Citation: Feilong GONG, Jingxuan LIU, Mengmeng LIU, Sankui XU, Feng LI. Dynamical modulation and electrochemical water splitting effect of oxygen doped onto MoS₂ core-shell spheres[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 256-262. doi: 10.11862/CJIC.20230390 shu

Dynamical modulation and electrochemical water splitting effect of oxygen doped onto MoS₂ core-shell spheres

Feilong GONG ¹ ,
Jingxuan LIU ¹ ,
Mengmeng LIU ¹ ,
Sankui XU ² ,
Feng LI ^{1, 3,,}

1.
Key Laboratory of Surface and Interface Science and Technology, Zhengzhou University of Light Industry, Zhengzhou 450002, China
2.
College of Material Engineering, Henan University of Technology, Zhengzhou 450001, China
3.
American Advanced Nanotechnology, Houston, TX 77459, USA

Corresponding author: Feng LI, lifeng696@yahoo.com
Received Date: 18 October 2023
Revised Date: 20 December 2023

Figures(4)

Monodispersed MoS₂ core-shell spheres were produced by annealing precursor MoS₂ core-shell superspheres at 900 ℃ in Ar. Simultaneously, O-doping amount (atomic fraction) can be tuned from 23.1% of precursor to 17.6%, 10.8%, 5.5%, and 6.2% of as-prepared materials by regulating the heating rate of 20, 10, 5, and 2 ℃·min^-1, respectively. The lower rate results in a lower amount of O doped onto MoS₂ core-shell spheres. Based on the special quasi-molecular superlattices of precursors, an in-situ anion exchange reaction mechanism was proposed to understand the dynamical modulation of O-doping. The study on the electrochemical properties of the materials demonstrates that their electrochemical performance in splitting water can be improved by tuning the O-doping amount.
- MoS₂,
- core-shell sphere,
- O-doped,
- dynamical modulation,
- electrochemical property,
- water splitting
1. [1]
  Zou X X, Zhang Y. Noble metal-free hydrogen evolution catalysts for water splitting[J]. Chem. Soc. Rev., 2015,44(15):5148-5180. doi: 10.1039/C4CS00448E
2. [2]
  Jaramillo T F, Jorgensen K P, Bonde J, Nielsen J H, Horch S, Chorkendorff I. Identification of active edge sites for electrochemical H₂ evolution from MoS₂ nanocatalysts[J]. Science, 2007,317(5834):100-102. doi: 10.1126/science.1141483
3. [3]
  Chen J, Liu G, Zhu Y Z, Su M, Yin P F, Wu X J, Lu Q P, Tan C L, Zhao M T, Liu Z Q, Yang W M, Li H, Nam G H, Zhang L P, Chen Z H, Huang X, Radjenovic P M, Huang W, Tian Z Q, Li J F, Zhang H. Ag@MoS₂ core-shell heterostructure as SERS platform to reveal the hydrogen evolution active sites of single-layer MoS₂[J]. J. Am. Chem. Soc., 2020,142(15):7161-7167. doi: 10.1021/jacs.0c01649
4. [4]
  Han J H, Kim H K, Baek B, Han J, Ahn H S, Baik M H, Cheon J. Activation of the basal plane in two-dimensional transition metal chalcogenide nanostructures[J]. J. Am. Chem. Soc., 2018,140(42):13663-13671. doi: 10.1021/jacs.8b05477
5. [5]
  Xiao W, Liu P T, Zhang J Y, Song W D, Feng Y P, Gao D Q, Ding J. Dual‑functional N dopants in edges and basal plane of MoS₂ nanosheets toward efficient and durable hydrogen evolution[J]. Adv. Energy Mater., 2017,7(7)1602086.
6. [6]
  Kim M, Anjum M A R, Lee M, Lee B J, Lee J S. Activating MoS₂ basal plane with Ni₂P nanoparticles for Pt-like hydrogen evolution reaction in acidic media[J]. Adv. Funct. Mater., 2019,29(10)1809151. doi: 10.1002/adfm.201809151
7. [7]
  Li G, Zhang D, Yu Y F, Huang S Y, Yang W T, Cao L Y. Activating MoS₂ for pH-universal hydrogen evolution catalysis[J]. J. Am. Chem. Soc., 2017,139(45):16194-16200. doi: 10.1021/jacs.7b07450
8. [8]
  Zhang Y C, Yang T R, Li J, Zhang Q, Li B Z, Gao M. Construction of Ru, O co-doping MoS₂ for hydrogen evolution reaction electrocatalyst and surface-enhanced Raman scattering substrate: High-performance, recyclable, and durability improvement[J]. Adv. Funct. Mater., 2022,33(3)2210939.
9. [9]
  Pető J, Ollár T, Vancsó P, Popov Z I, Magda G Z, Dobrik G, Hwang C, Sorokin P B, Tapasztó L. Spontaneous doping of the basal plane of MoS₂ single layers through oxygen substitution under ambient conditions[J]. Nat. Chem., 2018,10:1246-1251. doi: 10.1038/s41557-018-0136-2
10. [10]
