Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts
- Corresponding author: Hailang JIA, jiahailang85@126.com
Citation: Hailang JIA, Hongcheng LI, Pengcheng JI, Yang TENG, Mingyun GUAN. Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
Eissa A A, Kim N H, Lee J H. Rational design of a highly mesoporous Fe-N-C/Fe3C/C-S-C nanohybrid with dense active sites for superb electrocatalysis of oxygen reduction[J]. J. Mater. Chem. A, 2020,8:23436-23454. doi: 10.1039/D0TA06987F
Gewirth A A, Varnell J A, DiAscro A M. Nonprecious metal catalysts for oxygen reduction in heterogeneous aqueous systems[J]. Chem. Rev., 2018,118:2313-2339. doi: 10.1021/acs.chemrev.7b00335
Kundu A, Mallick S, Ghora S, Raj C R. Advanced oxygen electrocatalyst for air-breathing electrode in Zn-air batteries[J]. ACS Appl. Mater. Interfaces, 2021,13:40172-40199. doi: 10.1021/acsami.1c08462
Kang Z W, Wang X C, Wang D, Bai B, Zhao Y F, Xiang X, Zhang B, Shang H S. Carbon-based single-atom catalysts: Impacts of atomic coordination on the oxygen reduction reaction[J]. Nanoscale, 2023,15:9605-9634. doi: 10.1039/D3NR01272G
Kundu A, Kuila T, Murmu N C, Samanta P, Das S. Metal-organic framework-derived advanced oxygen electrocatalysts as air-cathodes for Zn-air batteries: Recent trends and future perspectives[J]. Mater. Horiz., 2023,10:745-787. doi: 10.1039/D2MH01067D
Zhao Z Q, Chen H, Zhang W Y, Yi S, Chen H L, Su Z, Niu B, Zhang Y Y, Long D H. Defect engineering in carbon materials for electrochemical energy storage and catalytic conversion[J]. Mater. Adv., 2023,4:835-867. doi: 10.1039/D2MA01009G
Nagappan S, Duraivel M, Park N, Prabakar K, Park K H. Implementation of heteroatom-doped nanomaterial/core-shell nanostructure based electrocatalysts for fuel cells and metal-ion/air/sulfur batteries[J]. Mater. Adv., 2022,3:6096-6124. doi: 10.1039/D2MA00390B
Cai M J, Xu L, Guo J J, Yang X B, He X X, Hu P. Recent advances in metal-free electrocatalysts for the hydrogen evolution reaction[J]. J. Mater. Chem. A, 2024,12:592-612. doi: 10.1039/D3TA05901D
Wang L L, Liu Z P, Zhang J. Synthetic carbon nanomaterials for electrochemical energy conversion[J]. Nanoscale, 2022,14:13473-13489. doi: 10.1039/D2NR03865J
Mohan R, Modak A, Schechter A. A Comparative study of plasma-treated oxygen-doped single-walled and multiwalled carbon nanotubes as electrocatalyst for efficient oxygen reduction reaction[J]. ACS Sustain. Chem. Eng., 2019,7:11396-11406. doi: 10.1021/acssuschemeng.9b01125
Lu Y Y, Li X T, Kumar A K S, Compton R G. Does nitrogen doping enhance the electrocatalysis of the oxygen reduction reaction by multiwalled carbon nanotubes?[J]. ACS Catal., 2022,12:8740-8745. doi: 10.1021/acscatal.2c02465
Yan X C, Jia Y, Yao X D. Defects on carbons for electrocatalytic oxygen reduction[J]. Chem. Soc. Rev., 2018,47:7628-7658. doi: 10.1039/C7CS00690J
Hu C G, Paul R, Dai Q B, Dai L M. Carbon-based metal-free electrocatalysts: From oxygen reduction to multifunctional electrocatalysis[J]. Chem. Soc. Rev., 2021,50:11785-11843. doi: 10.1039/D1CS00219H
Feng X, Bai Y, Liu M Q, Li Y, Yang H Y, Wang X R, Wu C. Untangling the respective effects of heteroatom-doped carbon materials in batteries, supercapacitors and the ORR to design high performance materials[J]. Energy Environ. Sci., 2021,14:2036-2089. doi: 10.1039/D1EE00166C
Garg R, Jaiswal M, Kumar K, Kaur K, Rawat B, Kailasam K, Gautam U K. Extending conducting channels in Fe-N-C by interfacial growth of CNTs with minimal metal loss for efficient ORR electrocatalysis[J]. Nanoscale, 2023,15:15590-15599. doi: 10.1039/D3NR02706F
Zhang D, Ding R X, Tang Y Z, Ma L X, He Y. Stable Co/N-doped carbon nanotubes as catalysts for oxygen reduction[J]. ACS Appl. Nano Mater., 2022,5:10026-10035. doi: 10.1021/acsanm.2c02453
Yuan Y K, Wang Y F, He X Y, Chen M D, Liu J F, Liu B, Zhao H, Liu S Z, Yang H Q. Increasing gas sensitivity of Co3O4 octahedra by tuning Co-Co3O4 (111) surface structure and sensing mechanism of 3-coordinated Co atom as an active center[J]. J. Mater. Sci., 2020,31:8852-8864.
Garg R, Jaiswal M, Kumar K, Kaur K, Rawat B, Kailasam K, Gautam U K. Extending conducting channels in Fe-N-C by interfacial growth of CNTs with minimal metal loss for efficient ORR electrocatalysis[J]. Nanoscale, 2023,15:15590-15599. doi: 10.1039/D3NR02706F
Wen X D, Yang X Y, Li M, Bai L, Guan J Q. Co/CoOx nanoparticles inlaid onto nitrogen-doped carbon-graphene as a trifunctional electrocatalyst[J]. Electrochim. Acta, 2019,296:830-841. doi: 10.1016/j.electacta.2018.11.129
Gao Y X, Zheng D B, Li Q C, Xiao W P, Ma T Y, Fu Y L, Wu Z X, Wang L. 3D Co3O4-RuO2 hollow spheres with abundant interfaces as advanced trifunctional electrocatalyst for water-splitting and flexible Zn-air battery[J]. Adv. Funct. Mater., 2022,322203206. doi: 10.1002/adfm.202203206
Huang J S, Lu Q Q, Ma X, Yang X R. Bio-inspired FeN5 moieties anchored on a threedimensional graphene aerogel to improve oxygen reduction catalytic performance[J]. J. Mater. Chem. A, 2018,6:18488-18497. doi: 10.1039/C8TA06455E
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Inset: the partial enlarged image of Co3O4 nanoparticles.
Inset: the corresponding K-L plots.