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Citation: Chao WANG, Dongmei HE, Yu GUAN, Jiayi XU, Limin ZHENG, Yuejian LIN, Zhenxia CHEN, Kai LIANG. Self-assembly of zero-dimensional cluster {[Cu6(H2tba)6]·2DMF·xSolvent}, 2D sheet {[Sc(H2tba)3(DMF)]·2DMF}n and 3D network {[Fe(H2tba)2(H2O)2]·2DMF}n based on 2-thiobarbituric acid[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 263-269. doi: 10.11862/CJIC.20230396 shu

Self-assembly of zero-dimensional cluster {[Cu6(H2tba)6]·2DMF·xSolvent}, 2D sheet {[Sc(H2tba)3(DMF)]·2DMF}n and 3D network {[Fe(H2tba)2(H2O)2]·2DMF}n based on 2-thiobarbituric acid

  • 1.

    College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China

  • 2.

    Department of Chemistry, Fudan University, Shanghai 200433, China

  • Corresponding author: Kai LIANG, kliang@dhu.edu.cn
  • Received Date: 20 October 2023
    Revised Date: 12 December 2023

Figures(6)

  • Three complexes with different structures, namely {[Cu6(H2tba)6]·2DMF·xSolvent} (1), {[Sc(H2tba)3(DMF)]·2DMF}n (2), and {[Fe(H2tba)2(H2O)2]·2DMF}n (3) (DMF=N, N-dimethylformamide), were obtained through diffusion reactions using Cu(ClO4)2·6H2O, Sc(ClO4)3·6H2O, and Fe(ClO4)3·9H2O as metal salts, respectively, and 2-thiobarbituric acid (H3tba) as ligand. Complexes 1-3 were further characterized by FTIR, elemental analysis, TGA, and powder X-ray diffraction techniques. Single-crystal X-ray diffraction analysis reveals that complex 1 is a hexa-copper cluster with a trigonal antiprism structure, complex 2 is a 2D sheet structure, and complex 3 is a 3D network structure. Complex 1 exhibited strong luminescent emission spectra at 735 nm with an excitation peak at 390 nm.
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