  Deng J, Li H B, Xiao J P, Tu Y C, Deng D H, Yang H X, Tian H F, Li J Q, Ren P J, Bao X H. Triggering the electrocatalytic hydrogen evolution activity of the inert two-dimensional MoS₂ surface via single-atom metal doping[J]. Energy Environ. Sci., 2015,8(5):1594-1601. doi: 10.1039/C5EE00751H
11. [11]
  Wu W Z, Niu C Y, Wei C, Jia Y, Li C, Xu Q. Activation of MoS₂ basal planes for hydrogen evolution by zinc[J]. Angew. Chem. Int. Ed., 2019,131(7):2051-2055. doi: 10.1002/ange.201812475
12. [12]
  Yang W W, Zhang S Q, Chen Q, Zhang C, Wei Y, Jiang H, Lin Y X, Zhao M T, He Q Q, Wang X G, Du Yi, Song L, Yang S B, Nie A M, Zou X L, Gong Y J. Conversion of intercalated MoO₃ to multi-heteroatoms-doped MoS₂ with high hydrogen evolution activity[J]. Adv. Mater., 2020,32(30)e2001167. doi: 10.1002/adma.202001167
13. [13]
  Cao D F, Ye K, Moses O A, Xu W J, Liu D B, Song P, Wu C Q, Wang C D, Ding S Q, Chen S M, Ge B H, Jiang J, Song L. Engineering the in-plane structure of metallic phase molybdenum disulfide via Co and O dopants toward efficient alkaline hydrogen evolution[J]. ACS Nano, 2019,13(10):11733-11740. doi: 10.1021/acsnano.9b05714
14. [14]
  Shi Y, Zhou Y, Yang D R, Xu W X, Wang C, Wang F B, Xu J J, Xia X H, Chen H Y. Energy level engineering of MoS₂ by transition- metal doping for accelerating hydrogen evolution reaction[J]. J. Am. Chem. Soc., 2017,139(43):15479-15485. doi: 10.1021/jacs.7b08881
15. [15]
  Chen Z X, Leng K, Zhao X X, Malkhandi S, Tang W, Tian B B, Dong L, Zheng L R, Lin M, Yeo B S, Loh K P. Interface confined hydrogen evolution reaction in zero valent metal nanoparticles-intercalated molybdenum disulfide[J]. Nat. Commun., 2017,814548. doi: 10.1038/ncomms14548
16. [16]
  Xie J F, Zhang J J, Li S, Grote F, Zhang X D, Zhang H, Wang R X, Lei Y, Pan B C, Xie Y. Controllable disorder engineering in oxygen- incorporated MoS₂ ultrathin nanosheets for efficient hydrogen evolution[J]. J. Am. Chem. Soc., 2013,135(47):17881-17888. doi: 10.1021/ja408329q
17. [17]
  Yu L, Xia B Y, Wang X, Lou X W. General formation of M-MoS₃ (M=Co, Ni) hollow structures with enhanced electrocatalytic activity for hydrogen evolution[J]. Adv. Mater., 2016,28(1):92-97. doi: 10.1002/adma.201504024
18. [18]
  Zhang L, Wu H B, Yan Y, Wang X, Lou X W. Hierarchical MoS₂ microboxes constructed by nanosheets with enhanced electrochemical properties for lithium storage and water splitting[J]. Energy Environ. Sci., 2014,7(10):3302-3306. doi: 10.1039/C4EE01932F
19. [19]
  Park S, Park J, Abroshan H, Zhang L, Kim J K, Zhang J, Guo J, Siahrostami S, Zheng X. Enhancing catalytic activity of MoS₂ basal plane S-vacancy by Co cluster addition[J]. ACS Energy Lett., 2018,3(11):2685-2693. doi: 10.1021/acsenergylett.8b01567
20. [20]
  Li H, Tsai C, Koh A L, Cai L, Contryman A W, Fragapane A H, Zhao J, Han H S, Manoharan H C, Abild-Pedersen F. Correction: Corrigendum: Activating and optimizing MoS₂ basal planes for hydrogen evolution through the formation of strained sulphur vacancies[J]. Nat. Mater., 2016,15(3):364-364.
21. [21]
  Pető J, Ollár T, Vancsó P, Popov Z I, Magda G Z, Dobrik G, Hwang C, Sorokin P B, Tapasztó L. Spontaneous doping of the basal plane of MoS₂ single layers through oxygen substitution under ambient conditions[J]. Nat. Chem., 2018,10(12):1246-1251. doi: 10.1038/s41557-018-0136-2
22. [22]
  Li L, Qin Z, Ries L, Hong S, Michel T, Yang J, Salameh C, Bechelany M, Miele P, Kaplan D. Role of sulfur vacancies and undercoordinated Mo regions in MoS₂ nanosheets toward the evolution of hydrogen[J]. ACS Nano, 2019,13(6):6824-6834. doi: 10.1021/acsnano.9b01583
23. [23]
  Gong F L, Peng L F, Liu H Z, Zhang Y H, Jia D Z, Fang S M, Li F, Li D M. 3D core-shell MoS₂ superspheres composed of oriented nanosheets with quasi molecular superlattices: Mimicked embryo formation and Li-storage properties[J]. J. Mater. Chem. A, 2018,6(38):18498-18507. doi: 10.1039/C8TA07165A
24. [24]
  Li F, Gong F L, Xiao Y H, Zhang A Q, Zhao J H, Fang S M, Jia D Z. ZnO twin-spheres exposed in +/-(001) facets: Stepwise self-assembly growth and anisotropic blue emission[J]. ACS Nano, 2013,7(12):10482-10491. doi: 10.1021/nn404591z
25. [25]
