Citation: Zhiwen HU, Weixia DONG, Qifu BAO, Ping LI. Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462 shu

Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis

Zhiwen HU ^{1, 2} ,
Weixia DONG ^{1, 2,,} ,
Qifu BAO ¹ ,
Ping LI ¹

1.
School of Materials Science and Engineering, Jingdezhen Ceramic University, Jingdezhen, Jiangxi 333403, China
2.
State Key Laboratory of Silicon Materials, Zhejiang University, Hangzhou 310027, China

Corresponding author: Weixia DONG, weixia_dong@sina.com
Received Date: 8 December 2023
Revised Date: 13 March 2024

Figures(9)

BaTiO₃ was synthesized at low-temperatures based on the starch gelatinization mechanism. The morphology and phase structure of as-synthesized samples were characterized by scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), UV visible (UV-Vis) absorption spectra, and X-ray photoelectron spectroscopy (XPS). The piezocatalytic performance of BaTiO₃ was tested targeting a series of typical dyes for degradation. The results showed that tetragonal BaTiO₃ powder was obtained at a calcination temperature of 600 ℃, and the crystallinity gradually increased with the increase in temperature. Cubic-like BaTiO₃ with uniform size distribution was synthesized at a calcination temperature of 700 ℃; The degradation of rhodamine B (RhB), Congo red (CR), and methyl orange (MO) dyes by BaTiO₃ all showed good performance, with reaction rate constants of 1.090×10^-2, 1.113×10^-2, and 1.084×10^-2 min^-1, respectively. Furthermore, the mechanism of piezocatalysis reveals that the hole (h⁺) and superoxide radicals (·O₂^-) are the main reactive species in the degradation process by targeting the degradation of CR.
- starch gelatinization,
- low-temperature,
- BaTiO₃,
- piezocatalysis
1. [1]
  Liu D M, Jin C C, Shan F K. Synthesizing BaTiO₃ nanostructures to explore morphological influence, kinetics, and mechanism of piezocatalytic dye degradation[J]. ACS Appl. Mater. Interfaces, 2020,12(15):17443-17451. doi: 10.1021/acsami.9b23351
2. [2]
  Ray S K, Cho J W, Jin H. A critical review on strategies for improving efficiency of BaTiO₃-based photocatalysts for wastewater treatment[J]. J. Environ. Manage., 2021,290(1)112679.
3. [3]
  Wu J, Qin N, Bao D H. Effective enhancement of piezocatalytic activity of BaTiO₃ nanowires under ultrasonic vibration[J]. Nano Energy, 2018,45:44-51. doi: 10.1016/j.nanoen.2017.12.034
4. [4]
  Jin C C, Liu D M, Hu J. The role of microstructure in piezocatalytic degradation of organic dye pollutants in wastewater[J]. Nano Energy, 2019,59:372-379. doi: 10.1016/j.nanoen.2019.02.047
5. [5]
  Yuan B W, Jiang W, Qin N. Enhanced piezocatalytic performance of (Ba, Sr)TiO₃ nanowires to degrade organic pollutants[J]. ACS Appl. Nano Mater., 2018,1(9):5119-5127. doi: 10.1021/acsanm.8b01206
6. [6]
  Xu S Y, Guo L M, Sun Q J. Piezotronic effect enhanced plasmonic photocatalysis by AuNPs/BaTiO₃ heterostructures[J]. Adv. Funct. Mater., 2019,29(13)1808737. doi: 10.1002/adfm.201808737
7. [7]
  DING H Y, SHANG S M, QIN G M. Submicron tetragonal barium titanate: Preparation by solid state reaction at low temperature and crystal phase control[J]. Chinese J. Inorg. Chem., 2018,34(8):1483-1488.
8. [8]
  Cheng Y, Liang K X, Chen Y F. Effect of molecular structure changes during starch gelatinization on its rheological and 3D printing properties[J]. Food Hydrocolloids, 2023,137108364. doi: 10.1016/j.foodhyd.2022.108364
9. [9]
  Gao R J, Guo W J, Zhang Y D. Enhancement of gelatinization on electrochemical performance of corn starch-based porous carbon as electrode material in supercapacitors[J]. Diam. Relat. Mat., 2024,141110598. doi: 10.1016/j.diamond.2023.110598
10. [10]
  Zhang C H, Wang Y X, Zheng J X. Improved supercapacitor performance of α-starch-derived porous carbon through gelatinization[J]. J. Power Sources, 2022,521230942. doi: 10.1016/j.jpowsour.2021.230942
11. [11]
  HU Z W, DONG W X, BAO Q F. Preparation and piezocatalytic properties of Rubik's cube-like nano-microstructure BaTiO₃[J]. Chinese J. Inorg. Chem., 2023,39(3):475-484.
12. [12]
13. [13]
  Fei R, Zhu G G, Zhang W B. In-situ generation of oxygen vacancies and metallic bismuth from (BiO)₂CO₃ via N₂-assisted thermal-treatment for efficient selective photocatalytic NO removal[J]. Appl. Catal. B-Environ., 2020,281119481.
14. [14]
