Citation: Yanzhe WANG, Xiaoming GUO, Qiangsheng GUO, Liang LI, Bin LU, Peihang YE. Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO₂ methanation[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(11): 2218-2228. doi: 10.11862/CJIC.20250202 shu

Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO₂ methanation

Faculty of Chemical Engineering and Energy Technology, Shanghai Institute of Technology, Shanghai 201418, China

Corresponding author: Xiaoming GUO, guoxiaoming@sit.edu.cn Liang LI, lilianglcx@sit.edu.cn
Received Date: 12 June 2025
Revised Date: 21 July 2025

Figures(9)

A series of NiAlCe_x (x=0.1, 0.2, 0.4, 0.6, x was the ratio of the amount of substance of Ni to that of Al and Ce combined) catalysts was prepared with the co-precipitation method and applied for the CO₂ methanation. The low-temperature catalytic activity of NiAl catalysts for CO₂ methanation improved significantly with the introduction of an appropriate amount of Ce. The CO₂ conversion reached 80.6% as x=0.2 under the conditions of 220 ℃, 100 kPa, and weight hourly space velocity of 24 000 mL·g^-1·h^-1. The incorporation of Ce weakened the Ni-Al interaction, suppressed the formation of NiAl₂O₄ spinel, and promoted the reduction of NiO species in the catalyst. Furthermore, it increased the specific surface area of metallic Ni, thereby facilitating H₂ adsorption and activation, while also enhancing the number of basic sites on the catalyst surface to promote CO₂ adsorption and activation. Stability tests demonstrated that the presence of Ce hindered the sintering and agglomeration of Ni species, thereby enhancing the catalyst stability. In‑situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) results revealed that the reaction over NiAl catalyst followed the CO intermediate route, and after introducing Ce into the NiAl catalyst, a dual pathway involving both formate and CO intermediates was observed.
- CO₂ methanation,
- NiAl catalyst,
- CeO₂,
- Ni specific surface area,
- reaction pathway
1. [1]
  KIM C, YOO C J, OH H S, MIN B K, LEE U. Review of carbon dioxide utilization technologies and their potential for industrial application[J]. J. CO2 Util., 2022,65102239. doi: 10.1016/j.jcou.2022.102239
2. [2]
  VALLURI S, CLAREMBOUX V, KAWATRA S. Opportunities and challenges in CO₂ utilization[J]. J. Environ. Sci., 2022,113:322-344. doi: 10.1016/j.jes.2021.05.043
3. [3]
  MEBRAHTU C, KREBS F, ABATE S, PERATHONER S, CENTI G, PALKOVITS R. CO₂ methanation: Principles and challenges[M]// ALBONETTI S, PERATHONER S, QUADRELLI E A. Studies in surface science and catalysis: Vol. 178. [S. l. ]: Elsevier, 2019: 85-103
4. [4]
  ASHOK J, PATI S, HONGMANOROM P, ZHANG T X, CHEN J M, KAWI S. A review of recent catalyst advances in CO₂ methanation processes[J]. Catal. Today, 2020,356:471-489. doi: 10.1016/j.cattod.2020.07.023
5. [5]
  GHAIB K, BEN-FARES F Z. Power-to-methane: A state-of-the-art review[J]. Renew. Sust. Energ. Rev., 2018,81:433-446. doi: 10.1016/j.rser.2017.08.004
6. [6]
  BUKHARI M H, JAVED A, KAZMI S A A, ALI M, CHAUDHARY M T. Techno-economic feasibility analysis of hydrogen production by PtG concept and feeding it into a combined cycle power plant leading to sector coupling in future[J]. Energy Conv. Manag., 2023,282116814. doi: 10.1016/j.enconman.2023.116814
