009.07.007
30. [30]
  GIEDYK M, GOLISZEWSKA K, GRYKO D. Vitamin B₁₂ catalysed reactions[J]. Chem. Soc. Rev., 2015, 44(11): 3391-3404 doi: 10.1039/C5CS00165J
31. [31]
  GRUBER K, PUFFER B, KRÄUTLER B. Vitamin B12-derivatives—Enzyme cofactors and ligands of proteins and nucleic acids[J]. Chem. Soc. Rev., 2011, 40(8): 4346-4363 doi: 10.1039/c1cs15118e
32. [32]
  GREGOROWICZ W, PAJCHEL L. The role of cobalt ions in angiogenesis—A review[J]. Int. J. Mol. Sci., 2025, 26(15): 7236 doi: 10.3390/ijms26157236
33. [33]
  BOER J L, MULROONEY S B, HAUSINGER R P. Nickel-dependent metalloenzymes[J]. Arch. Biochem. Biophys., 2014, 544: 142-152 doi: 10.1016/j.abb.2013.09.002
34. [34]
  RAGSDALE S W. Nickel-based enzyme systems[J]. J. Biol. Chem., 2009, 284(28): 18571-18575 doi: 10.1074/jbc.R900020200
35. [35]
  LIU Y C, LUO X M, PENG Y D, CAI L. Cardio-metabolic effects of nickel: A narrative review[J]. Cardiovasc. Toxicol., 2025, 25(7): 944-954 doi: 10.1007/s12012-025-10014-6
36. [36]
  ZAMBELLI B, UVERSKY V N, CIURLI S. Nickel impact on human health: An intrinsic disorder perspective[J]. BBA‒Proteins Proteomics, 2016, 1864(12): 1714-1731 doi: 10.1016/j.bbapap.2016.09.008
37. [37]
  SRIVASTAVA A K, SNAPPER D M, ZHENG J W, YILDRIM B S, SRIVASTAVA S, WOOD S C. Examining the role of nickel and NiTi nanoparticles promoting inflammation and angiogenesis[J]. J. Immunotoxicol., 2022, 19(1): 61-73 doi: 10.1080/1547691X.2022.2080307
38. [38]
  YANG J F, FENG P Y, LING Z M, KHAN A, WANG X, CHEN Y L, ALI G, FANG Y T, SALAMA E S, WANG X M, LIU P, LI X K. Nickel exposure induces gut microbiome disorder and serum uric acid elevation[J]. Environ. Pollut., 2023, 324: 121349 doi: 10.1016/j.envpol.2023.121349
39. [39]
  MARET W. Metalloproteomics, metalloproteomes, and the annotation of metalloproteins[J]. Metallomics, 2010, 2(2): 117-125 doi: 10.1039/B915804A
40. [40]
  ZHANG L, JIANG C, GUO L F, ZHANG X L, LIN X Q, KANG J, SUN W M. Synthesis, characterization, antitumor activity, and theoretical calculations of Co(Ⅱ) complex based on pyridine-2, 6-dicarboxylic acid[J]. Chinese J. Inorg. Chem., 2021, 37(2): 368-374
41. [41]
  LOUBALOVÁ I, KOPEL P. Coordination compounds of Cu, Zn, and Ni with dicarboxylic acids and N donor ligands, and their biological activity: A review[J]. Molecules, 2023, 28(3): 1445 doi: 10.3390/molecules28031445
42. [42]
  RUTA L L, FARCASANU I C, BACALUM M, RĂILEANU M, ROSTAS A M, DANILIUC C, CHIFIRIUC M C, MĂRUȚESCU L, POPA M, BADEA M, IORGULESCU E E, OLAR R. Biological activity of triazolopyrimidine copper(Ⅱ) complexes modulated by an auxiliary N-N-chelating heterocycle ligands[J]. Molecules, 2021, 26(22): 6772 doi: 10.3390/molecules26226772
43. [43]
  TAO Q, WU J, GE C, WANG M M, LÜ M D, XUE X L, LIU H K. Synthesis, characterization, fluorescence and interactions with DNA/BSA properties of ruthenium ferulate complexes[J]. Chinese J. Inorg. Chem., 2020, 36(10): 1853-1864
44. [44]
  JAHANI S, KHORASANI-MOTLAGH M, NOROOZIFAR M. DNA interaction of europium􀃮 complex containing 2,2′-bipyridine and its antimicrobial activity[J]. J. Biomol. Struct. Dyn., 2016, 34(3): 612-624 doi: 10.1080/07391102.2015.1048481
45. [45]
  PERONTSIS S, DIMITRIOU A, FOTIADOU P, HATZIDIMITRIOU A G, PAPADOPOULOS A N, PSOMAS G. Cobalt(Ⅱ) complexes with the non-steroidal anti-inflammatory drug diclofenac and nitrogen-donor ligands[J]. J. Inorg. Biochem., 2019, 196: 110688 doi: 10.1016/j.jinorgbio.2019.04.002
46. [46]
  DU L Q, CHEN Z X, WEI Q C, CHEN Z L, YANG Y. Chlorquinaldol-zinc(Ⅱ)-bipyridine complexes: Design, synthesis, structure and anticancer evaluation[J]. Inorg. Chem. Commun., 2023, 156: 111238 doi: 10.1016/j.inoche.2023.111238
47. [47]
  MESSINA M A, MAUGERI L, FORTE G, RUGGIERI M, PETRALIA S. A highly sensitive colorimetric approach based on tris (bipyridine) ruthenium (Ⅱ/Ⅲ) mediator for the enzymatic detection of phenylalanine[J]. Front. Chem., 2023, 11: 1164014 doi: 10.3389/fchem.2023.1164014
48. [48]
  CHEN Z Q, ZHANG X B, PENG C, WANG J A, XU Z J, CHEN K X, SHI J Y, ZHU W L. D3Pockets: A method and web server for systematic analysis of protein pocket dynamics[J]. J. Chem. Inf. Model., 2019, 59(8): 3353-3358 doi: 10.1021/acs.jcim.9b00332
