Citation: Shengwen XU, Longlong YANG, Houji CAO, Deshuang TU, Xing WEI, Changsheng LU, Hong YAN. Research progress on light-induced functionalization of polyhedral carborane clusters[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(11): 2187-2200. doi: 10.11862/CJIC.20250192 shu

Research progress on light-induced functionalization of polyhedral carborane clusters

Shengwen XU ¹ ,
Longlong YANG ¹ ,
Houji CAO ² ,
Deshuang TU ^1,, ,
Xing WEI ^3,, ,
Changsheng LU ^1,, ,
Hong YAN ^1,,

1.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
2.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China
3.
AIE Institute, Guangzhou 510530, China

Corresponding author: Deshuang TU, Xing WEI, Changsheng LU, Hong YAN, hyan1965@nju.edu.cn
Received Date: 8 June 2025
Revised Date: 25 September 2025

Figures(18)

Carboranes, as unique polyhedral boron cluster compounds, exhibit broad application prospects in numerous fields due to their three-dimensional aromatic structures and multicenter, multielectron bonding. However, the B—H bonds in carboranes are inert and pose challenges in regioselectivity, thus making their functionalization a great challenge in synthesis. In recent years, researchers have achieved carborane functionalization by employing light-induced strategies. These studies not only open new avenues for carborane functionalization but also yield a series of functionalized molecules containing carboranyl units, thereby laying a solid foundation for the further advancement of carborane chemistry.
- carboranes,
- boron clusters,
- functionalization,
- light-induced
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