Citation: Tong WANG, Xuefang ZHU, Qi GAO, Hongbo ZHANG, Chao REN, Lixia GE. Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137 shu

Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase

Tong WANG ¹ ,
Xuefang ZHU ¹ ,
Qi GAO ¹ ,
Hongbo ZHANG ^2,, ,
Chao REN ¹ ,
Lixia GE ¹

1.
School of Materials Engineering, Shanxi College of Technology, Shuozhou, Shanxi 036000, China
2.
Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: Hongbo ZHANG, zhb5388460@126.com
Received Date: 21 April 2025
Revised Date: 19 September 2025

Figures(22)

A series of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ were prepared. The influence of heat-treatment conditions on the microstructure and luminescent properties was systematically investigated using various characterization techniques, and the optimal heat-treatment condition for luminescence was determined to be 670 ℃ for 90 min. The optimal doping concentration (molar fraction) of Tb³⁺ was 0.5%, beyond which concentration quenching occurs primarily due to quadrupole-quadrupole interactions. The energy transfer from Tb³⁺ to Eu³⁺ was observed in co-doped glass-ceramics. Within the temperature range of 293-493 K, co-doped glass-ceramic exhibited good fluorescence thermal stability with a thermal quenching activation energy of 0.24 eV and a chromaticity shift of 2.1×10^-2. Furthermore, this material demonstrated promising temperature sensing capabilities, with a maximum sensitivity of 5.7×10^-3 K^-1 and a thermal repeatability ratio of 96.6%.
- silicate,
- glass-ceramic,
- Tb³⁺-Eu³⁺ doping,
- thermal stability,
- luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142

Luminescence and thermal stability of Tb3+-Eu3+ doped glass-ceramics containing Na8.12Y1.293Si6O18 crystal phase

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通讯作者: 陈斌, bchen63@163.com

Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase