Citation: Qilu DU, Li ZHAO, Peng NIE, Bo XU. Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006 shu

Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands

Guizhou Institute for Food and Drug Control, Guiyang 550004, China

Corresponding author: Peng NIE, niepeng2001@163.com
Received Date: 4 January 2023
Revised Date: 16 March 2024

Figures(5)

Reaction of [OsGe(ArTrip)(PPh₃)(H)Cl₂] (1), where ArTrip=C₆H₃-2-(η⁶-Trip)-6-Trip and Trip=2, 4, 6-ⁱPr₃-C₆H₃, with Grignard reagent EtMgBr afforded [OsGe(ArTrip)(PPh₃)(H)Br₂] (2) and [OsGe(ArTrip)(PPh₃)(H)Et₂] (3), respectively, depending on the temperature and reaction molar ratio. Unexpected formation of 2 and 3 underwent replacement of Cl atom on Ge center with Br instead of Et group. In addition, the treatment of 1 with LiHBEt₃ also led to the formation of 3 without hydrogenation. Moreover, complex 1 reacted with HBF₄ to yield additional product [OsGe(ArTrip)(PPh₃)(H)₂Cl₂]BF₄ (4), which converted back to 1 in the presence of H₂O (n_H₂O/n₄=1).
- osmium,
- germanium,
- bimetallic complex,
- substitution,
- addition
1. [1]
  Xue W X, Zhu Z W, Chen S X, You B, Tang C H. Atomically dispersed Co-N/C catalyst for divergent synthesis of nitrogen-containing compounds from alkenes[J]. J. Am. Chem. Soc., 2023,145(7):4142-4149. doi: 10.1021/jacs.2c12344
2. [2]
  Kushch N D, Kazakova A V, Dubrovskii A D, Shilov G V, Buravov L, Morgunov R B, Kurganova E V, Tanimoto Y, Yagubskii E B. Molecular magnetic semiconductors formed by cationic and anionic networks: (ET)₂Mn[N(CN)₂]₃ and (ET)₂CuMn[N(CN)₂]₄[J]. J. Mater. Chem., 2007,17(41):4407-4413. doi: 10.1039/b706129c
3. [3]
  Zou X Y, Li A, Ma C, Gao Z, Zhou B W, Zhu L, Huang Z. Nitrogen-doped carbon confined Cu-Ag bimetals for efficient electroreduction of CO₂ to high-order products[J]. Chem. Eng. J., 2023,468143606. doi: 10.1016/j.cej.2023.143606
4. [4]
  Cordero-Borboa A E, Sterling-Black E, Gómez-Cortés A, Vázquez-Zavala A. X-ray diffraction evidence of the single solid solution character of bi-metallic Pt-Pd catalyst particles on an amorphous SiO₂ substrate[J]. Appl. Surf. Sci., 2003,220(1/2/3/4):169-174.
5. [5]
  Fu F L, Cheng Z H, Lu J W. Synthesis and use of bimetals and bimetal oxides in contaminants removal from water: A review[J]. RSC Adv., 2015,5(104):85395-85409. doi: 10.1039/C5RA13067K
6. [6]
  Raza N, Kumar T, Singh V, Kim K H. Recent advances in bimetallic metal-organic framework as a potential candidate for supercapacitor electrode material[J]. Coord. Chem. Rev., 2021,430213660. doi: 10.1016/j.ccr.2020.213660
7. [7]
  Soni J, Sethiya A, Sahiba N, Agarwal S. Recent advancements in organic synthesis catalyzed by graphene oxide metal composites as heterogeneous nanocatalysts[J]. Appl. Organometal. Chem., 2021,35(4)e6162. doi: 10.1002/aoc.6162
8. [8]
  Yang Y, Jia T, Han Y Z, Nan Z A, Yuan S F, Yang F L, Sun D. An All-alkynyl protected 74-nuclei silver(Ⅰ)-copper(Ⅰ)-oxo nanocluster: Oxo-induced hierarchical bimetal aggregation and anisotropic surface ligand orientation[J]. Angew. Chime. Int. Ed., 2019,58(35):12280-12285. doi: 10.1002/anie.201906538
