Citation: Weichen WANG, Chunhua GONG, Junyong ZHANG, Yanfeng BI, Hao XU, Jingli XIE. Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415 shu

Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction

Weichen WANG ^{1, 2} ,
Chunhua GONG ^3,, ,
Junyong ZHANG ² ,
Yanfeng BI ^1,, ,
Hao XU ² ,
Jingli XIE ^2,,

1.
School of Petrochemical Engineering, Liaoning Petrochemical University, Fushun, Liaoning 113001, China
2.
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China
3.
School of Advanced Materials and Engineering, Jiaxing Nanhu University, Jiaxing, Zhejiang 314001, China

Corresponding author: Chunhua GONG, gongch@jxnhu.edu.cn Yanfeng BI, biyanfeng@lnpu.edu.cn Jingli XIE, jlxie@mail.zjxu.edu.cn
Received Date: 31 October 2023
Revised Date: 17 April 2024

Figures(6)

Two metal-organic frameworks (MOFs) containing rigid bis(triazole) ligand, namely {[Zn₂(L)(TP)₂(H₂O)·H₂O]}_n (1) and [Zn(L)(HTMA)]_n (2), where L=4, 4'-(3, 3'-dimethyl-(1, 1'-biphenyl)-4, 4'-diyl)bis(4H-1, 2, 4-triazole), H₂TP=terephthalic acid, H₃TMA=1, 3, 5-benzenetricarboxylic acid, were synthesized by using acid-base mixed ligands strategy and structurally characterized by X-ray single-crystal diffraction. Structural analysis reveals that MOF 1 displays a 3, 6-connected 2D structure with a new topological point symbol of (4²·6)₂(4⁸·6⁶·8), while MOF 2 presents a 2D sql topology structure. The catalytic studies reveal that 2 exhibits excellent catalytic activity for the cycloaddition reaction of CO₂ with epoxides under mild conditions. Furthermore, 2 can be reused at least three times while maintaining its catalytic ability.
- triazole,
- metal-organic framework,
- mixed-ligand strategy,
- CO₂ cycloaddition
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Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO2 cycloaddition reaction

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通讯作者: 陈斌, bchen63@163.com

Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction