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Citation: Ru SONG, Biao WANG, Chunling LU, Bingbing NIU, Dongchao QIU. Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material[J]. Chinese Journal of Inorganic Chemistry, ;2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397 shu

Electrochemical properties of stable and highly active PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ cathode material

  • School of Science, University of Science and Technology Liaoning, Anshan, Liaoning 114051, China

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  • Sr, Ni co-doped PrBaFe2O5+δ (PBF) was employed to prepare the PrBa0.5Sr0.5Fe1.6Ni0.4O5+δ (PBSFN) cathode for intermediate temperature solid oxide fuel cells (IT-SOFCs), and the performance of cathode was evaluated. X-ray diffraction (XRD) analysis revealed that the PBSFN cathode formed a cubic perovskite structure after being calcined at high temperatures. PBSFN cathode and La0.9Sr0.1Ga0.83Mg0.17O3-δ (LSGM) electrolyte exhibited good chemical compatibility after being co-calcined at 950 ℃. In an air atmosphere, the conductivity of the PBSFN cathode reached a maximum value of 681 S·cm-1 at 350 ℃. At 800 ℃, the polarization resistance of the PBSFN cathode on the LSGM electrolyte was 0.033 Ω·cm2 in an air atmosphere. The high-frequency resistance (R1) is only 6.4% more than that of low-frequency resistance (R2), indicating Sr, Ni doped significantly improves the efficiency of charge transfer. The polarization resistance (Rp) result is consistent with the oxygen vacancy formation energy of PBSFN by density function theory calculations. At 800 ℃, using H2 as the fuel, the maximum power density of the single cell reached 647 mW·cm-2. In particular, the output power of the single cell with the PBSFN cathode maintained good stability over 100 h.
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