Citation: Jiaxuan YANG, Chenfa DENG, Jingyang LIU, Chenzexi XU, Hongxin CHEN, Yahui ZHU, Ying LI, Shuhua WANG, Rongping ZHOU, Chao CHEN. Advances in selective hydrogenation of α, β-unsaturated aldehydes/ketones catalyzed by metal-organic frameworks and their derivatives: A review[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 1973-2010. doi: 10.11862/CJIC.20250175 shu

Advances in selective hydrogenation of α, β-unsaturated aldehydes/ketones catalyzed by metal-organic frameworks and their derivatives: A review

Jiaxuan YANG ^{1, #} ,
Chenfa DENG ^{1, #} ,
Jingyang LIU ¹ ,
Chenzexi XU ¹ ,
Hongxin CHEN ¹ ,
Yahui ZHU ¹ ,
Ying LI ¹ ,
Shuhua WANG ¹ ,
Rongping ZHOU ^2,, ,
Chao CHEN ^1,,

1.
Key Laboratory of Jiangxi Province for Environment and Energy, School of Chemistry and Chemical Engineering, Nanchang University, Nanchang 330031, China
2.
The first affiliated hospital of Nanchang University, Nanchang 330006, China

Corresponding author: Rongping ZHOU, rongg106@163.com Chao CHEN, chaochen@ncu.edu.cn
Received Date: 27 May 2025
Revised Date: 24 August 2025

Figures(24)

The selective hydrogenation of α, β-unsaturated aldehydes/ketones enables precise control over product structures and properties by regulating hydrogen transport pathways and bond cleavage sequences to selectively reduce C=C or C=O bonds while preserving other functional groups within the molecule. This approach serves as a critical strategy for the directional synthesis of high-value molecules. However, achieving such selectivity remains challenging due to the thermodynamic equilibrium and kinetic competition between C=O and C=C bonds in α, β-unsaturated systems. Consequently, constructing precisely targeted catalytic systems is essential to overcome these limitations, offering both fundamental scientific significance and industrial application potential. Metal-organic frameworks (MOFs) and their derivatives have emerged as innovative platforms for designing such systems, owing to their programmable topology, tunable pore microenvironments, spatially controllable active sites, and modifiable electronic structures. This review systematically summarizes the research progress of MOF-based catalysts for selective hydrogenation of α, β-unsaturated aldehydes/ketones in the last decade, with emphasis on the design strategy, conformational relationship, and catalytic mechanism, aiming to provide new ideas for the design of targeted catalytic systems for the selective hydrogenation of α, β-unsaturated aldehydes/ketones.
- α, β-unsaturated aldehydes/ketones,
- metal-organic frameworks,
- derivatives,
- selective hydrogenation,
- catalytic mechanism,
- hydrogenation path
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沈阳化工大学材料科学与工程学院沈阳 110142