Citation: Liping GUO. Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065 shu

Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex

Liping GUO

School of Materials and Chemical Engineering, Bengbu University, Bengbu, Anhui 233030, China

Author Bio: GUO Liping, E‐mail: guoliping251@126.com
Received Date: 25 February 2025
Revised Date: 18 April 2025

Figures(6)

2‐substituted‐1‐amino‐o‐carboranes 2‐R‐1‐NH₂‐ o‐C₂B₁₀H₁₀ (R=CH₃, 1a; R=Ph, 1b) were synthesized and the reactions of these compounds with the yttrium dialkyl complex [Y(L)(CH₂SiMe₃)₂] (L=[2‐(2, 5‐Me₂C₄H₂N)C₆H₄NC(Ph)=NDipp]^-, Dipp=2, 6‐ⁱPr₂C₆H₃) were investigated. The ¹H NMR spectroscopy indicate that the reaction of ytrrium dialkyl complex with one equivalent of 2‐R‐1‐NH₂‐ o‐C₂B₁₀H₁₀ produce the mixture of ytrrium alkyl‐amido complex [Y(L)(2‐R‐1‐NH‐ o‐C₂B₁₀H₁₀)(CH₂SiMe₃)] (R=CH₃, 2a; R=Ph, 2b) and bis(amido) complex [Y(L)(2‐R‐1‐NH‐ o‐C₂B₁₀H₁₀)2] (R=CH₃, 3a; R=Ph, 3b). The yttrium bridging imido complex [Y(L)(2‐CH₃‐1‐N‐ o‐C₂B₁₀H₁₀)]2 (4a) was obtained by heating the mixture at 55 ℃ for 12 h. Complex 3a was isolated and characterized by treating the yttrium dialkyl complex with two equivalents of 1a. The structures of complexes 3a and 4a were verified by single‐crystal X‐ray diffraction..
- yttrium imide,
- o‐carborane,
- synthesis,
- structure characterization
1. [1]
  TRIFONOV A A, BOCHKAREV M N, SCHUMANN H, LOEBEL J. Reduction of azobenzene by naphthaleneytterbium: A tetranuclear ytterbium(Ⅲ) complex combining 1, 2‐diphenylhydrazido(2-) and phenylimido ligands[J]. Angew. Chem.‒Int. Edit., 1991,30(9):1149-1151. doi: 10.1002/anie.199111491
2. [2]
  LIU Z X, CHEN Y F. One frontier of the rare‐earth organometallic chemistry: The chemistry of rare‐earth metal alkylidene, imido and phosphinidene complexes[J]. Sci. China Chem., 2011,41(2):304-313.
3. [3]
  SCHÄDLE D, ANWANDER R. Rare‐earth metal and actinide organoimide chemistry[J]. Chem. Soc. Rev., 2019,48(24):5752-5805. doi: 10.1039/C8CS00932E
4. [4]
  SCOTT J, BASULI F, FOUT A R, HUFFMAN J C, MINDIOLA D J. Evidence for the existence of a terminal imidoscandium compound: Intermolecular C—H activation and complexation reactions with the transient Sc=NAr species[J]. Angew. Chem.‒Int. Edit., 2008,47(44):8502-8505. doi: 10.1002/anie.200803325
5. [5]
  LU E L, LI Y X, CHEN Y F. A scandium terminal imido complex: Synthesis, structure and DFT studies[J]. Chem. Commun., 2010,46(25):4469-4471. doi: 10.1039/c002870c
6. [6]
  LU E L, CHU J X, CHEN Y F. Scandium terminal imido chemistry[J]. Acc. Chem. Res., 2018,51(2):557-566. doi: 10.1021/acs.accounts.7b00605
7. [7]
  CHAN H S, LI H W, XIE Z W. Synthesis and structural characterization of imido‐lanthanide complexes with a metal‐nitrogen multiple bond[J]. Chem. Commun., 2002(6):652-653. doi: 10.1039/b110793c
8. [8]
  PAN C L, CHEN W, SONG S Y, ZHANG H J, LI X W. Stabilization of imidosamarium(Ⅲ) cubane by amidinates[J]. Inorg. Chem., 2009,48(14):6344-6346. doi: 10.1021/ic900808f
9. [9]
  BEETSTRA D J, MEETSMA A, HESSEN B, TEUBEN J H. (Cyclo-pentadienylamine)scandium(2, 3‐dimethyl‐1, 3‐butadiene): A 1, 3‐diene complex of scandium with Sc􀃬‐and Sc(Ⅲ)‐like reactivity[J]. Organometallics, 2003,22(22):4372-4374. doi: 10.1021/om030267h
