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Citation: Min WANG, Dehua XIN, Wei ZHANG, Haiying YANG, Yuchun WANG, Zhaorong LIU, Meng SHI, Le SHI. Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C3N4/Bi/BiOBr/BiOI heterojunction material[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(11): 2283-2298. doi: 10.11862/CJIC.20250109 shu

Preparation and full-spectrum catalytic degradation performance of nitrogen vacancy g-C3N4/Bi/BiOBr/BiOI heterojunction material

  • Department of Applied Chemistry, Yuncheng University, Yuncheng, Shanxi 044000, China

Figures(11)

  • The multi-component nitrogen vacancy g-C3N4 (NVCN)/Bi/BiOBr/BiOI heterojunction photocatalytic material was prepared by an in-situ solvothermal method. The composition, morphology, specific surface area, pore structure, defect, and elemental chemical state, as well as the optical and photoelectrochemical properties of the prepared catalyst, were characterized using X-ray diffraction, scanning electron microscopy, transmission electron microscopy, N2 adsorption-desorption tests, X-ray photoelectron spectroscopy, photoluminescence spectroscopy, and photoelectrochemical measurements. The absorption ability of the heterojunction for visible and near-infrared light was significantly enhanced owing to the localized surface plasmon resonance effect of the defect and metallic Bi. 90.7% and 78.5% of ciprofloxacin could be decomposed by NVCN/Bi/BiOBr/BiOI within 60 min and 6 h of visible and near-infrared light irradiation, and the corresponding mineralization efficiencies were about 73.1% and 62.1%, respectively. Based on the results of photoelectrochemical measurements and free radical capture experiments, it could be inferred that the boosted full-spectrum catalytic performance of NVCN/Bi/BiOBr/BiOI heterojunction is attributed to the enhanced light absorption, improved separation efficiency, and prolonged lifetime of photogenerated charge carriers, as well as the formation of a double S-scheme charge transfer mechanism.
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