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Citation: Kun WANG, Wenrui LIU, Peng JIANG, Yuhang SONG, Lihua CHEN, Zhao DENG. Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037 shu

Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO2 reduction

  • State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China

  • Corresponding author: Zhao DENG, dengzhao@whut.edu.cn
  • Received Date: 25 January 2024
    Revised Date: 28 May 2024

Figures(9)

  • BiOBr-Pt catalysts with hierarchical hollow structures were synthesized by a one-step solvothermal method using ethylene glycol as solvent and polyvinylpyrrolidone as surfactant. The synthesized hierarchical hollow structure BiOBr-2h catalyst had a specific surface area of 28 m2·g-1, twice as large as the comparison sample BiOBr-1h. This structure provides more reactive sites for the catalytic reaction. Meanwhile, introducing Pt into the catalyst can enhance the carrier conduction rate of BiOBr. Moreover, it can act as an electron trap to capture many surrounding electrons and inhibit the complexation of photogenerated carriers, thus improving the catalytic activity of CO2 reduction. The main product of BiOBr-Pt was CO with 99% product selectivity and its CO yield was 20.8 μmol·h-1· g-1. Its performance was 2.1 times that of primitive BiOBr. This Pt loading with a hierarchical hollow structure can effectively convert CO2.
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