Citation: Xiaoxia WANG, Ya'nan GUO, Feng SU, Chun HAN, Long SUN. Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478 shu

Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters

Department of Chemistry, Changzhi University, Changzhi, Shanxi 046011, China

Corresponding author: Long SUN, sxsunlong@163.com
Received Date: 19 December 2023
Revised Date: 16 February 2024

Figures(7)

To explore the diversity of structure and optoelectronic applications of metal chalcogenide cluster materials, two Sb-based chalcogenide cluster compounds [Sb₄S₅(S₃)]·C₅H₁₁N (1) and (C₅H₁₂N)₂[In₂Sb₂S₇] (2) have been synthesized through solvothermal method using asymmetric coordination geometry with Sb(Ⅲ) containing lone pair electrons and sulfur. The two compounds consist of combinations between {SbS₃} or {InS₄} coordination units in a vertex-sharing manner, respectively. The electrocatalytic oxygen reduction reaction (ORR) studies showed that the limit current density and half-wave potential of compound 2 were higher than those of compound 1, indicating better ORR performance. The Koutecky-Levich plot analysis showed that the ORR catalytic process of layered compound 2 constructed from mixed metals is mainly through a four-electron pathway.
- metal sulfide,
- cluster chemistry,
- crystal structure,
- oxygen reduction reaction
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