10. [10]
  CUI D M, TARDIF O, HOU Z M. Tetranuclear rare earth metal polyhydrido complexes composed of "(C₅Me₄SiMe₃)LnH₂" units. Unique reactivities toward unsaturated C—C, C—N, and C—O bonds[J]. J. Am. Chem. Soc., 2004,126(5):1312-1313. doi: 10.1021/ja039324o
11. [11]
  BERTHET J C, THUÉRY P, EPHRITIKHINE M. Polyimido clusters of neodymium and uranium, including a cluster with an M₆(μ₃‐N)₈ Core[J]. Eur. J. Inorg. Chem., 2008(35):5455-5459.
12. [12]
  LU E L, CHU J X, CHEN Y F. Scandium terminal imido complex induced C—H bond selenation and formation of an Sc—Se bond[J]. Chem. Commun., 2011,47(2):743-745. doi: 10.1039/C0CC03212C
13. [13]
  RONG W F, CHENG J H, MOU Z H, XIE H Y, CUI D M. Facile preparation of a scandium terminal imido complex supported by a phosphazene ligand[J]. Organometallics, 2013,32(19):5523-5529. doi: 10.1021/om400803q
14. [14]
  SCHÄDLE D, MEERMANN ‐ ZIMMERMANN M, SCHÄDLE C, MAICHLE‐ MÖSSMER C, ANWANDER R. Rare‐earth metal complexes with terminal imido ligands[J]. Eur. J. Inorg. Chem., 2015(8):1334-1339.
15. [15]
  HONG J Q, ZHANG L X, WANG K, ZHANG Y, WENG L H, ZHOU X G. Methylidene rare‐earth‐metal complex mediated transformations of C=N, N=N and N—H bonds: New routes to imido rare‐earth‐metal clusters[J]. Chem.‒Eur. J., 2013,19(24):7865-7873. doi: 10.1002/chem.201300440
16. [16]
  LI H H, YAN H, LU C S. Progress in selective B—H bond functionalization of carborane[J]. Chinese J. Inorg. Chem., 2017,33(8):1313-1329.
17. [17]
  ZHANG X L, YAN H. Transition metal‐induced B—H functionalization of o‐carborane[J]. Coord. Chem. Rev., 2019,378:466-482. doi: 10.1016/j.ccr.2017.11.006
18. [18]
  GUO L P, GUO C J, PENG S Q, SONG R Y. Synthesis, structure, and coordination chemistry of a neutral pyrrolyl‐functionalized amidinate ligand[J]. New J. Chem., 2022,46(5):2465-2471. doi: 10.1039/D1NJ05548H
19. [19]
  GUO L P, WANG S W, XIE Z W. Synthesis, structure, and reactivity of rare‐earth metal carboryne complexes[J]. Organometallics, 2023,42(7):581-587. doi: 10.1021/acs.organomet.3c00002
20. [20]
  TANG C, XIE Z W. Nickel‐catalyzed cross‐coupling reactions of o‐carboranyl with aryl iodides: Facile synthesis of 1‐aryl‐o‐carboranes and 1, 2‐diaryl‐o‐carboranes[J]. Angew. Chem.‒Int. Edit., 2015,54(26):7662-7665. doi: 10.1002/anie.201502502
21. [21]
  NIE Y, WANG Y F, MIAO J L, LI Y X, ZHANG Z W. Synthesis and characterization of carboranyl Schiff base compounds from 1‐amino‐o‐carborane[J]. J. Organomet. Chem., 2015,798:182-188. doi: 10.1016/j.jorganchem.2015.05.046
22. [22]
  THIM R, DIETRICH H M, BONATH M, MAICHLE‐MÖSSMER C, ANWANDER R. Pentamethylcyclopentadienyl‐supported rare‐earth‐metal benzyl, amide, and imide complexes[J]. Organometallics, 2018,37(16):2769-2777. doi: 10.1021/acs.organomet.8b00420
1. [1]
  Lifang HE , Yaoze LUO , Qiying SHI , Jianxin TANG , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and properties of hydrated tricyclohexyltin theophylline-7-acetic acid complex. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 632-640. doi: 10.11862/CJIC.20250244
2. [2]