7. [7]
  YANG C Y, ZHANG T Y, CHEN Y S, WANG W J, ZHUO H Y, YANG X F, HUANG Y Q. Intrinsic mechanism for carbon dioxide methanation over Ru-based nanocatalysts[J]. ACS Catal., 2023,13(17):11556-11565. doi: 10.1021/acscatal.3c02502
8. [8]
  NOVÁK É, FODOR K, SZAILER T, OSZKÓ A, ERDÖHELYI A. CO₂ hydrogenation on Rh/TiO₂ previously reduced at different temperatures[J]. Top. Catal., 2002,20:107-117. doi: 10.1023/A:1016359601399
9. [9]
  LIU J, BING W H, XUE X G, WANG F, WANG B, HE S, ZHANG Y K, WEI M. Alkaline-assisted Ni nanocatalysts with largely enhanced low‑temperature activity toward CO₂ methanation[J]. Catal. Sci. Technol., 2016,6(11):3976-3983. doi: 10.1039/C5CY02026C
10. [10]
  BACARIZA M C, BÉRTOLO R, GRAÇA I, LOPES J M, HENRIQUES C. The effect of the compensating cation on the catalytic performances of Ni/USY zeolites towards CO₂ methanation[J]. J. CO2 Util., 2017,21:280-291. doi: 10.1016/j.jcou.2017.07.020
11. [11]
  BACARIZA M C, GRAÇA I, BEBIANO S S, LOPES J M, HENRIQUES C. Magnesium as promoter of CO₂ methanation on Ni-based USY zeolites[J]. Energy Fuels, 2017,31(9):9776-9789. doi: 10.1021/acs.energyfuels.7b01553
12. [12]
  LIANG C F, HU X, WEI T, JIA P, ZHANG Z M, DONG D H, ZHANG S, LIU Q, HU G Z. Methanation of CO₂ over Ni/Al₂O₃ modified with alkaline earth metals: Impacts of oxygen vacancies on catalytic activity[J]. Int. J. Hydrog. Energy, 2019,44(16):8197-8213. doi: 10.1016/j.ijhydene.2019.02.014
13. [13]
  GARBARINO G, KOWALIK P, RIANI P, ANTONIAK‑JURAK K, PIETA P, LEWALSKA‑GRACZYK A, LISOWSKI W, NOWAKOWSKI R, BUSCA G, PIETA I S. Improvement of Ni/Al₂O₃ catalysts for low-temperature CO₂ methanation by vanadium and calcium oxide addition[J]. Ind. Eng. Chem. Res., 2021,60(18):6554-6564. doi: 10.1021/acs.iecr.0c05556
14. [14]
  ZHANG Z Q, DENG S R, FANG X Z, XU J W, XU X L, WANG X. CrO_x-promoted Ru/Al₂O₃ for CO₂ methanation: Formation of surface Cr-doped RuO₂ solid solution plays key roles[J]. Fuel, 2023,339127414. doi: 10.1016/j.fuel.2023.127414
15. [15]
  TAMIMI K, ALAVI S M, REZAEI M, AKBARI E. Preparation of the Mn-Promoted NiO-Al₂O₃ nanocatalysts for low temperature CO₂ methanation[J]. J. Energy Inst., 2021,99:48-58. doi: 10.1016/j.joei.2021.08.008
16. [16]
  HU X, GUO X M, MENG T, GUO Q S, CHENG J L, WANG Y Z, HUANG W Z, NG F T T. NiAlFe catalysts based on hydrotalcite-like precursors for low temperature CO₂ methanation: Electronic effects among components and intrinsic activity of Ni site[J]. Appl. Surf. Sci., 2024,670160705. doi: 10.1016/j.apsusc.2024.160705
17. [17]
  TAKANO H, KIRIHATA Y, IZUMIYA K, KUMAGAI N, HABAZAKI H, HASHIMOTO K. Highly active Ni/Y-doped ZrO₂ catalysts for CO₂ methanation[J]. Appl. Surf. Sci., 2016,388:653-663. doi: 10.1016/j.apsusc.2015.11.187
18. [18]
  ZHOU L L, GUO X M, HU X, ZHANG Y X, CHENG J L, GUO Q S. CO₂ methanation reaction over La-modified NiAl catalysts derived from hydrotalcite-like precursors[J]. Fuel, 2024,362130888. doi: 10.1016/j.fuel.2024.130888
19. [19]
  CHENG J L, GUO X M, MENG T, HU X, LI L, WANG Y Z, HUANG W Z. NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor[J]. Chinese J. Inorg. Chem., 2024,40(8):1592-1602.
