Citation: Xiaoyong ZHAI, Yao KOU, Pingru SU, Yu TANG. Lanthanide metal-organic framework with msw topology: Synthesis and the application in 2, 4, 6-trinitrophenol detection[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2087-2094. doi: 10.11862/CJIC.20250182 shu

Lanthanide metal-organic framework with msw topology: Synthesis and the application in 2, 4, 6-trinitrophenol detection

Xiaoyong ZHAI ^{1, 2} ,
Yao KOU ¹ ,
Pingru SU ^1,, ,
Yu TANG ^1,,

1.
School of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
2.
School of Environment and Chemical Engineering, Lanzhou Resources & Environment Voc-Tech University, Lanzhou 730021, China

Corresponding author: Pingru SU, supr@lzu.edu.cn Yu TANG, tangyu@lzu.edu.cn
Received Date: 1 June 2025
Revised Date: 28 August 2025

Figures(4)

A lanthanide-based metal-organic framework Eu_0.52Tb_0.48-TCPP was synthesized under solvothermal conditions, where H₄TCPP=4,4′, 4″,4‴-(pyrazine-2, 3, 5, 6-tetrayl)-tetrabenzoic acid. The structure and composition were characterized by powder X-ray diffraction, thermogravimetric analysis, infrared spectroscope, and elemental analysis. Eu_0.52Tb_0.48-TCPP showed excellent chemical stability, thermal stability, and good fluorescence sensing performance, which realized efficient and sensitive detection of 2, 4, 6-trinitrophenol (TNP). The detection limit was 0.49 μmol·L^-1. In addition, the fluorescence sensing mechanism of TNP detected by Eu_0.52Tb_0.48-TCPP was explored and a portable fluorescence test papers and composite films were successfully prepared for the real-time and on-site inspection of TNP.
- lanthanide-based metal-organic framework,
- 2, 4, 6-trinitrophenol,
- fluorescence quenching
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