  Rongjian Chen , Jiahui Liu , Caixia Lin , Yuanming Li , Yanhou Geng , Yaofeng Yuan . Synthesis and properties of tetraphenylethene cationic cyclophanes based on o-carborane skeleton. Chinese Chemical Letters, 2024, 35(12): 110074-. doi: 10.1016/j.cclet.2024.110074
3. [3]
  Teng-Yu Huang , Junliang Sun , De-Xian Wang , Qi-Qiang Wang . Recent progress in chiral zeolites: Structure, synthesis, characterization and applications. Chinese Chemical Letters, 2024, 35(12): 109758-. doi: 10.1016/j.cclet.2024.109758
4. [4]
  Zhaodong WANG . In situ synthesis, crystal structure, and magnetic characterization of a trinuclear copper complex based on a multi-substituted imidazo[1,5-a]pyrazine scaffold. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 597-604. doi: 10.11862/CJIC.20240268
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
7. [7]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
8. [8]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
9. [9]
  Lixing ZHANG , Yaowen WANG , Xu HAN , Junhong ZHOU , Jinghui WANG , Liping LI , Guangshe LI . Research progress in the synthesis of fluorine-containing perovskites and their derivatives. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1689-1701. doi: 10.11862/CJIC.20250007
10. [10]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
11. [11]
  Fengchen Wang , Yujia Xiang , Yuqi Zhang , Xin Zhou , Jing Zhang , Chuanshu He , Heng Zhang , Zhaokun Xiong , Peng Zhou , Hongyu Zhou , Yang Liu , Bo Lai . A comprehensive review on oxygen vacancies modified catalysts: Synthesis, characterization, and crucial role in catalytic ozonation. Chinese Chemical Letters, 2026, 37(2): 111315-. doi: 10.1016/j.cclet.2025.111315
12. [12]
  Chengyu JIANG , Xufeng LIU . Synthesis, structural characterization, electrocatalytic proton reduction, and fungicidal activity of thiazole-containing di-iron complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 355-364. doi: 10.11862/CJIC.20250253
13. [13]
  Xiuli HAO , Chenhao ZHANG , Chenkun FENG , Haolin HAN , Xudong ZHAO , Guoliang SHI . Synthesis, characterization, and ion exchange properties of octamolybdate-based Cu(Ⅱ) coordination polymer. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 883-896. doi: 10.11862/CJIC.20250248
14. [14]
  Maitri Bhattacharjee , Rekha Boruah Smriti , R. N. Dutta Purkayastha , Waldemar Maniukiewicz , Shubhamoy Chowdhury , Debasish Maiti , Tamanna Akhtar . Synthesis, structural characterization, bio-activity, and density functional theory calculation on Cu(Ⅱ) complexes with hydrazone-based Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1409-1422. doi: 10.11862/CJIC.20240007
15. [15]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
16. [16]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
17. [17]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
18. [18]
  Yulin Mao , Jingyu Ma , Jiecheng Ji , Yuliang Wang , Wanhua Wu , Cheng Yang . Crown aldoxime ethers: Their synthesis, structure, acid-catalyzed/photo-induced isomerization and adjustable guest binding. Chinese Chemical Letters, 2024, 35(11): 109927-. doi: 10.1016/j.cclet.2024.109927
19. [19]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
20. [20]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(912)
HTML views(48)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142