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Citation: Kun WANG, Wenrui LIU, Peng JIANG, Yuhang SONG, Lihua CHEN, Zhao DENG. Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037 shu

Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction

  • State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

  • Corresponding author: Zhao DENG, dengzhao@whut.edu.cn
  • Received Date: 25 January 2024
    Revised Date: 28 May 2024

Figures(9)

  • BiOBr-Pt catalysts with hierarchical hollow structures were synthesized by a one-step solvothermal method using ethylene glycol as solvent and polyvinylpyrrolidone as surfactant. The synthesized hierarchical hollow structure BiOBr-2h catalyst had a specific surface area of 28 m2·g-1, twice as large as the comparison sample BiOBr-1h. This structure provides more reactive sites for the catalytic reaction. Meanwhile, introducing Pt into the catalyst can enhance the carrier conduction rate of BiOBr. Moreover, it can act as an electron trap to capture many surrounding electrons and inhibit the complexation of photogenerated carriers, thus improving the catalytic activity of CO2 reduction. The main product of BiOBr-Pt was CO with 99% product selectivity and its CO yield was 20.8 μmol·h-1· g-1. Its performance was 2.1 times that of primitive BiOBr. This Pt loading with a hierarchical hollow structure can effectively convert CO2.
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    1. [1]

      Wang H J, Wang Y J, Guo L J, Zhang X H, Ribeiro C, He T. Solarheating boosted catalytic reduction of CO2 under full-solar spectrum[J]. Chinese J. Catal., 2020,41(1):131-139. doi: 10.1016/S1872-2067(19)63393-0

    2. [2]

      Bie C B, Yu H G, Cheng B, Ho W K, Fan J J, Yu J G. Design, fabrication, and mechanism of nitrogen-doped graphene-based photocatalyst[J]. Adv. Mater., 2021,33(9)2003521. doi: 10.1002/adma.202003521

    3. [3]

      Das S, Pérez-Ramírez J, Gong J L, Dewangan N, Hidajat K, Gates B C, Kawi S. Core-shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO2[J]. Chem. Soc. Rev., 2020,49(10):2937-3004. doi: 10.1039/C9CS00713J

    4. [4]

      Jin X L, Lv C D, Zhou X, Xie H Q, Sun S F, Liu Y, Meng Q Q, Chen G. A bismuth rich hollow Bi4O5Br2 photocatalyst enables dramatic CO2 reduction activity[J]. Nano Energy, 2019,64103955. doi: 10.1016/j.nanoen.2019.103955

    5. [5]

      Li Q, Tang Q J, Xiong P Y, Chen D Z, Chen J M, Wu Z B, Wang H Q. Effect of palladium chemical states on CO2 photocatalytic reduction over g-C3N4: Distinct role of single-atomic state in boosting CH4 production[J]. Chinese J. Catal., 2023,46:177-190. doi: 10.1016/S1872-2067(22)64199-8

    6. [6]

      Zhou Y S, Wang Z T, Huang L, Zaman S, Lei K, Yue T, Li Z A, You B, Xia B Y. Engineering 2D photocatalysts toward carbon dioxide reduction[J]. Adv. Energy Mater., 2021,11(8)2003159. doi: 10.1002/aenm.202003159

    7. [7]

      Bai Y, Yang P, Wang L, Yang B, Xie H Q, Zhou Y, Ye L Q. Ultrathin Bi4O5Br2 nanosheets for selective photocatalytic CO2 conversion into CO[J]. Chem. Eng. J., 2019,360:473-482. doi: 10.1016/j.cej.2018.12.008

    8. [8]

      Wang M Y, Quesada-Cabrera R, Sathasivam S, Blunt M O, Borowiec J, Carmalt C J. Visible-light-active iodide-doped BiOBr coatings for sustainable infrastructure[J]. ACS Appl. Mater. Interfaces, 2023,15(42):49270-49280. doi: 10.1021/acsami.3c11525

    9. [9]

      XU L M, HUANG H B, SHEN J H, YOU Q H. Synthesis of Zn-doped BiOBr with enhanced photoreduction CO2 activity under visible light irradiation[J]. Chinese J. Inorg. Chem., 2020,36(12):2395-2403. doi: 10.11862/CJIC.2020.262

    10. [10]

      Deng C H, Guan H M. Fabrication of hollow inorganic fullerene-like BiOBr eggshells with highly efficient visible light photocatalytic activity[J]. Mater. Lett., 2013,107:119-122. doi: 10.1016/j.matlet.2013.05.041

    11. [11]

      GUO Q, TANG G B, WANG H, SUN Q, GAO X Y. Tunable synthesis of BiOBr for efficient photocatalytic degradation of carbamazepine in wastewater[J]. Chem. J. Chinese Universities, 2019,40(10):2164-2169. doi: 10.7503/cjcu20190229

    12. [12]

      HU H M, WANG T, LING X H, PENG L L, WANG T, HE Y Y, SUN Y T, DENG C H. Preparation and photocatalytic CO2 reduction performance of BiOBr-OV/RGO composite[J]. Chinese J. Inorg. Chem., 2023,39(2):234-244. doi: 10.11862/CJIC.2022.290

    13. [13]

      Devarayapalli K C, Zeng J, Lee D S, Vattikuti S V P, Shim J. In-situ Pt nanoparticles decorated BiOBr heterostructure for enhanced visible light-based photocatalytic activity: Synergistic effect[J]. Chemosphere, 2022,298134125. doi: 10.1016/j.chemosphere.2022.134125

    14. [14]

      JI L, WANG H R, YU R M. Preparation, characterization and visiblelight photocatalytic activities of p-n heterojunction BiOBr/NaBiO3 composites[J]. Chem. J. Chinese Universities, 2014,35(10):2170-2176. doi: 10.7503/cjcu20140339

    15. [15]

      Zhao J L, Miao Z R, Zhang Y F, Wen G Y, Liu L H, Wang X X, Cao X Z, Wang B Y. Oxygen vacancy-rich hierarchical BiOBr hollow microspheres with dramatic CO2 photo-reduction activity[J]. J. Colloid Interface Sci., 2021,593:231-243. doi: 10.1016/j.jcis.2021.02.117

    16. [16]

      Han L P, Guo Y X, Lin Z, Huang H W. 0D to 3D controllable nanostructures of BiOBr via a facile and fast room-temperature strategy[J]. Colloid Surf. A-Physicochem. Eng., 2020,603(10)125233.

    17. [17]

      Jiang Q, Ji M X, Chen R, Zhang Y, Li K, Meng C X, Chen Z G, Li H M, Xia J X. Ionic liquid induced mechanochemical synthesis of BiOBr ultrathin nanosheets at ambient temperature with superior visible light driven photocatalysis[J]. J. Colloid Interface Sci., 2020,574:131-139. doi: 10.1016/j.jcis.2020.04.018

    18. [18]

      Chai B, Zhou H, Zhang F, Liao X, Ren M X. Visible light photocatalytic performance of hierarchical BiOBr microspheres synthesized via a reactable ionic liquid[J]. Mat. Sci. Semicon. Proc., 2014,23:151-158. doi: 10.1016/j.mssp.2014.02.021

    19. [19]

      Liu H, Li W, Shen D K, Zhao D Y, Wang G X. Graphitic carbon conformal coating of mesoporous TiO2 hollow spheres for high performance lithium ion battery anodes[J]. J. Am. Chem. Soc., 2015,137(40):13161-13166. doi: 10.1021/jacs.5b08743

    20. [20]

      Lin X H, Wang S B, Tu W G, Wang H J, Hou Y D, Dai W X, Xu R. Magnetic hollow spheres assembled from graphene-encapsulated nickel nanoparticles for efficient photocatalytic CO2 reduction[J]. ACS Appl. Energy Mater., 2019,2(10):7670-7678. doi: 10.1021/acsaem.9b01673

    21. [21]

      Cai M J, Wu Z Y, Li Z, Wang L, Sun W, Tountas A A, Li C R, Wang S H, Feng K, Xu A B, Tang S L, Tavasoli A, Peng M W, Liu W X, Helmy A S, He L, Ozin G A, Zhang X H. Greenhouse-inspired supraphotothermal CO2 catalysis[J]. Nat. Energy, 2021,6(8):807-814. doi: 10.1038/s41560-021-00867-w

    22. [22]

      Ren G M, Shi M, Li Z Z, Zhang Z S, Meng X C. Electronic metal-support interaction via defective-induced platinum modified BiOBr for photocatalytic N2 fixation[J]. Appl. Catal. B, 2023,327122462. doi: 10.1016/j.apcatb.2023.122462

    23. [23]

      Shi M, Ren G M, Zhang Z S, Li Z Z, Meng X C. Strong metal-carrier interactions via modulation of Pt oxidation states on defective BiOBr with greatly improved photocatalytic activity[J]. Sol. Energy, 2023,261:33-42. doi: 10.1016/j.solener.2023.05.049

    24. [24]

      Zhang G Q, Cai L, Zhang Y F, Wei Y. Bi5+, Bi(3-x)+, and oxygen vacancy induced BiOClxI1-x solid solution toward promoting visiblelight driven photocatalytic activity[J]. Chem.-Eur. J., 2018,24(29):7434-7444. doi: 10.1002/chem.201706164

    25. [25]

      Wang B, Zhang W, Liu G P, Chen H L, Weng Y X, Li H M, Chu P K, Xia J X. Excited electron-rich Bi (3-x)+sites: A quantum well-like structure for highly promoted selective photocatalytic CO2 reduction performance[J]. Adv. Funct. Mater., 2022,32(35)2202885. doi: 10.1002/adfm.202202885

    26. [26]

      Wu J, Li X D, Shi W, Ling P Q, Sun Y F, Jiao X C, Gao S, Liang L, Xu J Q, Yan W S, Wang C M, Xie Y. Efficient visible-light-driven CO2 reduction mediated by defect-engineered BiOBr atomic layers[J]. Chem. Int. Ed., 2018,57(28):8719-8723. doi: 10.1002/anie.201803514

    27. [27]

      Gong M, Zhao H, Pan C S, Dong Y M, Guo Y X, Li H X, Zhang J W, Wang G L, Zhu Y F. Highly selective photocatalytic oxidation of 5-hydroxy-methylfurfural by interfacial Pt—O bonding Pt-Ov-BiOBr[J]. New J. Chem., 2023,47(15):7118-7126. doi: 10.1039/D3NJ00498H

    28. [28]

      Xu C P, Ravi Anusuyadevi P, Aymonier C, Luque R, Marre S. Nanostructured materials for photocatalysis[J]. Chem. Soc. Rev., 2019,48(14):3868-3902. doi: 10.1039/C9CS00102F

    29. [29]

      Wei Y Z, Yang N L, Huang K K, Wan J W, You F F, Yu R B, Feng S H, Wang D. Steering hollow multishelled structures in photocatalysis: Optimizing surface and mass transport[J]. Adv. Mater., 2020,32(44)2002556. doi: 10.1002/adma.202002556

    30. [30]

      Wang L B, Cheng B, Zhang L Y, Yu J G. In situ irradiated XPS investigation on S-scheme TiO2@ZnIn2S4 photocatalyst for efficient photocatalytic CO2 reduction. Small,2021,17(41): e2103447

    31. [31]

      Li X M, Dong Q B, Li F, Zhu Q H, Tian Q Y, Tian L, Zhu Y Y, Pan B, Padervand M, Wang C Y. Defective Bi@BiOBr/C microrods derived from Bi-MOF for efficient photocatalytic NO abatement: Directional regulation of interfacial charge transfer via carbon-loading[J]. Appl. Catal. B, 2024,340123238. doi: 10.1016/j.apcatb.2023.123238

    32. [32]

      Li X D, Wang S M, Li L, Sun Y F, Xie Y. Progress and perspective for in situ studies of CO2 reduction[J]. J. Am. Chem. Soc., 2020,142(21):9567-9581.

    33. [33]

      Wang X Y, Wang Y S, Gao M C, Shen J N, Pu X P, Zhang Z Z, Lin H X, Wang X X. BiVO4/Bi4Ti3O12 heterojunction enabling efficient photocatalytic reduction of CO2 with H2O to CH3OH and CO. Appl. Catal. B-Environ.,2020,270: 118876

    34. [34]

      Gao S Q, Zhang Q, Su X F, Wu X K, Zhang X G, Guo Y Y, Li Z Y, Wei J S, Wang H Y, Zhang S J, Wang J J. Ingenious artificial leaf based on covalent organic framework membranes for boosting CO2 photoreduction[J]. J. Am. Chem. Soc., 2023,145(17):9520-9529. doi: 10.1021/jacs.2c11146

    35. [35]

      Zhang Z Z, Wang M Y, Chi Z X, Li W J, Yu H, Yang N, Yu H B. Internal electric field engineering step-scheme-based heterojunction using lead free Cs3Bi2Br9 perovskite modified In4SnS8 for selective photocatalytic CO2 reduction to CO[J]. Appl. Catal. B, 2022,313121426. doi: 10.1016/j.apcatb.2022.121426

    36. [36]

      Ou H H, Ning S B, Zhu P, Chen S H, Han A, Kang Q, Hu Z F, Ye J H, Wang D S, Li Y D. Carbon nitride photocatalysts with integrated oxidation and reduction atomic active centers for improved CO2 conversion[J]. Chem. Int. Ed., 2022,61(34)e202206579. doi: 10.1002/anie.202206579

    37. [37]

      Lv C M, Huang K, Fan Y, Xu J, Lian C, Jiang H L, Zhang Y Z, Ma C, Qiao W M, Wang J T, Ling L C. Electrocatalytic reduction of carbon dioxide in confined microspace utilizing single nickel atom decorated nitrogen-doped carbon nanospheres[J]. Nano Energy, 2023,111108384. doi: 10.1016/j.nanoen.2023.108384

    38. [38]

      Zou H Y, Zhao G, Dai H, Dong H L, Luo W, Wang L, Lu Z G, Luo Y, Zhang G Z, Duan L L. Electronic perturbation of copper singleatom CO2 reduction catalysts in a molecular way[J]. Angew. Chem. Int. Ed., 2022,62(6)e202217220.

    39. [39]

      Wang F L, Fang R Q, Zhao X, Kong X P, Hou T T, Shen K, Li Y W. Ultrathin nanosheet assembled multishelled superstructures for photocatalytic CO2 reduction[J]. ACS Nano, 2022,16(3):4517-4527. doi: 10.1021/acsnano.1c10958

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