Citation: Xiaogang YANG, Xinya ZHANG, Jing LI, Huilin WANG, Min LI, Xiaotian WEI, Xinci WU, Lufang MA. Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2078-2086. doi: 10.11862/CJIC.20250167 shu

Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: Xiaogang YANG, yxg2233@126.com Lufang MA, mazhuxp@126.com
Received Date: 20 May 2025
Revised Date: 9 September 2025

Figures(5)

One metal-organic framework [Zn₃(NTB)₂(bipy)]·4H₂O (1) with charge transfer characteristic and 3D polyrotaxane structure was synthesized by the reaction of 4, 4′, 4″-nitrilotribenzoic acid (H₃NTB) as electron donor, 4, 4′-bipyridine (bipy) as electron acceptor and Zn(NO₃)₂·6H₂O under solvothermal method. Its crystal structure, phase purity, and thermal stability were characterized by X-ray single-crystal diffraction, powder X-ray diffraction, and thermogravimetric analysis. Complex 1 crystallizes in triclinic system, P1 space group with cell parameters: a=1.374 87(15) nm, b=1.376 65(15) nm, c=1.795 50(18) nm, α=86.994(9)°, β=82.384(9)°, γ=64.835(11)°. It emitted bright yellow emission peaking at 575 nm with lifetime of 16.01 ns under room temperature. The temperature- dependent photoluminescence shows that 1 could maintain 92.05% of its initial emission intensity after being heated to 150 ℃, higher than several silicates and borate based inorganic phosphors.
- metal-organic framework,
- crystal structure,
- thermal quenching
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