  Li F, Ding Y, Gao P X, Xin X Q, Wang Z L. Single-cystal hexagonal disks and rings of ZnO: Low temperature, large-scale synthesis and growth mechanism[J]. Angew. Chem. Int. Ed., 2004,43(39):5238-5242. doi: 10.1002/anie.200460783
26. [26]
  Liu Y H, Gong L H, Zhang Y H, Wang P Y, Wang G Q, Bai F H, Zhao Z T, Gong F L, Liu J. Metal sulfides yolk-shell nanoreactors with dual component for enhanced acidic electrochemical hydrogen production[J]. Small Struct., 2022,4(3)2200247.
27. [27]
  Yang Y, Luo M C, Xing Y, Wang S T, Zhang W Y, Lv F, Li Y J, Zhang Y L, Wang W, Guo S J. A Universal strategy for intimately coupled carbon nanosheets/MoM nanocrystals (M=P, S, C, and O) hierarchical hollow nanospheres for hydrogen evolution catalysis and sodium-ion storage[J]. Adv. Mater., 2018,30(18)e1706085. doi: 10.1002/adma.201706085
1. [1]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
2. [2]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
3. [3]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
4. [4]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
5. [5]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
6. [6]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
7. [7]
  Pingping HAO , Fangfang LI , Yawen WANG , Houfen LI , Xiao ZHANG , Rui LI , Lei WANG , Jianxin LIU . Hydrogen production performance of the non-platinum-based MoS₂/CuS cathode in microbial electrolytic cells. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1811-1824. doi: 10.11862/CJIC.20240054
8. [8]
  Guo-Hong Gao , Run-Ze Zhao , Ya-Jun Wang , Xiao Ma , Yan Li , Jian Zhang , Ji-Sen Li . Core–shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation. Chinese Chemical Letters, 2024, 35(8): 109181-. doi: 10.1016/j.cclet.2023.109181
9. [9]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
10. [10]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
11. [11]
  Wenhao Chen , Jian Du , Hanbin Zhang , Hancheng Wang , Kaicheng Xu , Zhujun Gao , Jiaming Tong , Jin Wang , Junjun Xue , Ting Zhi , Longlu Wang . Surface treatment of GaN nanowires for enhanced photoelectrochemical water-splitting. Chinese Chemical Letters, 2024, 35(9): 109168-. doi: 10.1016/j.cclet.2023.109168
12. [12]
  Shuyuan Pan , Zehui Yang , Fang Luo . Ni-based electrocatalysts for urea assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(8): 100373-100373. doi: 10.1016/j.cjsc.2024.100373
13. [13]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
14. [14]
  Hengying Xiang , Nanping Deng , Lu Gao , Wen Yu , Bowen Cheng , Weimin Kang . 3D core-shell nanofibers framework and functional ceramic nanoparticles synergistically reinforced composite polymer electrolytes for high-performance all-solid-state lithium metal battery. Chinese Chemical Letters, 2024, 35(8): 109182-. doi: 10.1016/j.cclet.2023.109182
15. [15]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
16. [16]
  Yang Yang , Jing-Li Luo , Xian-Zhu Fu . Water-oxidation intermediates enabling electrochemical propylene epoxidation. Chinese Journal of Structural Chemistry, 2024, 43(5): 100269-100269. doi: 10.1016/j.cjsc.2024.100269
17. [17]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
18. [18]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2023.100197
19. [19]
  Ji Chen , Yifan Zhao , Shuwen Zhao , Hua Zhang , Youyu Long , Lingfeng Yang , Min Xi , Zitao Ni , Yao Zhou , Anran Chen . Heterogeneous bimetallic oxides/phosphides nanorod with upshifted d band center for efficient overall water splitting. Chinese Chemical Letters, 2024, 35(9): 109268-. doi: 10.1016/j.cclet.2023.109268
20. [20]
  Rui Deng , Wenjie Jiang , Tianqi Yu , Jiali Lu , Boyao Feng , Panagiotis Tsiakaras , Shibin Yin . Cycad-leaf-like crystalline-amorphous heterostructures for efficient urea oxidation-assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(7): 100290-100290. doi: 10.1016/j.cjsc.2024.100290

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(320)
HTML views(31)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dynamical modulation and electrochemical water splitting effect of oxygen doped onto MoS2 core-shell spheres

Metrics

通讯作者: 陈斌, bchen63@163.com

Dynamical modulation and electrochemical water splitting effect of oxygen doped onto MoS₂ core-shell spheres