Citation: Wenbo LIU, Chunbo JIANG, Chao WU, Zhipeng HUANG, Chi ZHANG. A UV transparent rare earth metal formate exhibiting second harmonic generation response and moderate birefringence[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 281-288. doi: 10.11862/CJIC.20230429 shu

A UV transparent rare earth metal formate exhibiting second harmonic generation response and moderate birefringence

China-Australia Joint Research Center for Functional Molecular Materials, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

Corresponding author: Chao WU, wuc@tongji.edu.cn Chi ZHANG, chizhang@tongji.edu.cn
Received Date: 13 November 2023
Revised Date: 6 December 2023

Figures(6)

A rare earth metal formate, (C(NH₂)₃)[Er(HCOO)₄], was prepared via an evaporation method. Benefiting from its non-centrosymmetric structure, optical property studies reveal that (C(NH₂)₃)[Er(HCOO)₄] possessed a wide optical bandgap of 4.76 eV, moderate birefringence (0.066@546 nm), second harmonic generation (SHG) response (0.20 times that of KH₂PO₄ (KDP)), and phase-matchable capabilities at 1 064 nm. Theoretical calculations and crystal structure analysis revealed that the optical properties can be attributed to the synergy effects of the (C(NH₂)₃)⁺, [ErO₈], and HCOO^- units.
- formates,
- second harmonic generation,
- birefringence,
- first-principles calculation
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