Citation: Ping LI, Geng TAN, Xin HUANG, Fuxing SUN, Jiangtao JIA, Guangshan ZHU, Jia LIU, Jiyang LI. Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(10): 2063-2068. doi: 10.11862/CJIC.20250020 shu

Green synthesis of metal-organic frameworks with open metal sites for efficient ammonia capture

Ping LI ¹ ,
Geng TAN ² ,
Xin HUANG ² ,
Fuxing SUN ¹ ,
Jiangtao JIA ^2,, ,
Guangshan ZHU ² ,
Jia LIU ^1,, ,
Jiyang LI ¹

1.
College of Chemistry, Jilin University, Changchun 130012, China
2.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: Jiangtao JIA, jiangtaojia@nenu.edu.cn Jia LIU, jia@jlu.edu.cn
Received Date: 17 January 2025
Revised Date: 3 April 2025

Figures(4)

Ammonia, a toxic gas, poses significant risks to human health and the environment. Developing cost- effective and eco-friendly adsorbents for ammonia capture is crucial. In this study, a La³⁺-based metal-organic framework {[La₄(QS)₆(H₂O)₆]·18H₂O}_n (MOF-LaQS) was synthesized via a simple low-temperature hydrothermal method using inexpensive 8-hydroxyquinoline-5-sulfonic acid (H₂QS) as organic ligand. The material exhibited structural stability, low synthesis costs, and exceptional ammonia adsorption capacities of 228 cm³·g^-1 (10.2 mmol·g^-1) at 273 K (101 kPa) and 48 cm³·g^-1 (2.14 mmol·g^-1) at ultra-low pressure (0.101 kPa). In situ infrared spectroscopy and DFT calculations revealed that open La³⁺ sites are key to its ammonia adsorption, thereby elucidating the mechanism underlying its high ammonia uptake.
- ammonia capture,
- metal organic framework,
- open metal site,
- hydrothermal synthesis
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