20. [20]
  SUN C, BEAUNIER P, DA COSTA P. Effect of ceria promotion on the catalytic performance of Ni/SBA-16 catalysts for CO₂ methanation[J]. Catal. Sci. Technol., 2020,10(18):6330-6341. doi: 10.1039/D0CY00922A
21. [21]
  ZHANG Q W, XU R N, LIU N, DAI C N, YU G Q, WANG N, CHEN B H. In situ Ce-doped catalyst derived from NiCeAl-LDHs with enhanced low-temperature performance for CO₂ methanation[J]. Appl. Surf. Sci., 2022,579152204. doi: 10.1016/j.apsusc.2021.152204
22. [22]
  GUO X P, HE H Y, TRAITANGWONG A, GONG M M, MEEYOO V, LI P, LI C S, PENG Z J, ZHANG S J. Ceria imparts superior low temperature activity to nickel catalysts for CO₂ methanation[J]. Catal. Sci. Technol., 2019,9(20):5636-5650. doi: 10.1039/C9CY01186B
23. [23]
  ZHANG J Y, REN B J, FAN G L, YANG L, LI F. Exceptional low-temperature activity of a perovskite-type AlCeO₃ solid solution- supported Ni-based nanocatalyst towards CO₂ methanation[J]. Catal. Sci. Technol., 2021,11(11):3894-3904. doi: 10.1039/D1CY00340B
24. [24]
  BROOKS C S, KEHRER V J. Chemisorption of carbon monoxide on metal surfaces by pulse chromatography[J]. Anal. Chem., 1969,41(1):103-106. doi: 10.1021/ac60270a003
25. [25]
  ZHOU G L, LIU H R, CUI K K, XIE H M, JIAO Z J, ZHANG G Z, XIONG K, ZHENG X X. Methanation of carbon dioxide over Ni/CeO₂ catalysts: Effects of support CeO₂ structure[J]. Int. J. Hydrog. Energy, 2017,42(25):16108-16117. doi: 10.1016/j.ijhydene.2017.05.154
26. [26]
  JIMÉNEZ-GONZÁLEZ C, BOUKHA Z, DE RIVAS B, DELGADO J J, CAUQUI M Á, GONZÁLEZ-VELASCO J R, GUTIÉRREZ-ORTIZ J I, LÓPEZ-FONSECA R. Structural characterisation of Ni/alumina reforming catalysts activated at high temperatures[J]. Appl. Catal. A‒Gen., 2013,466:9-20. doi: 10.1016/j.apcata.2013.06.017
27. [27]
  GUO C L, WU Y Y, QIN H Y, ZHANG J L. CO methanation over ZrO₂/Al₂O₃ supported Ni catalysts: A comprehensive study[J]. Fuel Process. Technol., 2014,124:61-69. doi: 10.1016/j.fuproc.2014.02.017
28. [28]
  ZHANG J, XU H Y, JIN X L, GE Q J, LI W Z. Characterizations and activities of the nano-sized Ni/Al₂O₃ and Ni/La-Al₂O₃ catalysts for NH₃ decomposition[J]. Appl. Catal. A‒Gen., 2005,290(1/2):87-96.
29. [29]
  SANZ J M, TYULIEV G T. An XPS study of thin NiO films deposited on MgO(100)[J]. Surf. Sci., 1996(367):196-202.
30. [30]
  BIESINGER M C, PAYNE B P, LAU L W M, GERSON A, SMART R S C. X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems[J]. Surf. Interface Anal., 2009,41(4):324-332. doi: 10.1002/sia.3026
31. [31]
  VENEZIA A M, BERTONCELLO R, DEGANELLO G. X-ray photoelectron spectroscopy investigation of pumice-supported nickel catalysts[J]. Surf. Interface Anal., 1995,23(4):239-247. doi: 10.1002/sia.740230408
32. [32]
  LI H, LI H X, DAI W L, WANG W J, FANG Z G, DENG J F. XPS studies on surface electronic characteristics of Ni-B and Ni-P amorphous alloy and its correlation to their catalytic properties[J]. Appl. Surf. Sci., 1999,152(1/2):25-34.
33. [33]
  YU J S, PARK J M, KWON J H, PARK K S, CHOUNG J W, PARK M J, BAE J W. Roles of Al₂O₃ coating layer on an ordered mesoporous Ni/m-Al₂O₃ for combined steam and CO₂ reforming with CH₄[J]. Fuel, 2023,331125702. doi: 10.1016/j.fuel.2022.125702
34. [34]
  HUA Y X, GUO X M, MAO D S, LU G Z, REMPEL G L, NG F T T. Single-step synthesis of dimethyl ether from biomass-derived syngas over CuO-ZnO-MO_x (M=Zr, Al, Cr, Ti)/HZSM-5 hybrid catalyst: Effects of MO_x[J]. Appl. Catal. A‒Gen., 2017,540:68-74. doi: 10.1016/j.apcata.2017.04.015
35. [35]
  CASARIN M, FALCOMER D, GLISENTI A, VITTADINI A. Experimental and theoretical study of the interaction of CO₂ with α-Al₂O₃[J]. Inorg. Chem., 2003,42(2):436-445. doi: 10.1021/ic0257773
36. [36]
  BURGER T, KOSCHANY F, THOMYS O, KÖHLER K, HINRICHSEN O. CO₂ methanation over Fe- and Mn-promoted co-precipitated Ni-Al catalysts: Synthesis, characterization and catalysis study[J]. Appl. Catal. A‒Gen., 2018,558:44-54. doi: 10.1016/j.apcata.2018.03.021
37. [37]
  LIANG C F, ZHANG L J, ZHENG Y, ZHANG S, LIU Q, GAO G G, DONG D H, WANG Y, XU L L, HU X. Methanation of CO₂ over nickel catalysts: Impacts of acidic/basic sites on formation of the reaction intermediates[J]. Fuel, 2020,262116521. doi: 10.1016/j.fuel.2019.116521
38. [38]
  WEILACH C, SPIEL C, FÖTTINGER K, RUPPRECHTER G. Carbonate formation on Al₂O₃ thin film model catalyst supports[J]. Surf. Sci., 2011,605(15/16):1503-1509.
