Citation: Yan LIU, Jiaxin GUO, Song YANG, Shixian XU, Yanyan YANG, Zhongliang YU, Xiaogang HAO. Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043 shu

Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film

Yan LIU ^{1, 2} ,
Jiaxin GUO ² ,
Song YANG ³ ,
Shixian XU ² ,
Yanyan YANG ^2,, ,
Zhongliang YU ² ,
Xiaogang HAO ^3,,

1.
College of Chemistry, Taiyuan University of Technology, Taiyuan 030024, China
2.
School of Chemistry and Environmental Science, Shangrao Normal University, Shangrao, Jiangxi 334001, China
3.
Department of Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: Yanyan YANG, yangyy0927@163.com Xiaogang HAO, xghao@tyut.edu.cn; tyutxghao@hotmail.com
Received Date: 3 February 2024
Revised Date: 1 July 2024

Figures(11)

A high electroactive hybrid film of CoNi-layered double hydroxide grown on graphene (CoNi-LDH/G) with a three-dimensional (3D) flower-like structure was successfully prepared by using two-step coating and electro-deposition method, and applied to separate and recover low concentrated phosphate anions from wastewater via electrically switched ion exchange. The morphology, composition, and structure of the CoNi-LDH/G hybrid film were demonstrated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscope (TEM). The effect of absorption potentials, initial phosphate concentrations, co-existing anions, and pH on the phosphate electrochemistry adsorption performance of the hybrid film was also investigated. The experimental results indicated that the hybrid film had a high adsorption performance by adjusting the redox potential, even at low concentrations. In addition, it can be used in a wide pH range (4-10), and its adsorption capacity for PO₄^3- was little affected by coexisting ions and their variations in concentration. Further-more, the adsorption capacity of G and CoNi-LDH for PO₄^3- was 1.10 and 11.74 mg·g^-1, respectively. Moreover, the sum of these two was also lower than that of the CoNi-LDH/G hybrid film (16.25 mg·g^-1). Combined with O1s XPS analysis, it was found that PO₄^3- adsorption on CoNi-LDH/G hybrid film aside from interlayer ion exchange, complexation ligand exchange between PO₄^3- and layer-plate metal ions, the synergistic effects between G and CoNiLDH also existed.
- CoNi-layered double hydroxide/graphene,
- electrically switched ion exchange,
- exclusionary,
- low concentration,
- phosphate anion
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