Citation: Zhenzhong MEI, Hongyu WANG, Xiuqi KANG, Yongliang SHAO, Jinzhong GU. Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081 shu

Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands

College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Yongliang SHAO, shaoylc@lzu.edu.cn Jinzhong GU, gujzh@lzu.edu.cn
Received Date: 14 March 2024
Revised Date: 18 June 2024

Figures(10)

Three zinc(Ⅱ) and cobalt(Ⅱ) coordination polymers, namely {[Zn₂(μ₆-adip)(phen)₂]·4H₂O}_n (1), {[Co₂(μ₆-adip)(bipy)₂]·4H₂O}_n (2), and [Co₂(μ₄-adip)(μ-bpa)₂]_n (3) have been constructed hydrothermally using H₄adip (H₄adip= 5, 5'-azanediyldiisophthalic acid), phen (phen=1, 10-phenanthroline), bipy (bipy=2, 2'-bipyridine), bpa (bpa=bis(4-pyridyl)amine), and zinc and cobalt chlorides at 160 ℃. The products were isolated as stable crystalline solids and were characterized by IR spectra, elemental analyses, thermogravimetric analyses, and single-crystal X-ray diffraction analyses. Single-crystal X-ray diffraction analyses revealed that three compounds crystallize in the orthorhombic system Pnna (1 and 2) or P2₁2₁2 (3) space groups. All compounds exhibit 3D frameworks. The catalytic perfor-mances in the Henry reaction of these compounds were investigated. Compound 3 exhibited an effective catalytic activity in the Henry reaction at 70 ℃.
- coordination polymer,
- tetracarboxylic acid,
- catalytic properties,
- Henry reaction
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