Citation: Yukun CHEN, Kexin FENG, Bolun ZHANG, Wentao SONG, Jianjun ZHANG. Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448 shu

Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks

School of Chemistry, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: Jianjun ZHANG, zhangjj@dlut.edu.cn
Received Date: 20 December 2024
Revised Date: 5 April 2025

Figures(5)

The reaction of Mg²⁺ and 5-{1, 3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid (H₂L) leads to two metal-organic frameworks, [Mg(L)(DMF)₂(H₂O)₂]₂·5DMF·2H₂O (1) with a 1D structure and [Mg₂(L)₂(DMSO)₃(H₂O)] (2) with a 2D (4, 4)-net structure. Interestingly, the two compounds exhibit distinct luminescent responses to external mechanical stimuli. 1 exhibited exceptional resistance mechanical chromic luminescence (RMCL), which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure. 2 had a reversible MCL property, which can be attributed to the dominant π-π weak interactions, coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.
- metal-organic framework,
- crystal structure,
- mechanical chromic luminescence,
- resistance mechanical chromic luminescence,
- weak interaction
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