Citation: Qiangqiang SUN, Pengcheng ZHAO, Ruoyu WU, Baoyue CAO. Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454 shu

Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis

Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources, Shaanxi Engineering Research Center for Mineral Resources Clean & Efficient Conversion and New Materials, Research Centre of Grapheme Technology and Application, School of Chemical Engineering and Modern Materials, Shangluo University, Shangluo, Shaanxi 726000, China

Corresponding author: Baoyue CAO, 231052@slxy.edu.cn
Received Date: 2 December 2023
Revised Date: 27 March 2024

Figures(6)

The multistage microporous electrocatalysts to assist the energy-efficient hydrogen generation from water electrolysis were fabricated on the surface of three-dimensional porous foam (NF) by a one-step hydrothermal synthesis strategy. When the molar ratio of sulfur to phosphorus in the initial mixed solution was 1∶1, an amorphous P-doped nickel-based sulfide (NiSP/NF) electrocatalyst, with Ni₃S₂ and NiPS₃ as the main and secondary crystalline phase, respectively, was obtained by hydrothermal treatment at 120 ℃ for 24 h. Thanks to its unique bi-hierarchy microporous structure composed of interwoven interconnected ultra-thin nanosheets, yielding the nearly 14-fold increased electrochemical active surface area (ECSA), sufficient active sites and interface channels are provided for hydrogen evolution reaction (HER) during water splitting. Meanwhile, benefiting from the lattice defects created by crystalline Ni₃S₂ and the strong electronic interactions with crystalline P doping phases, respectively, the intrinsically catalytic activity of nickel-based electrocatalyst was significantly enhanced. The synergistic effects enable NiSP/NF to exhibit remarkable performances during the whole water splitting, achieving a current density of 10 mA·cm^-2 in 1 mol·L^-1 KOH solution with overpotentials for HER and OER as low as 67 and 212 mV, respectively. Assembled as an electrolyzer for overall water splitting (OWS), a current density of 100 mA·cm^-2 can be achieved only needing a cell voltage of 1.878 V, even at 500 mA·cm^-2 the needed cell voltage was only 2.558 V for NiSP/NF, which is dramatically superior to noble metal catalysts and helpful to improve hydrogen production efficiency for water electrolysis. Particularly, as a bifunctional electrocatalyst, NiSP/NF also exhibited excellent long-term stability and durability, because of less than a 0.03 V cell voltage increase after running a 120-hour chronopotentiometric test at 500 mA·cm^-2.
- P-doping,
- hydrogen evolution reaction,
- oxygen evolution reaction,
- synergistic catalysis
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