Citation: Huirong LIU, Hao XU, Dunru ZHU, Junyong ZHANG, Chunhua GONG, Jingli XIE. Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066 shu

Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials

Huirong LIU ^{1, 2} ,
Hao XU ² ,
Dunru ZHU ^1,, ,
Junyong ZHANG ² ,
Chunhua GONG ^3,, ,
Jingli XIE ^2,,

1.
College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China
2.
College of Biological, Chemical Sciences, and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
3.
School of Advanced Materials and Engineering, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China

Corresponding author: Dunru ZHU, zhudr@njtech.edu.cn Chunhua GONG, gongch@jxnhu.edu.cn Jingli XIE, jlxie@mail.zjxu.edu.cn
Received Date: 27 February 2024
Revised Date: 27 May 2024

Figures(7)

Two new viologen-polyoxometalate hybrid crystalline materials: (MV)₂[HPW₂^ⅤW₁₀^ⅥO₄₀] ·2H₂O (1) and (EV)₂[Mo₈O₂₆] (2) have been synthesized by using the cations of 1, 1'-dimethyl-4, 4'-bipyridinium dichloride (methyl viologen, MV) and 1, 1'-diethyl-4, 4'-bipyridinium dibromide (ethyl viologen, EV) as the electron acceptors, and the electron-rich polyoxometalate anions as the electron donors. The structures of compounds 1 and 2 have been determined by single-crystal X-ray crystallography. Hydrogen bond interactions exist between the cations and the anions in 1 and 2. Interestingly, 2 has a photochromic performance with a light response time within 1 min. The photochromic mechanism of compound 2 has been investigated by solid-state diffuse reflection, electron paramagnetic resonance and theoretical calculation. 1 and 2 show good catalytic performance in the photocatalytic degradation of several organic dyes (methylene blue, pararosaniline hydrochloride and rhodamine 6G).
- viologen,
- polyoxometalate,
- photochromism,
- photocatalysis
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