9. [9]
  Gholinejad M, Khosravi F, Afrasi M, Sansano J M, Najera C. Applications of bimetallic PdCu catalysts[J]. Catal. Sci. Technol., 2021,11(8):2652-2702. doi: 10.1039/D0CY02339F
10. [10]
  Liu Z H, Hao W J, Liu Z X, Gao W, Zhang Z H, Zhang Y N, Li X, Tong L L, Tang B. Bimetal-catalyzed cascade reaction for efficient synthesis of n-isopropenyl 1, 2, 3-triazoles via in-situ generated 2- azidopropenes[J]. Chem.-Asian J., 2019,14(12):2149-2154. doi: 10.1002/asia.201900402
11. [11]
  Gao Y Q, Zhang D W, Yuan H, Min Y X, Chen S Y, Xu L. Long distance bimetallic site in crystal with relay metal-N-N-metal mechanism and new descriptors for electrocatalytic nitrogen reduction reaction[J]. Appl. Catal. A-Gen., 2023,652119030. doi: 10.1016/j.apcata.2023.119030
12. [12]
  Settimi C, Zingaretti D, Sanna S, Verginelli I, Luisetto I, Tebano A, Baciocchi R. Synthesis and characterization of zero-valent Fe-Cu and Fe-Ni bimetals for the dehalogenation of trichloroethylene vapors[J]. Sustainability, 2022,14(13)7760. doi: 10.3390/su14137760
13. [13]
  Özdemir Z. Effect of heat treatment on the impact toughness of 'high-chromium cast iron-low alloy steel' bimetal components[J]. Met. Sci. Heat Treat., 2017,58(11/12):738-741.
14. [14]
  Zhao X X, Wei J N, Xi Z F. Light-driven dinitrogen activation with transition metal complexes: Mechanisms and applications[J]. Chin. J. Chem., 2023,41(18):2400-2407. doi: 10.1002/cjoc.202300151
15. [15]
  Zhong M D, Cui X L, Wu B T, Wang G X, Zhang W X, Wei J N, Zhao L L, Xi Z F. Dinitrogen functionalization affording structurally well-defined cobalt diazenido complexes[J]. CCS Chem., 2022,4(2):532-539. doi: 10.31635/ccschem.021.202100945
16. [16]
  Raidt M, Siegfried L, Kaden T A. Formation and dissociation kinetics of dinuclear metal complexes with pyrazole and triazole bridged bis-macrocycles[J]. Dalton Trans., 2003,23:4493-4497.
17. [17]
  Maurya R R, Mohan V, Singh P, Singh S, Bahadur I. A novel benzimidazole based cadmium(Ⅱ) dinuclear complex as bioactive material with different coordination number and their interactions with BSA and HSA: Synthesis, characterization and docking studies[J]. J. Mol. Liq., 2021,328115471. doi: 10.1016/j.molliq.2021.115471
18. [18]
  Simon J, Stammler A, Oldengott J, Bögge H, Glaser T. Proof of phosphate diester binding ability of cytotoxic DNA-binding complexes[J]. Inorg. Chem., 2020,59(19):14615-14619. doi: 10.1021/acs.inorgchem.0c02644
19. [19]
  Manda S, Hari N, Monda S, Mohanta S. Dinuclear, dimer-of-dinuclear and new type of polymeric metal complexes of copper(Ⅱ)-zinc(Ⅱ)/cadmium(Ⅱ) derived from a less explored compartmental ligand[J]. Inorg. Chim. Acta, 2018,483:527-538. doi: 10.1016/j.ica.2018.08.017
20. [20]
  Xing J P, Jiang X, Wang P, Zhao J J. Bimetal single-molecule magnets supported on benzene with large magnetic anisotropy and unquenched orbital moment[J]. Phys. Rev. Res., 2021,3(3)033005. doi: 10.1103/PhysRevResearch.3.033005
21. [21]
