Citation: Cuiping HE, Zhuxuan LI, Yuqing SUN, Jie LIU, Shicheng XU, Zhanchao WU. Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(11): 2299-2306. doi: 10.11862/CJIC.20250074 shu

Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor

Cuiping HE ¹ ,
Zhuxuan LI ² ,
Yuqing SUN ² ,
Jie LIU ^1,, ,
Shicheng XU ^2,, ,
Zhanchao WU ^1,,

1.
College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042, China
2.
School of Materials Science and Engineering, Linyi University, Linyi, Shandong 276000, China

Corresponding author: Jie LIU, zsuliujie@163.com Shicheng XU, xushicheng@lyu.edu.cn Zhanchao WU, wuzhan_chao@163.com
Received Date: 7 March 2025
Revised Date: 22 July 2025

Figures(7)

In this paper, Ba₃P₄O₁₃: Eu²⁺ was selected as the research object. By substituting Ba²⁺ with Ca²⁺, we investigated the effect of Ca²⁺ doping on the crystalline phase of Ba₃P₄O₁₃ and further explored its impact on the luminescent properties of the Ba_2.991P₄O₁₃: 0.009Eu²⁺ phosphor. Fixing Eu²⁺ concentration (mass fraction) at 0.3%, we further prepared Ba_2.991-3xP₄O₁₃: 0.009Eu²⁺, 3xCa²⁺ phosphors with different Ca²⁺ concentrations at 850 ℃. By altering the doping concentration of Ca²⁺ in the Ba_2.991P₄O₁₃: 0.009Eu²⁺ phosphor, we examined its effect on the crystal phase transition of the Ba_2.991P₄O₁₃: 0.009Eu²⁺ phosphor, as well as investigated changes in its luminescent properties and thermal stability through room-temperature spectroscopy and variable-temperature spectroscopy tests.
- phosphor,
- phosphate,
- spectral regulation,
- crystal-phase transformation
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ca2+ doping induced crystal phase transition and spectral regulation of Ba3P4O13: Eu2+ phosphor

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通讯作者: 陈斌, bchen63@163.com

Ca²⁺ doping induced crystal phase transition and spectral regulation of Ba₃P₄O₁₃: Eu²⁺ phosphor