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Citation: Yinglian LI, Chengcheng ZHANG, Xinyu ZHANG, Xinyi WANG. Spin crossover in [Co(pytpy)2]2+ complexes modified by organosulfonate anions[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087 shu

Spin crossover in [Co(pytpy)2]2+ complexes modified by organosulfonate anions

  • State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

  • Corresponding author: Xinyi WANG, wangxy66@nju.edu.cn
  • Received Date: 20 March 2024
    Revised Date: 20 April 2024

Figures(7)

  • Two mononuclear cobalt(Ⅱ) complexes, [Co(pytpy)2](2-NH2-1-NS)2·MeOH·H2O (1) and [Co(pytpy)2](4-NH2-1-NS)2·H2O (2), where pytpy=4'-(4-pyridyl)-2, 2'∶6', 2″-terpyridine, 2-NH2-1-NS-=2-amino-1-naphthalenesulfonate, and 4-NH2-1-NS-=4-amino-1-naphthalenesulfonate, were synthesized and characterized structurally and magnetically. Single-crystal X-ray analysis reveals that both complexes consist of the [Co(pytpy)2]2+ cations, organosulfonate anions, and crystallized solvent molecules. The difference between the two anions is the relative position of the sulfonate and amino groups. Interestingly, the 2-NH2-1-NS- anion with the sulfonate and amino group in adjacent positions, forms hydrogen bonds with the [Co(pytpy)2]2+ cation and solvent molecules, while the 4-NH2-1-NS- anion, with the sulfonate and amino groups in para positions, forms a 2D layer structure through hydrogen bonding. Magnetic measurements revealed significant differences in their magnetic properties: while complex 1 exhibits a reversible and gradual spin crossover behavior, complex 2 remains in the high-spin state.
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