Citation: Mengru CAO, Guoyuan JIANG, Hongli LI, Sinong LI, Huihua SONG. Two pairs of chiral cobalt enantiomeric coordination compounds based on D-(-)-/L-(+)-4-hydroxyphenylglycine: Synthesis, crystal structures, and electrochemical recognition[J]. Chinese Journal of Inorganic Chemistry, ;2024, 40(1): 232-246. doi: 10.11862/CJIC.20230381 shu

Two pairs of chiral cobalt enantiomeric coordination compounds based on D-(-)-/L-(+)-4-hydroxyphenylglycine: Synthesis, crystal structures, and electrochemical recognition

Hebei Key Laboratory of Organic Functional Molecules, College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050024, China

Corresponding author: Huihua SONG, songhuihua@hebtu.edu.cn
Received Date: 13 October 2023
Revised Date: 15 December 2023

Figures(14)

Two pairs of chiral coordination compounds {[Co(D-hpg)(4,4′-bipy)(H₂O)]Cl·H₂O}_n (1-D), {[Co(L-hpg)(4,4′-bipy)(H₂O)]Cl·H₂O}_n (1-L), [Co(D-hpg)₂(5,5′-BM-2,2′-bipy)]Cl·5.5H₂O (2-D), and [Co(L-hpg)₂(5,5′-BM-2,2′-bipy)] Cl·5.5H₂O (2-L), where D-Hhpg=D-(-)-4-hydroxyphenylglycine, L-Hhpg=L-(+)-4-hydroxyphenylglycine, 4,4′-bipy= 4,4′-bipyridine, 5,5′-BM-2,2′-bipy=5,5′-dimethyl-2,2′-bipyridine, have been successfully synthesized. Their structures were determined by single-crystal X-ray diffraction analysis and characterized by elemental analysis, X-ray photoelectron spectra, infrared spectroscopy, solid-state circular dichroism spectra, thermogravimetric analysis, powder X-ray diffraction, and electrochemical methods. Compounds 1-D and 1-L feature 2D (4, 4) rectangular grid networks that consist of left-or right-handed helical chains. Compounds 2-D and 2-L exhibit 0D molecule structures, and further 1D supramolecular double chains are formed by hydrogen bonding. The differences in the structures of these compounds are attributed to the influence of ancillary N-donor ligands and the coordination modes of Hhpg. Moreover, compound 1-D displays electrochemically reversible redox behavior, and serves as an electrochemical sensor for efficiently detecting histidine (His) enantiomers and quantitatively determining the enantiomeric excess in the His mixture.
- D-(-)-/L-(+)-4-hydroxyphenylglycine,
- chiral coordination compounds,
- crystal structures,
- electrochemical recognition
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