Citation: Kaimin WANG, Na HE, Shiyi LI, Xuling BAI, Weiqing SUN, Yanqing YE, Yulu MA. Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers[J]. Chinese Journal of Inorganic Chemistry, ;2026, 42(1): 55-64. doi: 10.11862/CJIC.20250178 shu

Synthesis, Hirshfeld surface analysis and properties of two Zn(Ⅱ)/Ni(Ⅱ) coordination polymers

Kaimin WANG ¹ ,
Na HE ¹ ,
Shiyi LI ¹ ,
Xuling BAI ¹ ,
Weiqing SUN ¹ ,
Yanqing YE ¹ ,
Yulu MA ^{2, 3,,}

1.
School of Chemistry & Environment, Yunnan Minzu University, Kunming 650504, China
2.
School of Pharmaceutical Sciences, Yunnan Key Laboratory of Pharmacology for Natural Products, Kunming Medical University, Kunming 650500, China
3.
College of Modern Biomedical Industry, Kunming Medical University, Kunming 650500, China

Corresponding author: Yulu MA, yuluma163@163.com
Received Date: 29 May 2025
Revised Date: 22 September 2025

Figures(9)

Two coordination polymers with different properties were successfully constructed under solvothermal conditions using zinc perchlorate, nickel perchlorate, and the same mixed ligand composed of 2, 7-naphthalenedicarboxylic acid (H₂NDA) and 1, 4-bis(1H-imidazol-1-yl)benzene (1, 4-DMB): {[Zn(NDA)(1, 4-DMB)_0.5(H₂O)]}_n (Zn-CP) and {[Ni(NDA)(1, 4-DMB)(H₂O)₃]}_n (Ni-CP). Single-crystal X-ray diffraction, thermogravimetric analysis, Hirshfeld surface analysis, and other characterization methods further explored the phase purity, thermal stability, and interaction in the crystal of the two complexes. The results show that the two coordination polymers have a 1D chain structure, and both of them are finally separated by abundant intermolecular hydrogen bonds and π…π stacking interactions form a 3D supramolecular structure. However, it is worth noting that when the two complexes are synthesized, except for the metal cations, the anions and other reagents and conditions are the same. Still, in Zn-CP, Zn²⁺ is in the center of the deformed tetrahedron with four coordinations, and the carboxyl groups in the NDA^2- ligands are all involved in the coordination, which is a bidentate bridging ligand. The final structure of the coordination polymer is a 1D ladder-shaped chain. In Ni-CP, Ni²⁺ is in the center of the deformed octahedron with hexacoordination, but only one carboxyl group is involved in the coordination in the NDA^2- ligand, which is a monodentate ligand end-group ligand, so the coordination polymer is only a 1D twisted trapezoidal chain. In addition, the solid-state fluorescence test results under 275 nm excitation showed that Zn-CP exhibited good fluorescence properties at 363 nm. Furthermore, the electrocatalytic performance test for nitrate reduction to ammonia indicated that Ni-CP exhibited a certain degree of electrocatalytic ability for nitrate reduction to ammonia.
- coordination polymers,
- Hirshfeld surface analysis,
- fluorescence properties,
- electrocatalysis,
- nitrate reduction
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