Citation: Zhihuan XU, Qing KANG, Yuzhen LONG, Qian YUAN, Cidong LIU, Xin LI, Genghuai TANG, Yuqing LIAO. Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447 shu

Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS

  • Corresponding author: Yuqing LIAO, dido_liaoyq@163.com
  • Received Date: 28 November 2023
    Revised Date: 21 May 2024

Figures(9)

  • Reduced graphene oxide/ZnS (rGO/ZnS) composites were successfully prepared by hydrothermal method using graphene oxide (GO), zinc acetate (Zn(CH3COO)2), and thiourea as raw materials. The microstructure and morphology of the sample were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), etc. The material was used as anodes for lithium-ion batteries, and electrochemical test results demonstrated that the asprepared rGO/ZnS composite exhibited significantly enhanced electrochemical lithium storage performance in comparison to rGO. The highly conductive rGO can provide an efficient path for the transport of lithium ions and electrons, and ZnS can provide a high theoretical specific capacity. The rGO/ZnS composites exhibited good lithium intercalation capacity and cycling performance under the synergistic effect of rGO and nanoscale highly dispersed spherical ZnS particles. When the GO mass concentration was 2 mg·mL-1, the rGO/ZnS composites had the best rate performance and the best cycling stability.
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    1. [1]

      Bruce P G, Freunberger S A, Hardwick L J, Tarascon J M. Li-O2 and Li-S batteries with high energy storage[J]. Nat. Mater., 2012,11:19-29. doi: 10.1038/nmat3191

    2. [2]

      Armand M, Tarascon J M. Building better batteries[J]. Nature, 2008,451:652-657. doi: 10.1038/451652a

    3. [3]

      Tarascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001,414:359-367. doi: 10.1038/35104644

    4. [4]

      CHEN J, TAO Z L, GOU X L. Chemical power sources: Principles, technologies and applications. Beijing: Chemical Industry Press, 2006: 288-290

    5. [5]

      Tao S S, Cai J M, Cao Z W, Song B, Deng W T, Liu Y C, Hou H S, Zou G Q, Ji X B. Revealing the valence evolution of metal element in heterostructures for ultra-high power Li-ion capacitors[J]. Adv. Energy Mater., 2023,13(35)2301653. doi: 10.1002/aenm.202301653

    6. [6]

      Brandt K. Historical development of secondary lithium batteries[J]. Solid State Ionics, 1994,69(3/4):173-183.

    7. [7]

      Reddy M V, Subba R G V, Chowdari B V R. Metal oxides and oxysalts as anode materials for Li ion batteries[J]. Chem. Rev., 2013,113(7):5364-5457. doi: 10.1021/cr3001884

    8. [8]

      Whittingham S M. Ultimate limits to intercalation reactions for lithium batteries[J]. Chem. Rev., 2014,114(23):11414-11443. doi: 10.1021/cr5003003

    9. [9]

      Liu W J, Zhang X, Xu Y N, Wang L, Li Z, Li C, Wang K, Sun X Z, An Y B, Wu Z S, Ma Y W. 2D graphene/MnO heterostructure with strongly Stable interface enabling high performance flexible solid-state lithium-ion capacitors[J]. Adv. Funct. Mater., 2022,32(30)2202342. doi: 10.1002/adfm.202202342

    10. [10]

      YANG X L, WANG C H, LU Z J, PAN S G, FU Y S, WANG X. Three-dimensional porous carbon nanotube-reduced graphene oxide composite aerogel for high-performance symmetric supercapacitors[J]. Chinese J. Inorg. Chem., 2024,40(1):155-163.  

    11. [11]

      WU Y P, WAN C R, JIANG C Y. Lithium-ion rechargeable battery. Beijing: Chemical Industry Press, 2002: 2-5

    12. [12]

      WEI L, WANG J K, LIU K G, ZHOU Q Y, PAN H X, FAN S, ZHANG Y. Nanocellulose/reduced graphene oxide composites for high-performance supercapacitors[J]. Chinese J. Inorg. Chem., 2023,39(3):456-464.  

    13. [13]

      Tao S S, Momen R Y, Luo Z, Zhu Y R, Xiao X H, Cao Z W, Xiong D Y, Deng W T, Liu Y C, Hou H S, Zou G Q, Ji X B. Trapping lithium selenides with evolving heterogeneous interfaces for high-power lithium-ion capacitors[J]. Small, 2023,19(15)2207975. doi: 10.1002/smll.202207975

    14. [14]

      WANG H Q. Preparation of mesophase carbon microspheres and their electrochemical properties. Changsha: Central South University, 2004: 25-42

    15. [15]

      ZHOU H H, WU X, ZHOU C K, REN J G. Preparation and electrochemical properties of AlF3-coated natural graphite anode materials[J]. Chinese J. Inorg. Chem., 2018,34(4):676-682.  

    16. [16]

      Dunn B, Kamath H, Tarascon J M. Electrical energy storage for the grid: A battery of choices[J]. Science, 2011,334:928-935. doi: 10.1126/science.1212741

    17. [17]

      XU G, JIANG X N, CHEN W X. Preparation of ZnS@C/rGO composites and their electrochemical reversible lithium storage properties[J]. Chinese J. Inorg. Chem., 2022,38(5):891-900.  

    18. [18]

      TIAN Y, LI L, XIN Z X, ZHANG W Z, XU Y M. Multi-mode photo-degradation of flower globular heterostructure composites ZnS/ZnO/ZnWO4 and hydrogen production by photolysis of water[J]. Chinese J. Inorg. Chem., 2019,35(3):493-504.  

    19. [19]

      LIU H R, FANG L Y, JIA W, JIA H S. Hydrothermal preparation of ZnS nanospheres and their photocatalytic properties[J]. Chinese J. Inorg. Chem., 2015,31(3):459-464.  

    20. [20]

      Valet S, Bohlmann T, Burkert A, Ebell G. Zinc acetate containing gel pads for electrochemical measurements of Zn samples[J]. J. Electroanal. Chem., 2023,948117814. doi: 10.1016/j.jelechem.2023.117814

    21. [21]

      Liao Y Q, Wu C, Zhong Y T, Chen M, Cai L Y, Wang H R, Liu X, Cao G Z, Li W S. Highly dispersed Co-Mo sulfide nanoparticles on reduced graphene oxide for lithium and sodiumion storage[J]. Nano Res., 2020,13:188-195. doi: 10.1007/s12274-019-2594-2

    22. [22]

      Lu J H, Lian F, Guan L L, Zhang Y X, Ding F. Adapting FeS2 micron particles as an electrode material for lithium-ion batteries via simultaneous construction of CNT internal networks and external cages[J]. J. Mater. Chem. A, 2019,7(3):991-997. doi: 10.1039/C8TA09955C

    23. [23]

      HUI K L, FU J P, GAO T, TANG M X. Research progress of metal sulfides in batteries[J]. Chinese Journal of Applied Chemistry, 2020,37(12):1384-1402. doi: 10.11944/j.issn.1000-0518.2020.12.200190

    24. [24]

      LIU Y, YANG C T. Preparation and properties of NiO/CNT cathode material for lithium sulfur batteries[J]. Electronic Components and Materials, 2023,42(2):153-157.  

    25. [25]

      Wu H, Li Z X, Wang Z C, Ma Y J, Huang S R, Ding F, Li F Q, Zhai Q X, Ren Y L, Zheng X W, Yang Y R, Tang S C, Deng Y, Meng X K. Regulation of electronic structure in mediumentropy metal sulfides nanoparticles as highly efficient bifunctional electrocatalysts for zinc-air battery[J]. Appl. Catal. B-Environ., 2023,325122356. doi: 10.1016/j.apcatb.2022.122356

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