49. [49]
  CHEN T, LIAO X, GAO L E. Hydrogen bonding and Hirshfeld surface analysis of gallic acid and its monohydrate based on terahertz spectroscopy[J]. Chem. Phys., 2024, 578: 112159 doi: 10.1016/j.chemphys.2023.112159
50. [50]
  YUAN H, XUE B, YANG D Y, RENCUS-LAZAR S, CAO Y, GAZIT E, TAN D, YANG R S. Rational design of biological crystals with enhanced physical properties by hydrogen bonding interactions[J]. Research, 2023, 6: 0046 doi: 10.34133/research.0046
51. [51]
  PHAN C Y, SHEN J, YU K X, LIU J Y, TANG G P. Hydrogen bonds, topologies, energy frameworks and solubilities of five sorafenib salts[J]. Int. J. Mol. Sci., 2021, 22(13): 6682 doi: 10.3390/ijms22136682
52. [52]
  SARANYA K, MUHILDHARANI E, RAJA C R. Growth, structural confirmation and the effect of hydrogen bond on the third-order nonlinear optical properties of diisopropylammonium 4-aminobenzenesulfonate crystal[J]. J. Mater. Sci. ‒Mater. Electron., 2023, 34(7): 661 doi: 10.1007/s10854-023-10088-4
53. [53]
  PRAJAPATI P, PANDEY J, TANDON P, SINHA K, SHIMPI M R. Molecular structural, hydrogen bonding interactions, and chemical reactivity studies of ezetimibe-L-proline cocrystal using spectroscopic and quantum chemical approach[J]. Front. Chem., 2022, 10: 848014 doi: 10.3389/fchem.2022.848014
54. [54]
  LI C J, LI R Y, CHU Z T, LIU H T, LU J, WANG S N, LI Y W. Synthesis, structure and proton conduction of a crystalline Ni(Ⅱ)-MOF with continuous hydrogen bonds[J]. Chinese J. Inorg. Chem., 2021, 37(4): 645-652
55. [55]
  PUNIYA R R, TAKHAR P, CHHAPOLIYA M, DEKA R, KALITA D J, SINGH D. Development of photoluminescent hydrogen-bonded frameworks based on pyromellitic diimide-tethered carboxylic acid hosts and multi-bonding solvent guests[J]. Mater. Adv., 2024, 5(19): 7817-7829 doi: 10.1039/D4MA00634H
56. [56]
  MAHAPATRA A D, SHAIK A, THIRUVENKATAM V, DATTA B. Supramolecular architecture in sulfonylurea, sulfonyldiurea and sulfonyltriurea drugs: Synthesis, X-ray structure and Hirshfeld surface analysis[J]. J. Mol. Struct., 2021, 1233: 130158 doi: 10.1016/j.molstruc.2021.130158
57. [57]
  LEÓN A C D, ECHEVERRÍA G A, PIRO O E, ULIC S E, JIOS J L, TAPIA L C A, GUZMÁN M M F. New thiourea and urea derivatives containing trifluoromethyl- and bis-triflouromethyl-4H-chromen-3-yl substituents[J]. Mol. Phys., 2019, 117(3): 368-381 doi: 10.1080/00268976.2018.1514132
58. [58]
  FEIJOO M G, FERNÁNDEZ-LIENCRES M P, GIL D M, GÓMEZ M I, ALTABEF A B, NAVARRO A, TUTTOLOMONDO M E. A detailed study of intermolecular interactions, electronic and vibrational properties of the metal complex bis(uracilato)diammine copper(Ⅱ) dihydrate[J]. J. Mol. Struct., 2018, 1155: 424-433 doi: 10.1016/j.molstruc.2017.11.030
59. [59]
  WEI Q, DONG J F, LI W B, ZHAO P R, DING F F, LI L Z. Syntheses, crystal structures, DNA interactions and SOD activities of two nickel(Ⅱ) complexes with L-histidine Schiff base[J]. Chinese J. Inorg. Chem., 2016, 32(05): 789-798
60. [60]
  FERNÁNDEZ C Y, ROCHA A, AZAM M, ALVAREZ N, MIN K, BATISTA A A, COSTA-FILHO A J, ELLENA J, FACCHIN G. Synthesis, characterization, DNA binding and cytotoxicity of copper(Ⅱ) phenylcarboxylate complexes[J]. Inorganics, 2023, 11(10): 398 doi: 10.3390/inorganics11100398
61. [61]
  ALEM M B, DAMENA T, DESALEGN T, KOOBOTSE M, ESWARAMOORTHY R, NGWIRA K J, OMBITO J O, ZACHARIAH M, DEMISSIE T B. Cytotoxic mixed-ligand complexes of Cu(Ⅱ): A combined experimental and computational study[J]. Front. Chem., 2022, 10: 1028957 doi: 10.3389/fchem.2022.1028957
62. [62]
  PEÑA Q, SCIORTINO G, MARÉCHAL J D, BERTAINA S, SIMAAN A J, LORENZO J, CAPDEVILA M, BAYÓN P, IRANZO O, PALACIOS Ò. Copper(Ⅱ) N, N, O-chelating complexes as potential anticancer agents[J]. Inorg. Chem., 2021, 60(5): 2939-2952 doi: 10.1021/acs.inorgchem.0c02932
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14. [14]
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15. [15]
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16. [16]
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沈阳化工大学材料科学与工程学院沈阳 110142