  Gao H W, Zang J B, Liu X X, Wang Y H, Tian P F, Zhou S Y, Song S W, Chen P P, Li W. Ruthenium and cobalt bimetal encapsulated in nitrogen-doped carbon material derived of ZIF-67 as enhanced hydrogen evolution electrocatalyst[J]. Appl. Surf. Sci., 2019,494:101-110. doi: 10.1016/j.apsusc.2019.07.181
22. [22]
  Zhang P Y, Zeng G C, Song T, Huang S B, Wang T T, Zeng H P. Synthesis of a plasmonic CuNi bimetal modified with carbon quantum dots as a non-semiconductor-driven photocatalyst for effective water splitting[J]. J. Catal., 2019,369:267-275. doi: 10.1016/j.jcat.2018.11.003
23. [23]
  Qu Z Q, Sun Q M. Advances in zeolite-supported metal catalysts for propane dehydrogenation[J]. Inorg. Chem. Front., 2022,9(13):3095-3115. doi: 10.1039/D2QI00653G
24. [24]
  Esteruelas M A, González A I, López A M, Oñate E. An osmium- carbene complex with Fischer‑Schrock ambivalent behavior[J]. Organometallics, 2003,22:414-425. doi: 10.1021/om0208826
25. [25]
  Esteruelas M A, Oliván M, Oñate E, Ruiz N, Tajada M A. Synthesis of hydrido-vinylidene and hydrido-carbyne osmium complexes containing pyrazole: New examples of N—H…Y (Y=N, F, Cl) hydrogen bonds[J]. Organometallics, 1999,18:2953-2960. doi: 10.1021/om990234v
26. [26]
  Dong C H, Ji M S, Yang X Z, Yao J N, Chen H. Reaction mechanisms of CO₂ reduction to formaldehyde catalyzed by hourglass Ru, Fe, and Os complexes: A density functional theory study[J]. Catalysts, 2017,7(1)5.
27. [27]
  Huang C Y, Huang W Q, Ji P C, Song F L, Liu T, Li M Y, Guo H Z, Huang Y L, Yu C C, Wang C X, Ni W X. A pyrazolate osmium(Ⅵ) nitride exhibits anticancer activity through modulating protein homeostasis in HepG2 cells[J]. Int. J. Mol. Sci., 2022,23(21)12779. doi: 10.3390/ijms232112779
28. [28]
  Baya M, Crochet P, Esteruelas M A, Gutierrez-Puebla E, Ruiz N. Oxidative addition of HX (X=H, SiR₃, GeR₃, SnR₃, Cl) molecules to the complex Os(η⁵-C₅H₅)Cl(PiPr₃)₂[J]. Organometallics, 1999,18:5034-5043. doi: 10.1021/om990235n
29. [29]
  Baya M, Esteruelas M A, Oñate E. Influence of the group 14 element on the deprotonation of OsH(η⁵-C₅H₅)(C≡CPh)(EPh₃)(PiPr₃) (E=Si, Ge): Two different organometallic chemistries[J]. Organometallics, 2001,20:4875-4886. doi: 10.1021/om010504l
30. [30]
  Pöller S, Beyl Y, Vivekananthan J, Guschin D A, Schuhmann W. A new synthesis route for Os-complex modified redox polymers for potential biofuel cell applications[J]. Bioelectrochemistry, 2012,87:178-184. doi: 10.1016/j.bioelechem.2011.11.015
31. [31]
  Wang D M, Zhai C, Chen Y Z, He Y H, Chen X D, Wang S L, Zhao L L, Frenking G, Wang X P, Tan G W. An isolable germylyne radical with a one-coordinate germanium atom[J]. Nat. Chem., 2023,15(2)200. doi: 10.1038/s41557-022-01081-1
32. [32]
  SUN C C, BI J L. Influence of edge modification on the electronic structure of germanene nanoribbons[J]. Materials Reports, 2023,37(13):151-158.
33. [33]
  ZHANG Y, SHAN T, WANG Y, ZHONG H L. Non-fullerene acceptors with germanium as bridge atom and their applications in organic solar cells[J]. Chem. J. Chinese Universities, 2023,44(7):151-158.