39. [39]
  FÖTTINGER K, SCHLÖGL R, RUPPRECHTER G. The mechanism of carbonate formation on Pd-Al₂O₃ catalysts[J]. Chem. Commun., 2008(3):320-322. doi: 10.1039/B713161E
40. [40]
  ALKHOORI A A, ELMUTASIM O, DABBAWALA A A, VASILIADES M A, PETALLIDOU K C, EMWAS A H, ANJUM D H, SINGH N, BAKER M A, CHARISIOU N D, GOULA M A, EFSTATHIOU A M, POLYCHRONOPOULOU K. Mechanistic features of the CeO₂-modified Ni/Al₂O₃ catalysts for the CO₂ methanation reaction: experimental and ab initio studies[J]. ACS Appl. Energy Mater., 2023,6(16):8550-8571. doi: 10.1021/acsaem.3c01437
41. [41]
  WESTERMANN A, AZAMBRE B, BACARIZA M C, GRAÇA I, RIBEIRO M F, LOPES J M, HENRIQUES C. The promoting effect of Ce in the CO₂ methanation performances on NiUSY zeolite: A FTIR in situ/operando study[J]. Catal. Today, 2017,283:74-81. doi: 10.1016/j.cattod.2016.02.031
42. [42]
  WESTERMANN A, AZAMBRE B, BACARIZA M C, GRAÇA I, RIBEIRO M F, LOPES J M, HENRIQUES C. Insight into CO₂ methanation mechanism over NiUSY zeolites: An operando IR study[J]. Appl. Catal. B‒Environ., 2015,174-175:120-125. doi: 10.1016/j.apcatb.2015.02.026
43. [43]
  LALINDE J A H, ROONGRUANGSREE P, ILSEMANN J, BÄUMER M, KOPYSCINSKI J. CO₂ methanation and reverse water gas shift reaction. Kinetic study based on in situ spatially-resolved measurements[J]. Chem. Eng. J., 2020,390124629. doi: 10.1016/j.cej.2020.124629
44. [44]
  LIN L L, GERLAK C A, LIU C, LLORCA J, YAO S Y, RUI N, ZHANG F, LIU Z Y, ZHANG S, DENG K X, MURRAY C B, RODRIGUEZ J A, SENANAYAKE S D. Effect of Ni particle size on the production of renewable methane from CO₂ over Ni/CeO₂ catalyst[J]. J. Energy Chem., 2021,61:602-611. doi: 10.1016/j.jechem.2021.02.021
45. [45]
  JIA X Y, ZHANG X S, RUI N, HU X, LIU C J. Structural effect of Ni/ZrO₂ catalyst on CO₂ methanation with enhanced activity[J]. Appl. Catal. B‒Environ., 2019,244:159-169. doi: 10.1016/j.apcatb.2018.11.024
46. [46]
  ZHU J, ZHANG G H, LI W H, ZHANG X B, DING F S, SONG C S, GUO X W. Deconvolution of the particle size effect on CO₂ hydrogenation over iron-based catalysts[J]. ACS Catal., 2020,10(13):7424-7433. doi: 10.1021/acscatal.0c01526
47. [47]
  FALBO L, VISCONTI C G, LIETTI L, SZANYI J. The effect of CO on CO₂ methanation over Ru/Al₂O₃ catalysts: A combined steady-state reactivity and transient DRIFT spectroscopy study[J]. Appl. Catal. B‒Environ., 2019,256117791. doi: 10.1016/j.apcatb.2019.117791
48. [48]
  KARELOVIC A, RUIZ P. Mechanistic study of low temperature CO₂ methanation over Rh/TiO₂ catalysts[J]. J. Catal., 2013,301:141-153. doi: 10.1016/j.jcat.2013.02.009
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Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO2 methanation

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Effect of Ce introduction on the low-temperature performance of NiAl catalyst for CO₂ methanation