"Shining dot" in vinegar—Extraction of carbon quantum dots and the fluorescence properties analysis
- Corresponding author: Qi WANG, wangq@tit.edu.cn Lifeng DING, dinglf@tit.edu.cn Jinqin GUO, guojq@tit.edu.cn
Citation:
Qi WANG, Ying CHENG, Yuyan WANG, Yibing XIAO, Haozhe LU, Yansong ZHANG, Shengling LI, Jiazi TANTAI, Na SUN, Lifeng DING, Jinqin GUO, Peng JIN. "Shining dot" in vinegar—Extraction of carbon quantum dots and the fluorescence properties analysis[J]. Chinese Journal of Inorganic Chemistry,
;2026, 42(1): 87-96.
doi:
10.11862/CJIC.20250127
LIM S Y, SHEN W, GAO Z Q. Carbon quantum dots and their applications[J]. Chem. Soc. Rev., 2015, 44(1): 362-381
doi: 10.1039/C4CS00269E
DAS S, MONDAL S, GHOSH D. Carbon quantum dots in bioimaging and biomedicines[J]. Front. Bioeng. Biotech., 2024, 1: 1333752
SHI L L, DING L Y, ZHANG Y Q, LU S Y. Application of room- temperature phosphorescent carbon dots in information encryption and anti-counterfeiting[J]. Nano Today, 2024, 55: 102200
doi: 10.1016/j.nantod.2024.102200
XUE S S, LI P F, SUN L, AN L, QU D, WANG X Y, SUN Z C. The formation process and mechanism of carbon dots prepared from aromatic compounds as precursors: A review[J]. Small, 2023, 19(31): 2206180
doi: 10.1002/smll.202206180
WANG B Y, SONG H Q, TANG Z Y, YANG B, LU S Y. Ethanol- derived white emissive carbon dots: The formation process investigation and multi-color/white LEDs preparation[J]. Nano Res., 2022, 15(2): 942-949
doi: 10.1007/s12274-021-3579-5
WANG B Y, YU J K, SUI L Z, ZHU S J, TANG Z Y, YANG B, LU S Y. Rational design of multi-color-emissive carbon dots in a single reaction system by hydrothermal[J]. Adv. Sci., 2021, 8(1): 2001453
doi: 10.1002/advs.202001453
LI J N, ZHANG D K, XIA J B. The controllable synthesis of multi- color carbon quantum dots modified by polythiophene and their application in fluorescence detection of Au3+ and Hg2+[J]. Spectrochim. Acta Pt. A‒Molec. Biomolec. Spectr., 2024, 322: 124794
doi: 10.1016/j.saa.2024.124794
LIAO J F, YAO Y, LEE C H, WU Y Z, LI P. In vivo biodistribution, clearance, and biocompatibility of multiple carbon dots containing nanoparticles for biomedical application[J]. Pharmaceutics, 2021, 13(11): 1872
doi: 10.3390/pharmaceutics13111872
SHI Y X, XU H M, YUAN T, MENG T, WU H, CHANG J Q, WANG H Y, SONG X Z, LI Y C, LI X H, ZHANG Y, XIE W J, FAN L Z. Carbon dots: An innovative luminescent nanomaterial[J]. Aggregate, 2022, 3: e108
doi: 10.1002/agt2.108
ZOU L L, WANG H, HE B, ZENG L J, TAN T, CAO H Q, HE X Y, ZHANG Z W, GUO S R, LI Y P. Current approaches of photothermal therapy in treating cancer metastasis with nanotherapeutics[J]. Theranostics, 2016, 6(6): 762-772
doi: 10.7150/thno.14988
GE J C, JIA Q Y, LIU W M, LAN M H, ZHOU B J, GUO L, ZHOU H Y, ZHANG H Y, WANG Y, GU Y, MENG X M, WANG P F. Carbon dots with intrinsic theranostic properties for bioimaging, red-light-triggered photodynamic/photothermal simultaneous therapy in vitro and in vivo[J]. Adv. Healthcare Mater., 2016, 5(6): 665-675
doi: 10.1002/adhm.201500720
FENG T L, TAO S Y, YUE D, ZENG Q S, CHEN W H, YANG B. Recent advances in energy conversion applications of carbon dots: From optoelectronic devices to electrocatalysis[J]. Small, 2020, 16(31): 2001295
