Citation: Lu LIU, Huijie WANG, Haitong WANG, Ying LI. Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489 shu

Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline

School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, Henan 453003, China

Corresponding author: Lu LIU, liululiulu2012@126.com Ying LI, hnliy0412@126.com
Received Date: 30 December 2023
Revised Date: 11 April 2024

Figures(14)

A Cd(Ⅱ) complex, formulated as {(H₂dbim)_0.5[Cd(Hbptc)]·H₂O}_n (1), where dbim=1-(4-((2, 6-dimethyl-2H-benzo[d]imidazol-3(3H)-yl)methyl)benzyl)-2, 7-dihydro-2, 5-dimethyl-1H-benzo[d]imidazole, H₄bptc=3, 3', 4, 4'-benzophenone tetracarboxylic acid, has been obtained by hydrothermal reactions and structurally characterized. Complex 1 exhibits a 2D layer with a point symbol of {4⁴·6⁶}. Complex 1 was used for fluorescence identification of some common environmental pollutants. The result of the research shows that complex 1 can effectively detect p-nitrophenol, tetracycline, and 2, 6-dichloro-4-nitroaniline. The calculated quenching constants for p-nitrophenol, tetracycline, and 2, 6-dichloro-4-nitroaniline were 2×10², 5.4×10⁴, and 2×10⁴ L·mol^-1, respectively.
- Cd (Ⅱ) complex,
- crystal structure,
- topology structure,
- fluorescence recognition
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