Citation: Xiuli HAO, Chenhao ZHANG, Chenkun FENG, Haolin HAN, Xudong ZHAO, Guoliang SHI. Synthesis, characterization, and ion exchange properties of octamolybdate-based Cu(Ⅱ) coordination polymer[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(4): 883-896. doi: 10.11862/CJIC.20250248 shu

Synthesis, characterization, and ion exchange properties of octamolybdate-based Cu(Ⅱ) coordination polymer

College of Chemical Engineering and Technology, Taiyuan University of Science and Technology, Taiyuan 030024, China

Corresponding author: Xiuli HAO, haoxiuli1@163.com Guoliang SHI, glshi@tyust.edu.cn
Received Date: 30 July 2025
Revised Date: 12 January 2026

Figures(14)

The ionothermal reaction between CuCl₂, 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (BBTZ), and (NH₄)₆Mo₇O₂₄ in 1-ethyl-3-methylimidazolium bromide ((Emim)Br) led to a new octamolybdate-based coordination polymer (Emim)₂[Cu(BBTZ)₂(β-Mo₈O₂₆)] (Mo₈-CP). Mo₈-CP was characterized by elemental analysis, thermogravimetry, IR, powder X-ray diffraction, and single-crystal X-ray diffraction. In Mo₈-CP, structural analysis reveals that Cu coordinates with BBTZ ligands to form an interlocked 1D chain. These chains are further bridged by (β-Mo₈O₂₆)^4- to construct a 3D coordination polymer. Notably, (Emim)⁺ acts as a structure-directing agent, occupying the channels of the 3D coordination polymer. Based on this unique structure, the ion exchange properties of Mo₈-CP toward rare-earth ions were investigated. It has been found that the luminescent color of the material can be successfully regulated by introducing Eu³⁺ or Tb³⁺ through ion exchange.
- octamolybdate,
- coordination polymer,
- ion exchange property,
- fluorescent materials
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