34. [34]
  XU Q H, XIAO B. Cross-coupling reactions of organogermanium nucleophiles[J]. Chemistry, 2020,83(7):610-614.
35. [35]
  Nie P, Yu Q, Zhu H P, Wen T B. Ruthenium and osmium germyl complexes derived from the reactions of MXCl(PPh₃)₃ (M=Ru, Os; X=Cl, H) with terphenylchlorogermylene (C₆H₃-2, 6-Trip₂)GeCl (Trip=2, 4, 6-iPr₃C₆H₂)[J]. Eur. J. Inorg. Chem., 2017:4784-4796.
36. [36]
  Hildebrandt J, Häfner N, Kritsch D, Görls H, Dürst M, Runnebaum I B, Weigand W. Highly cytotoxic osmium(Ⅱ) compounds and their ruthenium(Ⅱ) analogues targeting ovarian carcinoma cell lines and evading cisplatin resistance mechanisms[J]. Int. J. Mol. Sci., 2022,23(9)4976. doi: 10.3390/ijms23094976
37. [37]
  Wen T B, Hung W Y, Zhou Z Y, Lo M F, Williams I D, Jia G C. Synthesis and characterization of[OsCl₂(=C=CHR)(PPh₃)₂] and related complexes[J]. Eur. J. Inorg. Chem., 2004:2837-2846.
38. [38]
  Clark A M, Rickard C E F, Roper W R, Woodman T J, Wright L J. Stepwise conversion of an osmium trimethylstannyl complex to a triiodostannyl complex and nucleophilic substitution reactions at the tin-iodine bonds[J]. Organometallics, 2000,19:1766-1774. doi: 10.1021/om990904x
39. [39]
  Esteruelas M A, González A I, López A, Oliván M, Oñate E. Preparation of half-sandwich osmium-allyl complexes by consecutive C—C bond formation and C—H bond activation reactions[J]. Organometallics, 2006,25:693-705. doi: 10.1021/om050907b
40. [40]
  Buil M L, Esteruelas M A, Garcés K, García-Raboso J, Oliván M. Trapping of a 12‑valence‑electron osmium intermediate[J]. Organometallics, 2009,28:4606-4609. doi: 10.1021/om9002544
41. [41]
  Dub P A, Fillipov O A, Silantyev G A, Belkova N V, Daran J C, Epstein L M, Poli R, Shubina E S. Protonation of Cp*M(dppe)H hydrides: Peculiarities of the osmium congener[J]. Eur. J. Inorg. Chem., 2010:1489-1500.
42. [42]
  Esteruelas M A, García-Raboso J, Oliván M. Preparation of half-sandwich osmium complexes by deprotonation of aromatic and pro-aromatic acids with a hexahydride brønsted base[J]. Organometallics, 2011,30:3844-3852. doi: 10.1021/om200371r
43. [43]
  Baya M, Esteruelas M A, Oliván M, Oñate E. Monocationic trihydride and dicationic dihydride-dihydrogen and bis(dihydrogen) osmium complexes containing cyclic and acyclic triamine ligands: Influence of the N—Os—N angles on the hydrogen-hydrogen interactions[J]. Inorg. Chem., 2009,48:2677-2686. doi: 10.1021/ic8023259
1. [1]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
2. [2]
  Jiaqi AN , Yunle LIU , Jianxuan SHANG , Yan GUO , Ce LIU , Fanlong ZENG , Anyang LI , Wenyuan WANG . Reactivity of extremely bulky silylaminogermylene chloride and bonding analysis of a cubic tetragermylene. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1511-1518. doi: 10.11862/CJIC.20240072
3. [3]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
4. [4]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
7. [7]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
8. [8]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
9. [9]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
10. [10]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
11. [11]
  Daojuan Cheng , Fang Fang . Exploration and Implementation of Science-Education Integration in Organic Chemistry Teaching for Pharmacy Majors: A Case Study on Nucleophilic Substitution Reactions of Alkyl Halides. University Chemistry, 2024, 39(11): 72-78. doi: 10.12461/PKU.DXHX202403105
12. [12]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
13. [13]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
18. [18]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
19. [19]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
20. [20]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(112)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142