doi: 10.1002/smll.202001295
LI S H, SU W, WU H, YUAN T, YUAN C, LIU J, DENG G, GAO X C, CHEN Z M, BAO Y M, YUAN F L, ZHOU S X, TAN H W, LI Y C, LI X H, FAN L Z, ZHU J, CHEN A T, LIU F Y, ZHOU Y, LI M, ZHAI X C, ZHOU J B. Targeted tumour theranostics in mice via carbon quantum dots structurally mimicking large amino acids[J]. Nat. Biomed. Eng., 2020, 4(7): 704-716
doi: 10.1038/s41551-020-0540-y
WANG Q, CHENG Y, DING L F, LI S L, ZHANG J, NIU Y L, JING Z Y. N, S, Br co-doped carbon dots: One-step synthesis and fluorescent detection of 6-mercaptopurine in tablet[J]. J. Pharma. Anal., 2024, 14(2): 291-293
doi: 10.1016/j.jpha.2023.11.001
CARRERA C, GALÁN-GONZÁLEZ A, MASER W K, BENITO A M. Multifaceted role of H2O2 in the solvothermal synthesis of green-emitting nitrogen-doped graphene quantum dots[J]. Chem. Sci., 2025, 16(8): 3662-3670
doi: 10.1039/D4SC07896A
WANG Q, ZHANG Z R, YANG T, HAN Y J, CHENG Y, WU J N, BAI J J, MA C L, NIU Y L, SHUANG S M. Multiple fluorescence quenching effects mediated fluorescent sensing of captopril based on amino acids-derivative carbon nanodots[J]. Spectrochim. Acta Pt. A‒Molec. Biomolec. Spectr., 2022, 269: 120742
doi: 10.1016/j.saa.2021.120742
LI P F, XUE S S, SUN L, ZONG X P, AN L, QU D, WANG X Y, SUN Z C. Formation and fluorescent mechanism of red emissive carbon dots from o-phenylenediamine and catechol system[J]. Light‒Sci. Appl., 2022, 11(1): 298
MA Y J, WU L L, REN X Y, ZHANG Y Q, LU S Y. Toward kilogram-scale preparation of full-color carbon dots by simply stirring at room temperature in air[J]. Adv. Funct. Mater., 2023, 33(50): 2305867
doi: 10.1002/adfm.202305867
BARTOLOMEI B, BOGO A, AMATO F, RAGAZZON G, PRATO M. Nuclear magnetic resonance reveals molecular species in carbon nanodot samples disclosing flaws[J]. Angew. Chem. ‒Int. Edit., 2022, 61(20): e202200038
doi: 10.1002/anie.202200038
ZHAO C X, JIAO Y, HU F, YANG Y L. Green synthesis of carbon dots from pork and application as nanosensors for uric acid detection[J]. Spectrochim. Acta Pt. A‒Molec. Biomolec. Spectr., 2019, 190: 360-367
WU Y Y, SONG X Y, WANG N Y, CONG S, ZHAO X, RAIC R, TAN M Q. Carbon dots from roasted chicken accumulate in lysosomes and induce lysosome-dependent cell death[J]. Food Funct., 2020, 11(11): 10105-10113
doi: 10.1039/D0FO02144J
WANG L, ZHOU H S. Green synthesis of luminescent nitrogen-doped carbon dots from milk and its imaging application[J]. Anal. Chem., 2014, 86(18): 8902-8905
doi: 10.1021/ac502646x
ZHONG L N, CHEN J L, ZHAO Q H. Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid[J]. Chinese J. Inorg. Chem., 2025, 41(4): 709-718
doi: 10.11862/CJIC.20240280
GU D, SHANG S M, YU Q, SHEN J. Green synthesis of nitrogen-doped carbon dots from lotus root for Hg(Ⅱ) ions detection and cell imaging[J]. Appl. Surf. Sci., 2016, 390: 38-42
doi: 10.1016/j.apsusc.2016.08.012
WANG Y, GU Z Z, DONG J Y, ZHU J, LIU C G, LI G H, LU M C, HAN J, CAO S N, WANG W. Effects of kelp-derived carbon dots on embryonic development of zebrafish[J]. Chinese J. Inorg. Chem., 2024, 40(6): 1209-1217