  Yashika G, Albanesi E A, Walz M V. Grain size and lattice parameter's influence on band gap of SnS thin nano-crystalline films[J]. Thin Solid Films, 2016,612:310-316. doi: 10.1016/j.tsf.2016.05.056
15. [15]
  Wang S J, Qu P, Li C. Hydrothermal synthesis of dendritic BaTiO₃ ceramic powders and its application in BaTiO₃/P(VDF-TrFE) composites[J]. Int. J. Appl. Ceram. Technol., 2017,14(5):969-975. doi: 10.1111/ijac.12716
16. [16]
  Wang W, Zhou H X, Yang H. Effects of salts on the gelatinization and retrogradation properties of maize starch and waxy maize starch[J]. Food Chem., 2017,214:319-327. doi: 10.1016/j.foodchem.2016.07.040
17. [17]
  Zhao T T, Zhang H C, Chen F F. Study on structural changes of starches with different amylose content during gelatinization process[J]. Starch-Stärke, 2022,74(7/8)2100269.
18. [18]
  Wu J R, Wang W W, Tian Y. Piezotronic effect boosted photocatalytic performance of heterostructured BaTiO₃/TiO₂ nanofibers for degradation of organic pollutants[J]. Nano Energy, 2020,77105122. doi: 10.1016/j.nanoen.2020.105122
19. [19]
  Xu X L, Wu Z, Xiao L B. Strong piezo-electro-chemical effect of piezoelectric BaTiO₃ nanofibers for vibration-catalysis[J]. J. Alloy. Compd., 2018,762:915-921. doi: 10.1016/j.jallcom.2018.05.279
20. [20]
  Wu J, Xu Q, Lin E Z. Insights into the role of ferroelectric polarization in piezocatalysis of nanocrystalline BaTiO₃[J]. ACS Appl. Mater. Interfaces, 2018,10(21):17842-17849. doi: 10.1021/acsami.8b01991
21. [21]
  Li Q, Lewis J A. Nanoparticle inks for directed assembly of three-dimensional periodic structures[J]. Adv. Mater., 2003,15(19):1639-1643. doi: 10.1002/adma.200305413
22. [22]
  Wang S S, Wu Z, Chen J. Lead-free piezoelectric sodium niobate nanowires with strong piezo-catalysis for dye wastewater degradation[J]. Ceram. Int., 2019,45(9):11703-11708. doi: 10.1016/j.ceramint.2019.03.045
23. [23]
  You H L, Ma X X, Wu Z. Piezoelectrically/pyroelectrically-driven vibration/cold-hot energy harvesting for mechano-/pyro-bi-catalytic dye decomposition of NaNbO₃ nanofibers[J]. Nano Energy, 2018,52:351-359. doi: 10.1016/j.nanoen.2018.08.004
24. [24]
  Ling J S, Wang K, Wang Z Y. Enhanced piezoelectric-induced catalysis of SrTiO₃ nanocrystal with well-defined facets under ultrasonic vibration[J]. Ultrason. Sonochem., 2019,61104819.
25. [25]
  Lin E Z, Wu J, Qin N. Silver modified barium titanate as a highly efficient piezocatalyst[J]. Catal. Sci. Technol., 2018,8(18):4788-4796. doi: 10.1039/C8CY01127C
26. [26]
  Liu Q F, Ma J J, Sharma M. Photocatalytic, piezocatalytic, and piezo-photocatalytic effects in ferroelectric (Ba_0.875Ca_0.125)(Ti_0.95Sn_0.05)O₃ ceramics[J]. J. Am. Ceram. Soc., 2019,102(10):5807-5817. doi: 10.1111/jace.16502
27. [27]
  Yu C Y, Tan M X, Li Y. Ultrahigh piezocatalytic capability in eco-friendly BaTiO₃ nanosheets promoted by 2D morphology engineering[J]. J. Colloid Interface Sci., 2021,596(29):288-296.
28. [28]
  Zhou X F, Wu S H, Li C B. Piezophototronic effect in enhancing charge carrier separation and transfer in ZnO/BaTiO₃ heterostructures for high-efficiency catalytic oxidation[J]. Nano Energy, 2019,66104127. doi: 10.1016/j.nanoen.2019.104127
1. [1]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
4. [4]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
7. [7]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
8. [8]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
9. [9]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
10. [10]
  Lin Ding , Jinpeng Zhang , Junfeng Li , Daying Liu . Color Catcher: A Marvelous Encounter of Starch and Iodine. University Chemistry, 2024, 39(6): 334-341. doi: 10.3866/PKU.DXHX202311064
11. [11]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
12. [12]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
13. [13]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
14. [14]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
15. [15]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
16. [16]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
17. [17]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
18. [18]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
19. [19]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
20. [20]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(212)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis

Metrics

通讯作者: 陈斌, bchen63@163.com

Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis