Citation: Zhihong LUO, Yan SHI, Jinyu AN, Deyi ZHENG, Long LI, Quansheng OUYANG, Bin SHI, Jiaojing SHAO. Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444 shu

Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries

Zhihong LUO ¹ ,
Yan SHI ¹ ,
Jinyu AN ² ,
Deyi ZHENG ¹ ,
Long LI ¹ ,
Quansheng OUYANG ³ ,
Bin SHI ^4,, ,
Jiaojing SHAO ^1,,

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China
2.
College of Civil Engineering, Guizhou University, Guiyang 550025, China
3.
Advanced Batteries and Materials Engineering Research Center, Guizhou Light Industry Technical College, Guiyang 550025, China
4.
State Key Laboratory of Advanced Chemical Power Sources, Guizhou Meiling Power Supply Co., Ltd., Zunyi, Guizhou 563003, China

Corresponding author: Bin SHI, shibin401@sina.com Jiaojing SHAO, shaojiao_jing@163.com
Received Date: 27 November 2023
Revised Date: 11 March 2024

Figures(6)

Herein, the positively charged two-dimensional (2D) porous silica (PSN⁺) nanosheet was obtained by modifying the 2D silica obtained from acid-etched 2D vermiculite, and then the PSN⁺ was used as the filler of polyethylene oxide (PEO)-based solid polymer electrolytes (SPEs). Given the abundant positive charges, PSN⁺ effectively binds with the anions dissociated from lithium salts, thereby promoting lithium-ion transport and achieving a decent lithium-ion transference number. At 50 ℃, the PSN⁺-based SPEs demonstrated a higher ionic conductivity of 7.5×10^-5 S·cm^-1, lithium-ion transference number of 0.30, and a stable voltage window of 4.41 V. Consequently, the as-assembled LiFePO₄||Li batteries delivered excellent initial discharge specific capacity of 155.7 mAh·g^-1 at 0.2C with 97.1% capacity retention after 100 cycles at 50 ℃.
- lithium-ion battery,
- solid polymer electrolyte,
- filler,
- two-dimensional silica
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