doi: 10.11862/CJIC.20230423
ZHANG Q M, ZHANG L P, ZHENG K W, YANG G Q, HE S J, DU X J, CHEN F H, LI B. Green synthesis of high-stability black rice carbon dots for application in cell imaging[J]. Chinese J. Inorg. Chem., 2023, 39(4): 735-745
doi: 10.11862/CJIC.2023.045
SK M P, JAISWAL A, PAUL A, GHOSH S S, CHATTOPADHYAY A. Presence of amorphous carbon nanoparticles in food caramels[J]. Sci. Rep., 2012, 2: 383
doi: 10.1038/srep00383
YIN J, LIU K F, YUAN S F, GUO Y H, YU H, CHENG Y L, XIE Y F, QIAN H, YAO W R. Carbon dots in breadcrumbs: Effect of frying on them and interaction with human serum albumin[J]. Food Chem., 2023, 424: 136371
doi: 10.1016/j.foodchem.2023.136371
WEN F Z, LI P Y, ZHANG Y, ZHONG H Y, YAN H J, SU W. Preparation, characterization of green tea carbon quantum dots/curcumin antioxidant and antibacterial nanocomposites[J]. J. Mol. Struct., 2023, 1273: 134247
WANG Q, CHENG Y, DING L F, ZHANG X R, LI S L, ZHANG J, NIU Y L, DONG C, SHUANG S M. Chinese food seasoning derived carbon dots for highly selective detection of Fe3+ and smartphone-based dual-color fluorescence ratiometric visualization sensing[J]. J. Mol. Struct., 2024, 1318: 139209
CAO L. Discovery and property studies of carbon nanoparticles in mature vinegar[D]. Dalian: Dalian Polytechnic University, 2019: 10-28
CAO L, SONG X Y, SONG Y K, BI J R, SHUANG C, YU C X, TAN M Q. Fluorescent nanoparticles from mature vinegar: Their properties and interaction with dopamine[J]. Food Funct., 2017, 8: 4744-4751
doi: 10.1039/C7FO01475A
PENG J, GAO W, GUPTA B K, LIU Z, ROMERO-ABURTO R, GE L H, SONG L, ALEMANY L B, ZHAN X B, GAO G H, VITHAYATHIL S A, KAIPPARETTU B A, MARTI A A, HAYASHI T, ZHU J J, AJAYAN P M. Graphene quantum dots derived from carbon fibers[J]. Nano Lett., 2012, 12: 844-849
doi: 10.1021/nl2038979
TANG Q W, ZHU W L, HE B L, YANG P Z. Rapid conversion from carbohydrates to large-scale carbon quantum dots for all-weather solar cells[J]. ACS Nano, 2017, 11(2): 1540-1547
doi: 10.1021/acsnano.6b06867
ZHANG X R, WANG J, HASAN E, SUN X C, ASIF M, AZIZ A, LU W J, DONG C, SHUANG S M. Bridging biological and food monitoring: A colorimetric and fluorescent dual-mode sensor based on N-doped carbon dots for detection of pH and histamine[J]. J. Hazard. Mater., 2024, 470: 134271
doi: 10.1016/j.jhazmat.2024.134271
Lingqi Zhang , Hairong Huang , Jialin Li , Li Ji , Yufan Pan , Meiling Ye , Cuixue Chen , Shunü Peng . 桂花碳量子点的绿色制备及科普应用方案. University Chemistry, 2025, 40(8): 298-306. doi: 10.12461/PKU.DXHX202409138
Chengcheng Si , Linshan Chai , Huiyuan Liu , Liye Sun , Shijian Cheng , Hailing Li , Wenyun Wang , Fang Liu , Qing Feng , Min Liu . Harry Potter China Tour Themed Innovative Science Popularization Experiment: Chemistry Magic Meets the Real World at Wuhan Station. University Chemistry, 2024, 39(9): 283-287. doi: 10.12461/PKU.DXHX202401069
Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
Tong WANG , Qinyue ZHONG , Qiong HUANG , Weimin GUO , Xinmei LIU . Mn-doped carbon quantum dots/Fe-doped ZnO flower-like microspheres heterojunction: Construction and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1589-1600. doi: 10.11862/CJIC.20250011
Shuting Zhuang , Lida Zhao . Teaching through Research: A Comprehensive Experiment on Carbon Quantum Dots from Microplastic Waste. University Chemistry, 2025, 40(10): 217-224. doi: 10.12461/PKU.DXHX202412010
Shiyi Chen , Jialong Fu , Jianping Qiu , Guoju Chang , Shiyou Hao . Waste medical mask-derived carbon quantum dots enhance the photocatalytic degradation of polyethylene terephthalate (PET) over BiOBr/g-C3N4 S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(1): 100135-0. doi: 10.1016/j.actphy.2025.100135
Kuaibing Wang , Feifei Mao , Weihua Zhang , Bo Lv . Design and Practice of a Comprehensive Teaching Experiment for Preparing Biomass Carbon Dots from Rice Husk. University Chemistry, 2025, 40(5): 342-350. doi: 10.12461/PKU.DXHX202407042
Yuecheng ZHANG , Fan YANG , Shiyu ZHANG , Chengjun MA , Rui TIAN , Xuehua SUN , Haoyu LI , Lingbo SUN , Hongyan MA . B-doped carbon quantum dots with long-afterglow room-temperature phosphorescence: Applications in information encryption and humidity sensing. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1361-1370. doi: 10.11862/CJIC.20240415
Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
Yufan Pan , Xue Ding , Jiayu Lin , Haiting Wu , Hairong Huang , Cuixue Chen , Meiling Ye . Oil Cosmetics, Charming Chemistry: A Gradient Science Popularization Scheme for Cream Cosmetic Preparation. University Chemistry, 2025, 40(4): 382-389. doi: 10.12461/PKU.DXHX202406078
Wei Gao , Jinyue Yang , Wenwei Zhang . Practice and Exploration of Promoting the “Double Reduction” Work with Popular Science Resources in Universities. University Chemistry, 2024, 39(9): 385-391. doi: 10.3866/PKU.DXHX202311008
Xiangrong Zhang , Guoxin Yang , Peiling Lin , Yanhong Bai , Baoping Li , Honglang Liu , Kai Xi . Exploration and Practice of University Resources in Diversifying Chemistry Science Popularization. University Chemistry, 2026, 41(2): 248-254. doi: 10.12461/PKU.DXHX202502018
Yihan Xue , Xue Han , Jie Zhang , Xiaoru Wen . NCQDs修饰FeOOH基复合材料的制备及其电容脱盐性能. Acta Physico-Chimica Sinica, 2025, 41(7): 100072-0. doi: 10.1016/j.actphy.2025.100072
Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta3N5 S-scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-0. doi: 10.3866/PKU.WHXB202403005
Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide:Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
Tianlong Zhang , Xinyuan Zhang , Xing Zhao , Hongsheng Tang , Yan Li , Hua Li . Colors of Dotted Stone: The Colorful World of Dunhuang Murals. University Chemistry, 2024, 39(6): 238-245. doi: 10.3866/PKU.DXHX202401047
Qiuyu Ming , Huijun Jiang , Zhihao Zhang . A Sightseeing Tour of Folic Acid Processing Plant. University Chemistry, 2024, 39(9): 11-15. doi: 10.12461/PKU.DXHX202404092
Feiyang Liu , Liuhong Song , Miaoyu Fu , Zhi Zheng , Gang Xie , Junlong Zhao . Tryptophan’s Employment Journey. University Chemistry, 2024, 39(9): 16-21. doi: 10.12461/PKU.DXHX202404037
Tianlong Zhang , Chenjia Song , Wenmin Zhao , Hongsheng Tang , Yan Li , Hua Li . Dream as a Horse, Poem “Liquor” while the Age. University Chemistry, 2024, 39(9): 48-54. doi: 10.12461/PKU.DXHX202403076