Citation: Qin′ai FENG, Jianjun LI, Lili ZHANG, Linxin WU, Huiling WANG, Wenjing HOU, Lei WANG, Mingjie REN. Amphiphilic surface modification of magnetic adsorbents and its adsorption properties of two microplastics[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(4): 789-807. doi: 10.11862/CJIC.20250208 shu

Amphiphilic surface modification of magnetic adsorbents and its adsorption properties of two microplastics

  • Corresponding author: Jianjun LI, lijj3@aust.edu.cn
  • Received Date: 12 November 2025
    Revised Date: 3 February 2026

Figures(20)

  • This study fabricated an amphiphilic magnetic composite Fe3O4/rGO/PDA (polydopamine)/SDBS/HSB, denoted as FGPSH, via a one-step solvothermal method followed by multi-surface modification. The composite was constructed using Fe3O4 and reduced graphene oxide (rGO) as core materials, grafted with dopamine hydrochloride (DA), sodium dodecylbenzenesulfonate (SDBS), and hexadecyl dimethyl hydroxypropyl sulfonated betaine (HSB1618). Its adsorption behavior toward polyvinyl chloride (PVC) and polyethylene terephthalate (PET) microplastics (MPs) in aqueous solutions was systematically investigated. Results showed that FGPSH exhibited a nanoporous spherical structure with an average particle size of 426.15 nm and an average pore size of 33.02 nm. It displayed excellent superparamagnetism, with a saturation magnetization of 44.15 emu·g-1, enabling efficient magnetic separation. The multilayer surface modification imparts both hydrophilic and hydrophobic properties, allowing high dispersibility in water while offering matched adsorption sites for MPs of different polarities, thereby achieving broad-spectrum and selective adsorption. Under optimized conditions (initial MPs mass concentration: 25 mg·L-1 for both PVC and PET; solution pH: 9.0; FGPSH dosage: 0.50 g·L-1 for PVC and 0.40 g·L-1 for PET; adsorption time: 30 min for PVC and 80 min for PET), the adsorption rates for PVC and PET reached 97.58% and 95.30%, respectively, with equilibrium capacities of 48.75 and 60.33 mg·g-1. After five adsorption-desorption cycles, the material maintained an adsorption efficiency exceeding 85%. Thermodynamic studies indicated that the adsorption of hydrophilic PVC followed pseudo-second-order kinetics and the Freundlich model, whereas the adsorption of hydrophobic PET conformed to the Langmuir model, reflecting distinct adsorption mechanisms based on MPs polarity.
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