Citation: Gaofeng WANG, Shuwen SUN, Yanfei ZHAO, Lixin MENG, Bohui WEI. Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479 shu

Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone

  • Corresponding author: Gaofeng WANG, wgf1979@126.com
  • Received Date: 19 December 2023
    Revised Date: 9 March 2024

Figures(9)

  • Three zinc coordination polymers, {[Zn2(bipmo)2(ipa)2]·3H2O}n (1), {[Zn(bipmo)(5-OH-ipa)]·DMA·H2O}n (2), and {[Zn(bipmo)(5-Me-ipa)]·H2O}n (3), where bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2ipa=isophthalic acid, 5-OH-ipaH2=5-hydroxyisophthalic acid, 5-Me-ipaH2=5-methylisophthalic acid, were synthesized under solvothermal conditions. These complexes have been characterized by elemental analyses, IR spectra, single-crystal X-ray diffraction, etc. Complex 1 shows a 2D 2-fold interpenetrating {44·62} network. Complex 2 displays a 2D uninodal framework with the {65·8} topology. Complex 3 reveals a 2D layer structure with {63} topology. The results indicate that the presence of a 5-substituted group in the isophthalate exerts a significant influence on the formation of the final structures. The luminescent properties of the complexes in the solid state have also been studied.
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